GB1065514A - A process for the polymerisation of ª‡-olefines - Google Patents
A process for the polymerisation of ª‡-olefinesInfo
- Publication number
- GB1065514A GB1065514A GB852965A GB852965A GB1065514A GB 1065514 A GB1065514 A GB 1065514A GB 852965 A GB852965 A GB 852965A GB 852965 A GB852965 A GB 852965A GB 1065514 A GB1065514 A GB 1065514A
- Authority
- GB
- United Kingdom
- Prior art keywords
- aluminium
- halide
- catalyst
- salts
- components
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
- F02B3/00—Engines characterised by air compression and subsequent fuel addition
- F02B3/06—Engines characterised by air compression and subsequent fuel addition with compression ignition
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
a -Olefines of formula CH2=CHR, in which R represents H or an aliphatic radical containing 1 to 5 carbon atoms in the main chain which may be unsubstituted or substituted by an alkyl- or phenyl group, e.g. ethylene, propylene or 4-methyl pentene-1, are polymerized in an organic solvent medium such as diesel oil or n-heptane in the presence of a catalyst comprising (a) a titanium halide, (b) a dialkyl aluminium halide and/or an alkyl aluminium sesquihalide, if desired with addition of a trialkyl aluminium to convert the monoalkyl aluminium halide into a dialkyl aluminium monohalide, and (c) an alkali metal- or alkaline earth metal salt of a carboxylic acid, which may be substituted by a halogen, or in the presence of a conversion product of these salts with one or more of the aforesaid catalyst components. The titanium halide (a) (e.g. TiCl4) is preferably reduced (to TiCl3) with ethyl aluminium sesquichloride prior to the addition of components (b) and (c). The exemplified components (b) are diethyl aluminium chloride, ethyl aluminium sesquichloride and triethyl aluminium. For component (c) sodium and potassium acetates are preferred, the salts exemplified being calcium acetate and the sodium salts of benzoic, butyric, monochloracetic, trichloracetic and oxalic acids. The catalyst has a high activity and produces a polymer of high stereospecificity, e.g. atactic amorphous polymers are produced from propylene and higher olefines. The reaction is terminated with butanol and the polymer washed with acetone.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEF0042132 | 1964-02-26 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1065514A true GB1065514A (en) | 1967-04-19 |
Family
ID=7098953
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB852965A Expired GB1065514A (en) | 1964-02-26 | 1965-02-26 | A process for the polymerisation of ª‡-olefines |
Country Status (3)
Country | Link |
---|---|
BE (1) | BE660309A (en) |
FR (1) | FR1425247A (en) |
GB (1) | GB1065514A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4444967A (en) * | 1975-12-22 | 1984-04-24 | Stauffer Chemical Company | Substantially agglomeration-free catalyst component |
US5116795A (en) * | 1985-08-02 | 1992-05-26 | Quantum Chemical Corporation | Alpha olefin oligomerization catalyst |
US5122581A (en) * | 1985-08-02 | 1992-06-16 | Quantum Chemical Corporation | Polymerization method |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL153555B (en) * | 1968-05-15 | 1977-06-15 | Stamicarbon | PROCESS FOR PREPARING ALKIN POLYMERS. |
CA1125268A (en) * | 1978-04-14 | 1982-06-08 | Exxon Research And Engineering Company | Trialkyl aluminum cocatalyst |
CA1142908A (en) * | 1979-03-07 | 1983-03-15 | Arthur W. Langer, Jr. | Trialkyl aluminum cocatalyst |
-
1965
- 1965-02-26 BE BE660309D patent/BE660309A/xx unknown
- 1965-02-26 GB GB852965A patent/GB1065514A/en not_active Expired
- 1965-02-26 FR FR7103A patent/FR1425247A/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4444967A (en) * | 1975-12-22 | 1984-04-24 | Stauffer Chemical Company | Substantially agglomeration-free catalyst component |
US5116795A (en) * | 1985-08-02 | 1992-05-26 | Quantum Chemical Corporation | Alpha olefin oligomerization catalyst |
US5122581A (en) * | 1985-08-02 | 1992-06-16 | Quantum Chemical Corporation | Polymerization method |
Also Published As
Publication number | Publication date |
---|---|
BE660309A (en) | 1965-08-26 |
FR1425247A (en) | 1966-01-14 |
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