GB1041876A - New catalytic systems for the polymerisation of vinyl chloride - Google Patents
New catalytic systems for the polymerisation of vinyl chlorideInfo
- Publication number
- GB1041876A GB1041876A GB29565/63A GB2956563A GB1041876A GB 1041876 A GB1041876 A GB 1041876A GB 29565/63 A GB29565/63 A GB 29565/63A GB 2956563 A GB2956563 A GB 2956563A GB 1041876 A GB1041876 A GB 1041876A
- Authority
- GB
- United Kingdom
- Prior art keywords
- vinyl chloride
- polymerisation
- catalytic systems
- new catalytic
- hydrazine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F218/02—Esters of monocarboxylic acids
- C08F218/04—Vinyl esters
- C08F218/08—Vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/02—Monomers containing chlorine
- C08F214/04—Monomers containing two carbon atoms
- C08F214/06—Vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
- C08F4/12—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of boron, aluminium, gallium, indium, thallium or rare earths
- C08F4/14—Boron halides or aluminium halides; Complexes thereof with organic compounds containing oxygen
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Abstract
In a modification of Specification 969,552 vinyl chloride is copolymerized with vinyl acetate at a temperature of 0 DEG C. or below using a catalyst comprising an organic peroxide and a trialkylboron complexed with hydrazine, said complex having the general formula R3B: NH2-NH2, where R is an alkyl group having 1 to 4 carbon atoms. A solvent such as methanol or acetone may be present during the copolymerization. Chain terminators, e.g. an aldehyde or a chlorinated solvent, and plasticizers such as phthalates may be present. In the examples the catalyst comprises triethyl-boron-hydrazine and monochloracetyl peroxide.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR851643A FR1287583A (en) | 1961-02-03 | 1961-02-03 | New vinyl chloride polymerization catalytic systems |
FR905055A FR82032E (en) | 1962-07-25 | 1962-07-25 | New vinyl chloride polymerization catalytic systems |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1041876A true GB1041876A (en) | 1966-09-07 |
Family
ID=26189177
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB4325/62A Expired GB969552A (en) | 1961-02-03 | 1962-02-05 | Improvements in or relating to the polymerisation of vinyl chloride |
GB29565/63A Expired GB1041876A (en) | 1961-02-03 | 1963-07-25 | New catalytic systems for the polymerisation of vinyl chloride |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB4325/62A Expired GB969552A (en) | 1961-02-03 | 1962-02-05 | Improvements in or relating to the polymerisation of vinyl chloride |
Country Status (5)
Country | Link |
---|---|
BE (1) | BE613381A (en) |
DE (2) | DE1299867B (en) |
FR (1) | FR1287583A (en) |
GB (2) | GB969552A (en) |
NL (3) | NL274241A (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
LU52929A1 (en) * | 1966-02-10 | 1967-04-03 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2586550A (en) * | 1947-09-10 | 1952-02-19 | Atomic Energy Commission | Halogen-substituted acetyl peroxide catalyst for halo-olefin polymerization |
NL231154A (en) * | 1957-09-06 |
-
0
- NL NL120881D patent/NL120881C/xx active
- NL NL295813D patent/NL295813A/xx unknown
- NL NL274241D patent/NL274241A/xx unknown
- BE BE613381D patent/BE613381A/xx unknown
-
1961
- 1961-02-03 FR FR851643A patent/FR1287583A/en not_active Expired
-
1962
- 1962-01-31 DE DEC26126A patent/DE1299867B/en not_active Withdrawn
- 1962-02-05 GB GB4325/62A patent/GB969552A/en not_active Expired
-
1963
- 1963-07-03 DE DE19631495309 patent/DE1495309A1/en active Pending
- 1963-07-25 GB GB29565/63A patent/GB1041876A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
BE613381A (en) | |
DE1299867B (en) | 1969-07-24 |
DE1495309A1 (en) | 1969-02-20 |
NL274241A (en) | |
NL295813A (en) | |
GB969552A (en) | 1964-09-09 |
FR1287583A (en) | 1962-03-16 |
NL120881C (en) |
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