GB1041058A - Antimicrobial composition and process - Google Patents
Antimicrobial composition and processInfo
- Publication number
- GB1041058A GB1041058A GB23641/63A GB2364163A GB1041058A GB 1041058 A GB1041058 A GB 1041058A GB 23641/63 A GB23641/63 A GB 23641/63A GB 2364163 A GB2364163 A GB 2364163A GB 1041058 A GB1041058 A GB 1041058A
- Authority
- GB
- United Kingdom
- Prior art keywords
- bismuth
- group
- phenyl
- substituted
- acetate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
- A01N55/02—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur containing metal atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0058—Biocides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/907—Resistant against plant or animal attack
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Plant Pathology (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Health & Medical Sciences (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Paper (AREA)
- Paints Or Removers (AREA)
Abstract
Paints are protected against attack by fungi and bacteria by applying to the surface of said material or incorporating therein a bismuth compound of the formula R13BiX2 or RnBiX3-n, wherein n is 1 or 2, X is a monovalent anionic atom or group of two X's when taken together represent a divalent anionic atom or group, R1 is a substituted or unsubstituted aryl group and R is a substituted or unsubstituted alkyl, cyclo-alkyl, alkenyl or aryl group. X may be a halogen, e.g. F, Br, Cl, oxygen, sulphur, carboxylate, phenoxide, mercapto propionate; hydroxybenzoate, amino benzoate, chloroacetate, tartrate isooctyl mercapto-acetate methacrylate, acrylate, thiocyanate, alkoxide, hydroxide, acetate, salicylate, benzoate, or cyanide group. R11 may be a phenyl, chlorophenyl, tolyl alkoxy phenyl, nitrophenyl or xylyl group. Other microbicides, e.g. quaternary ammonium salts such as lauryl dimethyl benzy ammonium chloride, triorganotin compounds, pentachlorophenol, copper-8-quinolisolate, bisphenols, o-phenyl phenol, brominated salicylanilides or zinc dialkyl dithiocarbanate. The bismuth compounds may be formulated as dusts, solutions, suspensions, aerosols and emulsions containing if desired nonionic, cationic or anionic surfactants. In the examples, a paint comprising TiO2/CaSo4, calcium carbonate, magnesium silicate, ester gum solution, bodied linseed oil, mineral spirits, cobalt naphthenate, lead naphthenate and phenyl bismuth dilauryl mercaptide is described.ALSO:Paper mill and oil recovery waters are protected against attack by fungi and bacteria by applying to the surface of said material or incorporating therein a bismuth compound of the formula R13BiX2 or RnBiX3- n, wherein n is 1 or 2, X is a monovalent anionic atom or group or two X's when taken together represent a divalent anionic atom or group, R1 is a substituted or unsubstituted aryl group and R is a substituted or unsubstituted alkyl, cycloalkyl, alkenyl or aryl group. X may be a halogen, e.g. F, BrCl, oxygen, sulphur, carboxylate, phenoxide, mercapto propionate, hydroxybenzoate, amino benzoate, chloroacetate, tartrate iso-octyl mercapto-acetate, methacrylate, acrylate, thiocyanate, alkoxide, hydroxide, acetate, salicylate, benzoate, or cyanide group. R11 may be a phenyl, chlorophenyl, tolyl alkoxy phenyl, nitrophenyl or xylyl group. Other microbicides, e.g. quaternary ammonium salts such as lauryl dimethyl benzy ammonium chloride, triorganotin compounds, pentachlorophonol, copper-8-quinolisolate, bisphenols, o-phenyl phenol, brominated salicylanilides or zinc dialkyl dithiocarbamate. The bismuth compounds may be formulated as dusts, solutions, suspensions, aerosols and emulsions containing if desired nonionic, cationic or anionic surfactants.ALSO:Synthetic resin compositions are protected against attack by fungi and bacteria by applying to the surface of said material or incorporating therein a bismuth compound of the formula R13BiX2 or RnBiX3- n, wherein n is 1 or 2, X is a monovalent anionic atom or group or two X's when taken together represent a divalent anionic atom or group, R1 is a substituted or unsubstituted aryl group and R is a substituted or unsubstituted alkyl, cyclo-alkyl, alkenyl or aryl group. The Examples describe compositions containing (1) TiO2 aluminium silicate, talc, a methyl methacrylate-butyl methacrylate copolymer mineral spirits, and dibutyl bismuth acetate (5) TiO2, bentonite, tricresyl phosphite a vinylchloride-vinyl acetate copolymer, triphenyl bismuth chloride and phenyl bismuth chloride toluene and methyl isobutyl ketone, and (23)-(26) polyvinyl chloride, triphenyl-bismuth dichloride, dioctyl phthalate and stearic acid.ALSO:Materials are protected against attack by fungi and bacteria by applying to the surface of said material or incorporating therein a bismuth compound of the formula R 1/3 B1X2 or RnBiX3-n, wherein n is 1 or 2, X is a manovalent anionic atom or group or two X's when taken together represent a divalent anionic atom or group, R1 is a substituted or unsubstituted aryl group and R is a substituted or unsubstituted alkyl, cyclo-alkyl, alkenyl or aryl group. X may be a halogen e.g. F, Br, Cl oxygen, sulphur, carboxylate, phenoxide, mercapto propionate; hydroxy benzoale, amino benzoate, chloroacetate, tatrate isochylmercaptoacetate methacrylate, acrylate, thiocyanate, alkoxide, hydroxide, acetate, salicylate, benzoate, or cyanide group. R1, may be a phenyl, chlorophenyl, tolyl alkoxyphenyl nitrophenyl or xylyl group. Other microbicides e.g. quaternary ammonium salts such as lauryl dimethyl benzyl ammonium chloride, triorganotin compounds, pentachlorophenol, copper-8-quinolinolate, bisphenols, o-phenyl phenol, brominated salicylanilides or zinc dialkyl dithiocarbanate. The bismuth compounds may be formulated as dusts, solutions, suspensions, aerosols and emulsions containing if desired nonionic, cationic or anionic surfactants. The bismuth compounds may be used to treat materials such as textiles, paper paper mill and oil recovery waters, adhesives, plants, synthetic resins and paints. In the examples paints comprising T1O2, aluminium silicate, talc, methyl methacrylatebutyl methacrylate copolymer mineral spirits, and dibutyl bismuth acetate-Ex5, T1O2, bentonite, tricresyl phosphite vinylchloride-vinyl acetate copolymer, triphenyl bismuth chloride and phenyl bismuth chloride-Ex6 and T1O2/CaSO4, calcium carbonate, magnesium silicate ester gum solution, bodies linseed oil, mineral spirits, cobalt naphthenate, lead naphthenate and phenyl bismuth dilauryl mercaptide are described.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US202377A US3239411A (en) | 1962-06-14 | 1962-06-14 | Organo bismuth biocide |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1041058A true GB1041058A (en) | 1966-09-01 |
Family
ID=22749621
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB23641/63A Expired GB1041058A (en) | 1962-06-14 | 1963-06-13 | Antimicrobial composition and process |
Country Status (5)
Country | Link |
---|---|
US (1) | US3239411A (en) |
CH (1) | CH462771A (en) |
DE (1) | DE1492391A1 (en) |
GB (1) | GB1041058A (en) |
SE (1) | SE305975B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8821906B2 (en) | 2003-05-23 | 2014-09-02 | Gambro Lundia Ab | Biocompatible polymer |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL299665A (en) * | 1963-01-26 | |||
US3323928A (en) * | 1964-09-16 | 1967-06-06 | Carlisle Chemical Works | Cement containing calcium carbonate particles coated with bis (tributyltin)-oxide |
US3504005A (en) * | 1966-01-03 | 1970-03-31 | Monsanto Co | Organoantimony and -bismuth compounds |
CH1246067D (en) * | 1966-10-06 | |||
US3530158A (en) * | 1966-11-25 | 1970-09-22 | M & T Chemicals Inc | Organo antimony mercaptides and the preparation thereof |
US3852441A (en) * | 1970-12-14 | 1974-12-03 | Procter & Gamble | Synergistic mixtures of diphenylbismuth acetate and the zinc salt of 1-hydroxy-2-pyridine thione effect as antibacterial and antifungal agents |
US3753990A (en) * | 1972-01-17 | 1973-08-21 | Procter & Gamble | Phenylbismuth bis(2-pyridinethiol 1-oxide) |
US3998785A (en) * | 1974-06-13 | 1976-12-21 | International Business Machines Corporation | Anti-fungal and/or anti-bacterial hardware for ink printing apparatus |
US5939045A (en) * | 1994-12-22 | 1999-08-17 | Nissan Chemical Industries, Ltd. | Organic bismuth derivatives for X-ray imaging |
GB9501560D0 (en) | 1995-01-26 | 1995-03-15 | Nycomed Imaging As | Contrast agents |
HUP9900428A2 (en) * | 1995-01-26 | 1999-06-28 | Nycomed Imaging A/S | Bismuth compounds, diagnostic contrast medium containing them, use thereof and pharmaceutical composition |
US6899804B2 (en) * | 2001-12-21 | 2005-05-31 | Applied Materials, Inc. | Electrolyte composition and treatment for electrolytic chemical mechanical polishing |
DE10236347A1 (en) † | 2002-08-08 | 2004-02-19 | Basf Coatings Ag | Electrodip paints, useful for coating electrically conductive materials, in preparation of electrodip coated components and/or in multilayer wet-on-wet painting, contain bismuth compounds and binder |
FR3027770B1 (en) * | 2014-10-30 | 2018-10-19 | Universite De Haute-Alsace | USE OF BISMUTH SUB-SALICYLATE OR ONE OF ITS DERIVATIVES AS A PHYTOPHARMACEUTICAL AGENT |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2114012A (en) * | 1935-06-12 | 1938-04-12 | Lever Brothers Ltd | Aromatic mercury alcoholates of salts of hydroxy carboxylic acids |
US2113567A (en) * | 1936-09-28 | 1938-04-12 | Lever Brothers Ltd | Aryl mercury oxygenated compounds of arsenic, antimony, or bismuth |
US2423262A (en) * | 1943-08-28 | 1947-07-01 | Frank J Sowa | Compounds having the formula |
US2555114A (en) * | 1944-11-17 | 1951-05-29 | Ward Blenkinsop & Co Ltd | Manufacture of derivatives of disubstituted methane compounds |
-
1962
- 1962-06-14 US US202377A patent/US3239411A/en not_active Expired - Lifetime
-
1963
- 1963-06-12 DE DE19631492391 patent/DE1492391A1/en active Pending
- 1963-06-13 CH CH737463A patent/CH462771A/en unknown
- 1963-06-13 GB GB23641/63A patent/GB1041058A/en not_active Expired
- 1963-06-13 SE SE6569/63A patent/SE305975B/xx unknown
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8821906B2 (en) | 2003-05-23 | 2014-09-02 | Gambro Lundia Ab | Biocompatible polymer |
Also Published As
Publication number | Publication date |
---|---|
DE1492391A1 (en) | 1970-03-05 |
CH462771A (en) | 1968-11-15 |
SE305975B (en) | 1968-11-11 |
US3239411A (en) | 1966-03-08 |
CH737463A4 (en) | 1968-06-14 |
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