GB1042474A - Dibenzocycloheptenes - Google Patents

Dibenzocycloheptenes

Info

Publication number
GB1042474A
GB1042474A GB3183365A GB3183365A GB1042474A GB 1042474 A GB1042474 A GB 1042474A GB 3183365 A GB3183365 A GB 3183365A GB 3183365 A GB3183365 A GB 3183365A GB 1042474 A GB1042474 A GB 1042474A
Authority
GB
United Kingdom
Prior art keywords
alkyl
substituted
hydrogen
formula
trimethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3183365A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Merck and Co Inc
Original Assignee
Merck and Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US209311A external-priority patent/US3270067A/en
Priority claimed from US212144A external-priority patent/US3272880A/en
Application filed by Merck and Co Inc filed Critical Merck and Co Inc
Publication of GB1042474A publication Critical patent/GB1042474A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C33/00Unsaturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C33/05Alcohols containing rings other than six-membered aromatic rings
    • C07C33/16Alcohols containing rings other than six-membered aromatic rings containing rings with more than six ring members
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C07C13/54Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with three condensed rings
    • C07C13/605Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with three condensed rings with a bridged ring system
    • C07C13/615Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with three condensed rings with a bridged ring system with an adamantane ring
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C33/00Unsaturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C33/05Alcohols containing rings other than six-membered aromatic rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C35/00Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring
    • C07C35/22Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring polycyclic, at least one hydroxy group bound to a condensed ring system

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

The invention comprises compounds of the formula <FORM:1042474/C2/1> in which the dotted line indicates that the compounds are saturated or unsaturated at the indicated position, each of X and X1 is a hydrogen, fluorine, chlorine, bromine or iodine atom, or a C1- 6 alkyl, C2- 6 alkenyl, C1- 4 perfluoroalkyl, phenyl, substituted phenyl, C1- 4 acyl, C1- 4 perfluoroacyl, C1- 4 alkylamino, C2- 8 dialkylamino, C1- 4 acylamino, C1- 4 perfluoroacylamino, C1- 4 alkylsulphonylamino, hydroxy, C1- 4 alkoxy, C1- 4 perfluoroalkoxy, cyano carboxy, carbamoyl, C2- 5 alkylcarbamoyl, C3- 9 dialkylcarbamoyl, C2- 6 carboalkoxy, mercapto, C1- 4 alkylmercapto, C1- 4 perfluoroalkylmercapto, C1- 4 alkylsulphonyl, C1- 4 perfluoroalkylsulphonyl, sulphamoyl, C1- 4 alkylsulphamoyl, or C2- 8 dialkylsulphamoyl group; and more than one substituent may be present on each benzene ring; Y is a hydrogen or halogen atom; and Z1 is a trimethylene or alkyl-substituted trimethylene radical; and a process for their preparation comprising adding HBr by a peroxide-catalysed addition reaction to a compound of the formula <FORM:1042474/C2/2> in which Z is an allyl or alkyl-substituted allyl radical.
GB3183365A 1962-07-12 1963-06-05 Dibenzocycloheptenes Expired GB1042474A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US209311A US3270067A (en) 1962-07-12 1962-07-12 Chemical process and products produced thereby
US212144A US3272880A (en) 1962-07-24 1962-07-24 Chemical process and products produced thereby

Publications (1)

Publication Number Publication Date
GB1042474A true GB1042474A (en) 1966-09-14

Family

ID=26904041

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3183365A Expired GB1042474A (en) 1962-07-12 1963-06-05 Dibenzocycloheptenes

Country Status (1)

Country Link
GB (1) GB1042474A (en)

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