GB1028908A - Improvements in or relating to the manufacture of polymeric cellular materials - Google Patents

Improvements in or relating to the manufacture of polymeric cellular materials

Info

Publication number
GB1028908A
GB1028908A GB49132/63A GB4913263A GB1028908A GB 1028908 A GB1028908 A GB 1028908A GB 49132/63 A GB49132/63 A GB 49132/63A GB 4913263 A GB4913263 A GB 4913263A GB 1028908 A GB1028908 A GB 1028908A
Authority
GB
United Kingdom
Prior art keywords
isocyanate
acids
polymers
specified
vinyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB49132/63A
Inventor
John Richard Lewis
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB49132/63A priority Critical patent/GB1028908A/en
Publication of GB1028908A publication Critical patent/GB1028908A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/68—Unsaturated polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0025—Foam properties rigid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/005—< 50kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/0058—≥50 and <150kg/m3

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Laminated Bodies (AREA)

Abstract

Cellular materials are obtained by interacting an unsaturated polyester with at least 2 isocyanate-reactive groups per molecule, an ethylenically unsaturated comonomer, an organic polyisocyanate and water in the presence of a polymerization catalyst, a volatile organic liquid which is inert with respect to the other ingredients, and a thermoplastic film-forming polymer. The majority of isocyanate-reactive groups may be hydroxyl. Unsaturated polyesters specified are made from a : b -unsaturated polycarboxylic acids, with or without the addition of saturated or aromatic mono- or poly-carboxylic acids, and polyhydric alcohols. Among the acids mentioned are trimesic and trimellitic acids. Polyhydric alcohols part from the usual glycols include diethylene glycol, trimethylol propane, trimethylol ethane, pentaerythritol and glycerol. The proportions of the acids and polyols are so chosen to give the required 2 or more isocyanate-reactive groups which are usually hydroxyl groups. Specified comonomers include styrene and derivatives thereof, esters and nitriles of acrylic and methacrylic acids, vinyl and vinylidene halides, and esters of vinyl and allyl alcohols including diallyl phthalate. Polyisocyanates specified, include, apart from the usual di-isocyanates, tri-isocyanates such as 2:4:6-triisocyanatotoluene, 2:4:41 - triisocyanato - diphenylether, and the reaction product of an excess of di-isocyanate with trimethylol propane, and the uretedione dimers and isocyanurate polymers of di-isocyanates. Specified polymerization catalysts include benzoyl peroxide, methyl-ethylketone peroxide, cumene hydroperoxide, cyclohexanone peroxide, and cobalt naphthenate. Volatile liquids are preferably soluble in the reaction mixture and boil at temperatures not exceeding 90 DEG C., and preferably below 50 DEG C., examples being various fluorine and chlorine containing hydrocarbons, pentanes and hexanes, acetone and di-isopropyl ether. Thermoplastic film-forming polymers include cellulose ethers and esters, polymers and co-polymers of vinyl chloride and vinyl acetate (partially hydrolysed). Catalysts for the isocyanate reaction include various nitrogen containing bases, potassium carbonate, acetate and naphthenate, various lead zinc and tin compounds. Various silicone and polyether surfactants are mentioned. Preferred compositions include, on the weight of the total mixture: 15-40% polyisocyanate, 0.25-4% polymerization catalyst, 5-20% volatile liquid, 0.5-3.0% water, and 2-10% thermoplastic film-forming polymer.
GB49132/63A 1963-12-12 1963-12-12 Improvements in or relating to the manufacture of polymeric cellular materials Expired GB1028908A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB49132/63A GB1028908A (en) 1963-12-12 1963-12-12 Improvements in or relating to the manufacture of polymeric cellular materials

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB49132/63A GB1028908A (en) 1963-12-12 1963-12-12 Improvements in or relating to the manufacture of polymeric cellular materials

Publications (1)

Publication Number Publication Date
GB1028908A true GB1028908A (en) 1966-05-11

Family

ID=10451273

Family Applications (1)

Application Number Title Priority Date Filing Date
GB49132/63A Expired GB1028908A (en) 1963-12-12 1963-12-12 Improvements in or relating to the manufacture of polymeric cellular materials

Country Status (1)

Country Link
GB (1) GB1028908A (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4032485A (en) * 1975-02-27 1977-06-28 Miyoshi Yushi Kabushiki Kaisha Polyurethane foams based on mixed itaconic acid polyesters
US4261946A (en) 1978-12-16 1981-04-14 Bayer Aktiengesellschaft Process for the production of thermoplastic polymer by introducing thermoplastic polymer into an extruder and adding organic polyisocyanate and chain lengthening agent
WO1981002017A1 (en) * 1980-01-14 1981-07-23 Whitney & Co Inc Cellular forming agent in resinous systems and resulting products
WO1983000458A1 (en) * 1981-08-10 1983-02-17 Saidla, Glen, W. Molding of unsaturated polyester
US4464320A (en) * 1980-01-14 1984-08-07 Whitney & Company, Inc. Reaction injection molding system for expanded synthetic articles
US4476076A (en) * 1980-01-14 1984-10-09 Whitney & Company, Inc. Method of open forming an expanded polyester resin article involving a controlled induction period
US4664982A (en) * 1983-07-15 1987-05-12 American Standard Inc. Multi-layer composite structure
FR2594123A1 (en) * 1986-01-29 1987-08-14 Cahart Christine Process making it possible to facilitate the use of unsaturated polyester resins and products obtained by this process
US5868396A (en) * 1996-01-16 1999-02-09 Tts Theissen Training Systems Gmbh Movable target for shooting practice

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4032485A (en) * 1975-02-27 1977-06-28 Miyoshi Yushi Kabushiki Kaisha Polyurethane foams based on mixed itaconic acid polyesters
US4261946A (en) 1978-12-16 1981-04-14 Bayer Aktiengesellschaft Process for the production of thermoplastic polymer by introducing thermoplastic polymer into an extruder and adding organic polyisocyanate and chain lengthening agent
WO1981002017A1 (en) * 1980-01-14 1981-07-23 Whitney & Co Inc Cellular forming agent in resinous systems and resulting products
US4358548A (en) * 1980-01-14 1982-11-09 Whitney & Company, Inc. Cellular forming agent in resinous systems and resulting products
US4464320A (en) * 1980-01-14 1984-08-07 Whitney & Company, Inc. Reaction injection molding system for expanded synthetic articles
US4476076A (en) * 1980-01-14 1984-10-09 Whitney & Company, Inc. Method of open forming an expanded polyester resin article involving a controlled induction period
WO1983000458A1 (en) * 1981-08-10 1983-02-17 Saidla, Glen, W. Molding of unsaturated polyester
US4664982A (en) * 1983-07-15 1987-05-12 American Standard Inc. Multi-layer composite structure
FR2594123A1 (en) * 1986-01-29 1987-08-14 Cahart Christine Process making it possible to facilitate the use of unsaturated polyester resins and products obtained by this process
US5868396A (en) * 1996-01-16 1999-02-09 Tts Theissen Training Systems Gmbh Movable target for shooting practice

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