GB1017271A - New reactive dyestuffs containing triazine residues - Google Patents

New reactive dyestuffs containing triazine residues

Info

Publication number
GB1017271A
GB1017271A GB1926361A GB1926361A GB1017271A GB 1017271 A GB1017271 A GB 1017271A GB 1926361 A GB1926361 A GB 1926361A GB 1926361 A GB1926361 A GB 1926361A GB 1017271 A GB1017271 A GB 1017271A
Authority
GB
United Kingdom
Prior art keywords
groups
dyes
formula
radical
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1926361A
Inventor
Herbert Francis Andrew
Dennis Eckersley
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB1926361A priority Critical patent/GB1017271A/en
Publication of GB1017271A publication Critical patent/GB1017271A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
    • C09B62/44—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring
    • C09B62/4401—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring with two or more reactive groups at least one of them being directly attached to a heterocyclic system and at least one of them being directly attached to a non-heterocyclic system
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
    • C09B62/02—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group directly attached to a heterocyclic ring
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
    • C09B62/02—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group directly attached to a heterocyclic ring
    • C09B62/04—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group directly attached to a heterocyclic ring to a triazine ring
    • C09B62/08—Azo dyes

Abstract

The invention comprises reactive dyes of formula <FORM:1017271/C4-C5/1> wherein D and D1 are radicals of the same or different water-soluble azo, anthraquinone, nitro or phthalocyanine dyes having the indicated nitrogen atom attached to a carbon atom of the dyestuff radical, R, R1, R2, R3, R4 R5 are independently hydrogen atoms or alkyl groups, A is a direct link or a divalent organic linking group, P is an alkylene, arylene or substituted arylene radical, Q is any substituent and Z is an acyl radical which contains an acyl radical capable of reaction with the hydroxyl groups of cellulose with formation of a covalent bond. Specified acyl radicals include the radicals of acrylic, a -chloro-acrylic, propiolic, maleic, mono-and di-chloromaleic, chloroacetic, b -chloro- or bromo-propionic and a ,b -dichloro-propionic acids. Preferred acyl radicals are triazine and pyrimidine residues containing as reactive groups chlorine and bromine atoms; sulphonic acid, thiocyano, negatively substituted aryloxy or arylthio groups; groups of formula:- <FORM:1017271/C4-C5/2> wherein Y completes a 5- or 6-membered heterocyclic ring which may be substituted or form part of a fused ring system; quaternary ammonium or pyridinium groups; groups of formula:- <FORM:1017271/C4-C5/3> wherein R6 and R7 are alkyl, cycloalkyl, aryl or aralkyl groups or together with the nitrogen atom a 5- or 6-membered ring; and groups of formula:- <FORM:1017271/C4-C5/4> wherein R8 and R9 are hydrogen atoms or alkyl, aryl or aralkyl groups. The dyes are prepared by reacting a compound of formula:- <FORM:1017271/C4-C5/5> with an equimolar proportion of an acid halide or anhydride of an acid which contains a group capable of reaction with the hydroxyl groups of cellulose fibre to form a covalent bond. Dyes containing as group Q a radical of formula:- <FORM:1017271/C4-C5/6> are obtained by obtaining a dye of formula <FORM:1017271/C4-C5/7> with 2 moles of the acid halide or anhydride. The dyes may be used to colour natural and artificial textile materials such as wool, silk, polyamide, polyester and polyacrylonitrile fibres and especially cellulose fibres to which the dyes are applied in conjunction with an acid-binding agent. The dyes may also be applied together with a resin-forming composition as described in Specification 846,505. The preparation of the dyes if described in examples.
GB1926361A 1961-05-29 1961-05-29 New reactive dyestuffs containing triazine residues Expired GB1017271A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB1926361A GB1017271A (en) 1961-05-29 1961-05-29 New reactive dyestuffs containing triazine residues

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1926361A GB1017271A (en) 1961-05-29 1961-05-29 New reactive dyestuffs containing triazine residues

Publications (1)

Publication Number Publication Date
GB1017271A true GB1017271A (en) 1966-01-19

Family

ID=10126472

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1926361A Expired GB1017271A (en) 1961-05-29 1961-05-29 New reactive dyestuffs containing triazine residues

Country Status (1)

Country Link
GB (1) GB1017271A (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4447357A (en) * 1980-03-18 1984-05-08 Ciba-Geigy Corporation Fibre-reactive azo dyestuffs containing a halotriazinyl radical and a non-reactive triazinyl radical
US5059681A (en) * 1986-08-15 1991-10-22 Imperial Chemical Industries Plc Bis-azotriazinyl reactive dyes having an n-alkyl-phenylenediamine link
US5149790A (en) * 1988-12-02 1992-09-22 Imperial Chemical Industries Plc Bis chlorotriazine reactive dyes containing a benzylamine linking group
US5196033A (en) * 1986-08-15 1993-03-23 Imperial Chemical Industries Plc BIS-azotriazinyl reactive dyes having an N-alkyl-phenylenediamine link for cellulose textiles
US5269816A (en) * 1988-12-02 1993-12-14 Imperial Chemical Industries Plc Process for coloring textile materials
WO1994012717A1 (en) * 1992-11-27 1994-06-09 Zeneca Limited Dyes, their preparation and use in the coloration of substrates
US5328995A (en) * 1990-07-02 1994-07-12 Ciba-Geigy Corporation Azo dyes containing triazine middle components and a 1,4-phenylene-2,5-disubstituted coupling component
US5383960A (en) * 1992-03-06 1995-01-24 Zeneca Limited Ink jet printing inks
TR28127A (en) * 1992-11-27 1996-01-02 Zeneca Ltd Paints and painting processes.

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4447357A (en) * 1980-03-18 1984-05-08 Ciba-Geigy Corporation Fibre-reactive azo dyestuffs containing a halotriazinyl radical and a non-reactive triazinyl radical
US5059681A (en) * 1986-08-15 1991-10-22 Imperial Chemical Industries Plc Bis-azotriazinyl reactive dyes having an n-alkyl-phenylenediamine link
US5196033A (en) * 1986-08-15 1993-03-23 Imperial Chemical Industries Plc BIS-azotriazinyl reactive dyes having an N-alkyl-phenylenediamine link for cellulose textiles
US5149790A (en) * 1988-12-02 1992-09-22 Imperial Chemical Industries Plc Bis chlorotriazine reactive dyes containing a benzylamine linking group
US5269816A (en) * 1988-12-02 1993-12-14 Imperial Chemical Industries Plc Process for coloring textile materials
US5328995A (en) * 1990-07-02 1994-07-12 Ciba-Geigy Corporation Azo dyes containing triazine middle components and a 1,4-phenylene-2,5-disubstituted coupling component
US5383960A (en) * 1992-03-06 1995-01-24 Zeneca Limited Ink jet printing inks
WO1994012717A1 (en) * 1992-11-27 1994-06-09 Zeneca Limited Dyes, their preparation and use in the coloration of substrates
US5474580A (en) * 1992-11-27 1995-12-12 Zeneca Limited Chemical compounds
TR28127A (en) * 1992-11-27 1996-01-02 Zeneca Ltd Paints and painting processes.
US5703215A (en) * 1992-11-27 1997-12-30 Zeneca Limited Water-soluble dyes which are polymerizable containing molecules which contain a nucleophilic group and an electrophilic group

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