GB1037773A - Heterogeneous cobalt complex monoazo dye compounds their production and use - Google Patents

Heterogeneous cobalt complex monoazo dye compounds their production and use

Info

Publication number
GB1037773A
GB1037773A GB1367263A GB1367263A GB1037773A GB 1037773 A GB1037773 A GB 1037773A GB 1367263 A GB1367263 A GB 1367263A GB 1367263 A GB1367263 A GB 1367263A GB 1037773 A GB1037773 A GB 1037773A
Authority
GB
United Kingdom
Prior art keywords
hydroxy
dyes
cobalt
amino
monoazo
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1367263A
Inventor
Rheinhard Neier
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sandoz Patent Ltd
Sandoz AG
Original Assignee
Sandoz Patent Ltd
Sandoz AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sandoz Patent Ltd, Sandoz AG filed Critical Sandoz Patent Ltd
Publication of GB1037773A publication Critical patent/GB1037773A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B62/00Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
    • C09B62/44Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring
    • C09B62/523Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring the reactive group being an esterified or non-esterified hydroxyalkyl sulfonyl amido or hydroxyalkyl amino sulfonyl group, a quaternised or non-quaternised amino alkyl sulfonyl amido group, or a substituted alkyl amino sulfonyl group, or a halogen alkyl sulfonyl amido or halogen alkyl amino sulfonyl group or a vinyl sulfonylamido or a substituted vinyl sulfonamido group
    • C09B62/527Azo dyes
    • C09B62/535Metal complex azo dyes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Coloring (AREA)

Abstract

The invention comprises heterogeneous cobalt complex compounds containing monoazo dyes, one of the said monoazo dyes being of the formula <FORM:1037773/C4-C5/1> wherein X represents hydrogen, halogen, alkyl or alkoxy and the NH2 group is in the adjacent position to the -N = N- group and the other monoazo dye being a member of the ortho, ortho1-dihydroxy - benzene - azonapthalene series, and cobalt, less than two cobalt atoms being in complex combination with two molecules of monoazo compound. The dye complexes are obtained by treating appropriate dyes with an appropriate quantity of a cobalt yielding agent. In example (1) a cobalt complex is obtained by reacting the dyes 2-amino-1-hydroxy - 5 - nitrobenzene \sQ 2 - aminonaphthalene - 6 - sulphonic acid - (21 - hydroxy)-propylamide and 2-amino-1-hydroxy-5-nitrobenzene \sQ 2 - hydroxynapthalene in aqueous sodium hydroxide solution with a solution of cobaltous sulphate and tartaric acid. Many additional examples are furnished.ALSO:A vinyl chloride-vinyl acetate copolymer solution is coloured with the cobalt complex of the dyes 2-amino-1-hydroxy-5-nitro-benzene --> 2 - aminonaphthalene - 6 - sulphonic acid-(21 - hydroxy) - propylamide and 2 - amino - 1 -hydroxy - 5 - nitrobenzene --> 2 - hydroxynaphthalene (see Division C4).
GB1367263A 1962-04-11 1963-04-05 Heterogeneous cobalt complex monoazo dye compounds their production and use Expired GB1037773A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH443262A CH411173A (en) 1962-04-11 1962-04-11 Process for the production of mixed cobalt complex compounds

Publications (1)

Publication Number Publication Date
GB1037773A true GB1037773A (en) 1966-08-03

Family

ID=4276010

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1367263A Expired GB1037773A (en) 1962-04-11 1963-04-05 Heterogeneous cobalt complex monoazo dye compounds their production and use

Country Status (2)

Country Link
CH (1) CH411173A (en)
GB (1) GB1037773A (en)

Also Published As

Publication number Publication date
CH411173A (en) 1966-04-15

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