GB1039345A - Preparation of zeolites x and y - Google Patents

Preparation of zeolites x and y

Info

Publication number
GB1039345A
GB1039345A GB1318863A GB1318863A GB1039345A GB 1039345 A GB1039345 A GB 1039345A GB 1318863 A GB1318863 A GB 1318863A GB 1318863 A GB1318863 A GB 1318863A GB 1039345 A GB1039345 A GB 1039345A
Authority
GB
United Kingdom
Prior art keywords
alkali metal
clay
silica
water
slurry
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1318863A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Socony Mobil Oil Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Socony Mobil Oil Co Inc filed Critical Socony Mobil Oil Co Inc
Publication of GB1039345A publication Critical patent/GB1039345A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/20—Silicates
    • C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
    • C01B33/28—Base exchange silicates, e.g. zeolites
    • C01B33/2807—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures
    • C01B33/2838—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures of faujasite type, or type X or Y (UNION CARBIDE trade names; correspond to GRACE's types Z-14 and Z-14HS, respectively)
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/20—Silicates
    • C01B33/36—Silicates having base-exchange properties but not having molecular sieve properties
    • C01B33/46—Amorphous silicates, e.g. so-called "amorphous zeolites"

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)

Abstract

A crystalline aluminosilicate zeolite having the crystal structure common to zeolites X and Y is prepared by forming a frit from an aqueous slurry of clay, alkali metal hydroxide and either silica or a precursor thereof by maintaining the slurry at a temperature of 230-1600 DEG F., the proportions of the reactants in the slurry being as follows:- Weight ratio total alkali metal oxide : water-free clay 0.95-7.4 : 1 Weight ratio silica/water-free clay 0.01-3.8 : 1, and digesting the frit in water at 180-220 DEG F., the mole ratio of water : alkali metal oxide being 35-180 : 1, until crystalline alumino-silicate is formed. The term "crystalline" is used to mean either wholly or partially crystalline. Preferably before digestion the frit is ground to \sT60 mesh and dispersed in water in proportion 3 : 1 parts respectively. The clay may be a raw uncalcined natural clay; the alkali metal hydroxide is preferably sodium, and silica is supplied as sand, quartz, colloidal silica, silica gel, siliceous earth, alkali metal silicate or ethyl orthosilicate. To obtain a catalyst material suitable, for example, for cracking hydrocarbons, the alkali metal ions may be exchanged up to 97% by alkaline earth metals, rare earth or transition metals, silver, magnesium ammonium or hydrogen; alternatively, providing the stipulated alkali metal oxide to clay ratio is maintained, at least one of the ions may be included in the initial slurry. The base-exchanged material is used per se as a catalyst or suspended in a matrix of, for example, a clay or a cogel of silica (55-100% weight) and alumina and/or zirconia, the catalyst being air-dried and calcined before use.
GB1318863A 1962-04-11 1963-04-03 Preparation of zeolites x and y Expired GB1039345A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US18679462A 1962-04-11 1962-04-11
US18680462A 1962-04-11 1962-04-11

Publications (1)

Publication Number Publication Date
GB1039345A true GB1039345A (en) 1966-08-17

Family

ID=26882419

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1318863A Expired GB1039345A (en) 1962-04-11 1963-04-03 Preparation of zeolites x and y

Country Status (2)

Country Link
DE (1) DE1467133A1 (en)
GB (1) GB1039345A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004087573A1 (en) * 2003-04-04 2004-10-14 Nanochem Holdings Pty Ltd Aluminosilicates of zeolite n structure

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004087573A1 (en) * 2003-04-04 2004-10-14 Nanochem Holdings Pty Ltd Aluminosilicates of zeolite n structure
AU2004226362B2 (en) * 2003-04-04 2009-07-30 Nanochem Holdings Pty Ltd Aluminosilicates of zeolite N structure

Also Published As

Publication number Publication date
DE1467133A1 (en) 1969-02-13

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