FR3114502A1 - Process for removing make-up from colored keratin materials using an aqueous composition containing a water-soluble salt of a monovalent or divalent cation. - Google Patents
Process for removing make-up from colored keratin materials using an aqueous composition containing a water-soluble salt of a monovalent or divalent cation. Download PDFInfo
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- FR3114502A1 FR3114502A1 FR2009931A FR2009931A FR3114502A1 FR 3114502 A1 FR3114502 A1 FR 3114502A1 FR 2009931 A FR2009931 A FR 2009931A FR 2009931 A FR2009931 A FR 2009931A FR 3114502 A1 FR3114502 A1 FR 3114502A1
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- 239000000203 mixture Substances 0.000 title claims abstract description 142
- 239000000463 material Substances 0.000 title claims abstract description 32
- 238000000034 method Methods 0.000 title claims abstract description 32
- 102000011782 Keratins Human genes 0.000 title claims abstract description 31
- 108010076876 Keratins Proteins 0.000 title claims abstract description 31
- 230000008569 process Effects 0.000 title claims abstract description 30
- 150000003839 salts Chemical class 0.000 title claims abstract description 22
- 150000001768 cations Chemical class 0.000 title claims abstract description 18
- 239000008346 aqueous phase Substances 0.000 claims abstract description 33
- 238000004140 cleaning Methods 0.000 claims abstract description 9
- 239000000980 acid dye Substances 0.000 claims abstract description 8
- 239000000975 dye Substances 0.000 claims description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 24
- -1 BROMOTHYLOL BLUE Chemical compound 0.000 claims description 19
- 239000002253 acid Substances 0.000 claims description 16
- 239000000982 direct dye Substances 0.000 claims description 14
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 12
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 11
- 239000003349 gelling agent Substances 0.000 claims description 10
- 239000003021 water soluble solvent Substances 0.000 claims description 10
- 229920005862 polyol Polymers 0.000 claims description 9
- 150000003077 polyols Chemical class 0.000 claims description 9
- 239000002904 solvent Substances 0.000 claims description 9
- 239000000341 volatile oil Substances 0.000 claims description 9
- HMEKVHWROSNWPD-UHFFFAOYSA-N Erioglaucine A Chemical compound [NH4+].[NH4+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 HMEKVHWROSNWPD-UHFFFAOYSA-N 0.000 claims description 8
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 claims description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 8
- CEZCCHQBSQPRMU-UHFFFAOYSA-L chembl174821 Chemical compound [Na+].[Na+].COC1=CC(S([O-])(=O)=O)=C(C)C=C1N=NC1=C(O)C=CC2=CC(S([O-])(=O)=O)=CC=C12 CEZCCHQBSQPRMU-UHFFFAOYSA-L 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 239000011575 calcium Substances 0.000 claims description 7
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 claims description 6
- 150000004056 anthraquinones Chemical class 0.000 claims description 6
- 125000004429 atom Chemical group 0.000 claims description 6
- 239000011777 magnesium Substances 0.000 claims description 6
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 6
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 6
- 239000002736 nonionic surfactant Substances 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- 239000011780 sodium chloride Substances 0.000 claims description 6
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 claims description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- 230000003165 hydrotropic effect Effects 0.000 claims description 5
- 229910052708 sodium Inorganic materials 0.000 claims description 5
- UJMBCXLDXJUMFB-GLCFPVLVSA-K tartrazine Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-GLCFPVLVSA-K 0.000 claims description 5
- 150000003732 xanthenes Chemical class 0.000 claims description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 4
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 4
- UCMIRNVEIXFBKS-UHFFFAOYSA-N beta-alanine Chemical compound NCCC(O)=O UCMIRNVEIXFBKS-UHFFFAOYSA-N 0.000 claims description 4
- 235000012745 brilliant blue FCF Nutrition 0.000 claims description 4
- 239000004161 brilliant blue FCF Substances 0.000 claims description 4
- 229910052791 calcium Inorganic materials 0.000 claims description 4
- PZTQVMXMKVTIRC-UHFFFAOYSA-L chembl2028348 Chemical compound [Ca+2].[O-]S(=O)(=O)C1=CC(C)=CC=C1N=NC1=C(O)C(C([O-])=O)=CC2=CC=CC=C12 PZTQVMXMKVTIRC-UHFFFAOYSA-L 0.000 claims description 4
- 150000002334 glycols Chemical class 0.000 claims description 4
- 229910052749 magnesium Inorganic materials 0.000 claims description 4
- 230000003020 moisturizing effect Effects 0.000 claims description 4
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 claims description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 3
- FENRSEGZMITUEF-ATTCVCFYSA-E [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].OP(=O)([O-])O[C@@H]1[C@@H](OP(=O)([O-])[O-])[C@H](OP(=O)(O)[O-])[C@H](OP(=O)([O-])[O-])[C@H](OP(=O)(O)[O-])[C@H]1OP(=O)([O-])[O-] Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].OP(=O)([O-])O[C@@H]1[C@@H](OP(=O)([O-])[O-])[C@H](OP(=O)(O)[O-])[C@H](OP(=O)([O-])[O-])[C@H](OP(=O)(O)[O-])[C@H]1OP(=O)([O-])[O-] FENRSEGZMITUEF-ATTCVCFYSA-E 0.000 claims description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 3
- 230000000887 hydrating effect Effects 0.000 claims description 3
- 229940083982 sodium phytate Drugs 0.000 claims description 3
- FTUYQIPAPWPHNC-UHFFFAOYSA-M sodium;4-[[4-[benzyl(ethyl)amino]phenyl]-[4-[benzyl(ethyl)azaniumylidene]cyclohexa-2,5-dien-1-ylidene]methyl]benzene-1,3-disulfonate Chemical compound [Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=CC=CC=2)C=2C(=CC(=CC=2)S([O-])(=O)=O)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC=C1 FTUYQIPAPWPHNC-UHFFFAOYSA-M 0.000 claims description 3
- 235000012756 tartrazine Nutrition 0.000 claims description 3
- 239000004149 tartrazine Substances 0.000 claims description 3
- KIUKXJAPPMFGSW-DNGZLQJQSA-N (2S,3S,4S,5R,6R)-6-[(2S,3R,4R,5S,6R)-3-Acetamido-2-[(2S,3S,4R,5R,6R)-6-[(2R,3R,4R,5S,6R)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylic acid Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 KIUKXJAPPMFGSW-DNGZLQJQSA-N 0.000 claims description 2
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 2
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 claims description 2
- 239000004471 Glycine Substances 0.000 claims description 2
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 claims description 2
- 229910052783 alkali metal Inorganic materials 0.000 claims description 2
- 150000001340 alkali metals Chemical class 0.000 claims description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 2
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 2
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 claims description 2
- 229910052788 barium Inorganic materials 0.000 claims description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 2
- 229940000635 beta-alanine Drugs 0.000 claims description 2
- 239000004202 carbamide Substances 0.000 claims description 2
- 229960002449 glycine Drugs 0.000 claims description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 2
- 229920002674 hyaluronan Polymers 0.000 claims description 2
- 229960003160 hyaluronic acid Drugs 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 229910052712 strontium Inorganic materials 0.000 claims description 2
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 2
- 229960003080 taurine Drugs 0.000 claims description 2
- FPAYXBWMYIMERV-UHFFFAOYSA-L disodium;5-methyl-2-[[4-(4-methyl-2-sulfonatoanilino)-9,10-dioxoanthracen-1-yl]amino]benzenesulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1NC(C=1C(=O)C2=CC=CC=C2C(=O)C=11)=CC=C1NC1=CC=C(C)C=C1S([O-])(=O)=O FPAYXBWMYIMERV-UHFFFAOYSA-L 0.000 claims 8
- OIQPTROHQCGFEF-UHFFFAOYSA-L chembl1371409 Chemical compound [Na+].[Na+].OC1=CC=C2C=C(S([O-])(=O)=O)C=CC2=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 OIQPTROHQCGFEF-UHFFFAOYSA-L 0.000 claims 6
- ONTQJDKFANPPKK-UHFFFAOYSA-L chembl3185981 Chemical compound [Na+].[Na+].CC1=CC(C)=C(S([O-])(=O)=O)C=C1N=NC1=CC(S([O-])(=O)=O)=C(C=CC=C2)C2=C1O ONTQJDKFANPPKK-UHFFFAOYSA-L 0.000 claims 6
- LQJVOKWHGUAUHK-UHFFFAOYSA-L disodium 5-amino-4-hydroxy-3-phenyldiazenylnaphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].OC1=C2C(N)=CC(S([O-])(=O)=O)=CC2=CC(S([O-])(=O)=O)=C1N=NC1=CC=CC=C1 LQJVOKWHGUAUHK-UHFFFAOYSA-L 0.000 claims 6
- GTKIEPUIFBBXJQ-UHFFFAOYSA-M sodium;2-[(4-hydroxy-9,10-dioxoanthracen-1-yl)amino]-5-methylbenzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1NC1=CC=C(O)C2=C1C(=O)C1=CC=CC=C1C2=O GTKIEPUIFBBXJQ-UHFFFAOYSA-M 0.000 claims 6
- GVKCHTBDSMQENH-UHFFFAOYSA-L phloxine B Chemical compound [Na+].[Na+].[O-]C(=O)C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1C1=C2C=C(Br)C(=O)C(Br)=C2OC2=C(Br)C([O-])=C(Br)C=C21 GVKCHTBDSMQENH-UHFFFAOYSA-L 0.000 claims 5
- RZSYLLSAWYUBPE-UHFFFAOYSA-L Fast green FCF Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC(O)=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 RZSYLLSAWYUBPE-UHFFFAOYSA-L 0.000 claims 4
- SEACYXSIPDVVMV-UHFFFAOYSA-L eosin Y Chemical compound [Na+].[Na+].[O-]C(=O)C1=CC=CC=C1C1=C2C=C(Br)C(=O)C(Br)=C2OC2=C(Br)C([O-])=C(Br)C=C21 SEACYXSIPDVVMV-UHFFFAOYSA-L 0.000 claims 4
- CQPFMGBJSMSXLP-UHFFFAOYSA-M acid orange 7 Chemical compound [Na+].OC1=CC=C2C=CC=CC2=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 CQPFMGBJSMSXLP-UHFFFAOYSA-M 0.000 claims 3
- 229940099540 acid violet 43 Drugs 0.000 claims 3
- RYCIBGACBRAXBM-UHFFFAOYSA-N 3',6'-dihydroxy-4',5'-dinitrospiro[2-benzofuran-3,9'-xanthene]-1-one Chemical compound O1C(=O)C2=CC=CC=C2C21C(C=CC(O)=C1[N+]([O-])=O)=C1OC1=C([N+]([O-])=O)C(O)=CC=C21 RYCIBGACBRAXBM-UHFFFAOYSA-N 0.000 claims 2
- CQPFMGBJSMSXLP-ZAGWXBKKSA-M Acid orange 7 Chemical compound OC1=C(C2=CC=CC=C2C=C1)/N=N/C1=CC=C(C=C1)S(=O)(=O)[O-].[Na+] CQPFMGBJSMSXLP-ZAGWXBKKSA-M 0.000 claims 2
- WLDHEUZGFKACJH-UHFFFAOYSA-K amaranth Chemical compound [Na+].[Na+].[Na+].C12=CC=C(S([O-])(=O)=O)C=C2C=C(S([O-])(=O)=O)C(O)=C1N=NC1=CC=C(S([O-])(=O)=O)C2=CC=CC=C12 WLDHEUZGFKACJH-UHFFFAOYSA-K 0.000 claims 2
- WXLFIFHRGFOVCD-UHFFFAOYSA-L azophloxine Chemical compound [Na+].[Na+].OC1=C2C(NC(=O)C)=CC(S([O-])(=O)=O)=CC2=CC(S([O-])(=O)=O)=C1N=NC1=CC=CC=C1 WXLFIFHRGFOVCD-UHFFFAOYSA-L 0.000 claims 2
- JBBPTUVOZCXCSU-UHFFFAOYSA-L dipotassium;2',4',5',7'-tetrabromo-4,7-dichloro-3-oxospiro[2-benzofuran-1,9'-xanthene]-3',6'-diolate Chemical compound [K+].[K+].O1C(=O)C(C(=CC=C2Cl)Cl)=C2C21C1=CC(Br)=C([O-])C(Br)=C1OC1=C(Br)C([O-])=C(Br)C=C21 JBBPTUVOZCXCSU-UHFFFAOYSA-L 0.000 claims 2
- DLMKCDGEDBPAFO-UHFFFAOYSA-L disodium 3-[[4-[1-[4-[[7-(benzenesulfonyloxy)-1-hydroxy-3-sulfonatonaphthalen-2-yl]diazenyl]phenyl]cyclohexyl]phenyl]diazenyl]-4,6-dihydroxynaphthalene-2-sulfonate Chemical compound OC1=C(C(=CC2=CC=C(C=C12)O)S(=O)(=O)[O-])N=NC1=CC=C(C=C1)C1(CCCCC1)C1=CC=C(C=C1)N=NC1=C(C2=CC(=CC=C2C=C1S(=O)(=O)[O-])OS(=O)(=O)C1=CC=CC=C1)O.[Na+].[Na+] DLMKCDGEDBPAFO-UHFFFAOYSA-L 0.000 claims 2
- AOMZHDJXSYHPKS-UHFFFAOYSA-L disodium 4-amino-5-hydroxy-3-[(4-nitrophenyl)diazenyl]-6-phenyldiazenylnaphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC2=CC(S([O-])(=O)=O)=C(N=NC=3C=CC=CC=3)C(O)=C2C(N)=C1N=NC1=CC=C([N+]([O-])=O)C=C1 AOMZHDJXSYHPKS-UHFFFAOYSA-L 0.000 claims 2
- IVKWXPBUMQZFCW-UHFFFAOYSA-L disodium;2-(2,4,5,7-tetraiodo-3-oxido-6-oxoxanthen-9-yl)benzoate;hydrate Chemical compound O.[Na+].[Na+].[O-]C(=O)C1=CC=CC=C1C1=C2C=C(I)C(=O)C(I)=C2OC2=C(I)C([O-])=C(I)C=C21 IVKWXPBUMQZFCW-UHFFFAOYSA-L 0.000 claims 2
- INPXKEACWBDDSB-UHFFFAOYSA-L disodium;2-(4,5-diiodo-3-oxido-6-oxoxanthen-9-yl)benzoate Chemical compound [Na+].[Na+].[O-]C(=O)C1=CC=CC=C1C1=C2C=CC(=O)C(I)=C2OC2=C(I)C([O-])=CC=C21 INPXKEACWBDDSB-UHFFFAOYSA-L 0.000 claims 2
- FPVGTPBMTFTMRT-UHFFFAOYSA-L disodium;2-amino-5-[(4-sulfonatophenyl)diazenyl]benzenesulfonate Chemical compound [Na+].[Na+].C1=C(S([O-])(=O)=O)C(N)=CC=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 FPVGTPBMTFTMRT-UHFFFAOYSA-L 0.000 claims 2
- VQHWSAGRWJWMCJ-UHFFFAOYSA-K disodium;4-chloro-2-methyl-6-[(3-methyl-5-oxo-1-phenylpyrazol-2-id-4-yl)diazenyl]phenolate;chromium(3+);hydron Chemical compound [H+].[Na+].[Na+].[Cr+3].O=C1C(N=NC=2C(=C(C)C=C(Cl)C=2)[O-])=C(C)[N-]N1C1=CC=CC=C1.O=C1C(N=NC=2C(=C(C)C=C(Cl)C=2)[O-])=C(C)[N-]N1C1=CC=CC=C1 VQHWSAGRWJWMCJ-UHFFFAOYSA-K 0.000 claims 2
- 235000019240 fast green FCF Nutrition 0.000 claims 2
- GNBHRKFJIUUOQI-UHFFFAOYSA-N fluorescein Chemical compound O1C(=O)C2=CC=CC=C2C21C1=CC=C(O)C=C1OC1=CC(O)=CC=C21 GNBHRKFJIUUOQI-UHFFFAOYSA-N 0.000 claims 2
- WDPIZEKLJKBSOZ-UHFFFAOYSA-M green s Chemical compound [Na+].C1=CC(N(C)C)=CC=C1C(C=1C2=CC=C(C=C2C=C(C=1O)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](C)C)C=C1 WDPIZEKLJKBSOZ-UHFFFAOYSA-M 0.000 claims 2
- SXQCTESRRZBPHJ-UHFFFAOYSA-M lissamine rhodamine Chemical compound [Na+].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=C(S([O-])(=O)=O)C=C1S([O-])(=O)=O SXQCTESRRZBPHJ-UHFFFAOYSA-M 0.000 claims 2
- CTIQLGJVGNGFEW-UHFFFAOYSA-L naphthol yellow S Chemical compound [Na+].[Na+].C1=C(S([O-])(=O)=O)C=C2C([O-])=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 CTIQLGJVGNGFEW-UHFFFAOYSA-L 0.000 claims 2
- LGZQSRCLLIPAEE-UHFFFAOYSA-M sodium 1-[(4-sulfonaphthalen-1-yl)diazenyl]naphthalen-2-olate Chemical compound [Na+].C1=CC=C2C(N=NC3=C4C=CC=CC4=CC=C3O)=CC=C(S([O-])(=O)=O)C2=C1 LGZQSRCLLIPAEE-UHFFFAOYSA-M 0.000 claims 2
- COEZWFYORILMOM-UHFFFAOYSA-M sodium 4-[(2,4-dihydroxyphenyl)diazenyl]benzenesulfonate Chemical compound [Na+].OC1=CC(O)=CC=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 COEZWFYORILMOM-UHFFFAOYSA-M 0.000 claims 2
- UWMZZSRDUVJJDP-UHFFFAOYSA-N sodium 4-[[9-(2-carboxyphenyl)-6-(2-methylanilino)xanthen-10-ium-3-yl]amino]-3-methylbenzenesulfonate Chemical compound [Na+].Cc1ccccc1Nc1ccc2c(-c3ccccc3C(O)=O)c3ccc(Nc4ccc(cc4C)S([O-])(=O)=O)cc3[o+]c2c1 UWMZZSRDUVJJDP-UHFFFAOYSA-N 0.000 claims 2
- DJDYMAHXZBQZKH-UHFFFAOYSA-M sodium;1-amino-4-(cyclohexylamino)-9,10-dioxoanthracene-2-sulfonate Chemical compound [Na+].C1=2C(=O)C3=CC=CC=C3C(=O)C=2C(N)=C(S([O-])(=O)=O)C=C1NC1CCCCC1 DJDYMAHXZBQZKH-UHFFFAOYSA-M 0.000 claims 2
- AYQGOOLZDOHXAY-UHFFFAOYSA-M sodium;3-[[4-[(2-chlorophenyl)-[4-[ethyl-[(3-sulfonatophenyl)methyl]azaniumylidene]-2-methylcyclohexa-2,5-dien-1-ylidene]methyl]-n-ethyl-3-methylanilino]methyl]benzenesulfonate Chemical compound [Na+].C=1C=C(\C(=C\2C(=CC(C=C/2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C)C=2C(=CC=CC=2)Cl)C(C)=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 AYQGOOLZDOHXAY-UHFFFAOYSA-M 0.000 claims 2
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- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- 230000005489 elastic deformation Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 210000000744 eyelid Anatomy 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 150000002306 glutamic acid derivatives Chemical class 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229940031575 hydroxyethyl urea Drugs 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 125000003010 ionic group Chemical group 0.000 description 1
- KUVMKLCGXIYSNH-UHFFFAOYSA-N isopentadecane Natural products CCCCCCCCCCCCC(C)C KUVMKLCGXIYSNH-UHFFFAOYSA-N 0.000 description 1
- 229940102253 isopropanolamine Drugs 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 150000003893 lactate salts Chemical class 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 229940031674 laureth-7 Drugs 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 150000005677 organic carbonates Chemical class 0.000 description 1
- 230000003534 oscillatory effect Effects 0.000 description 1
- 235000019161 pantothenic acid Nutrition 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 235000002949 phytic acid Nutrition 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- DQAKJEWZWDQURW-UHFFFAOYSA-N pyrrolidonecarboxylic acid Chemical class OC(=O)N1CCCC1=O DQAKJEWZWDQURW-UHFFFAOYSA-N 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- UIIMBOGNXHQVGW-UHFFFAOYSA-N sodium;hydron;carbonate Chemical compound [Na+].OC(O)=O UIIMBOGNXHQVGW-UHFFFAOYSA-N 0.000 description 1
- 229950004959 sorbitan oleate Drugs 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 235000010356 sorbitol Nutrition 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 229960004418 trolamine Drugs 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/20—Halogens; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/23—Sulfur; Selenium; Tellurium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/14—Preparations for removing make-up
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
- A61K2800/432—Direct dyes
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
Abstract
Titre de l’invention : Procédé de démaquillage de matières kératiniques colorées au moyen d’une composition aqueuse contenant un sel hydrosoluble de cation monovalent ou divalent. La présente demande se rapporte à un procédé de démaquillage et/ou de nettoyage de matières kératiniques colorées, de préférence la peau colorée, comprenant :- l’application sur des matières kératiniques d’une composition (A) comprenant au moins, de préférence dans un milieu physiologiquement acceptable, une phase aqueuse comprenant au moins un colorant direct acide et - l’application sur lesdites matières kératiniques colorées d’une composition (B) démaquillante, comprenant au moins, de préférence dans un milieu physiologiquement acceptable, une phase aqueuse comprenant au moins un sel hydrosoluble de cation monovalent ou divalent.Title of the invention: Process for removing make-up from colored keratin materials using an aqueous composition containing a water-soluble salt of a monovalent or divalent cation. The present application relates to a process for removing make-up and/or cleaning colored keratin materials, preferably colored skin, comprising:- the application to keratin materials of a composition (A) comprising at least, preferably in a physiologically acceptable medium, an aqueous phase comprising at least one direct acid dye and - the application to said colored keratin materials of a makeup-removing composition (B), comprising at least, preferably in a physiologically acceptable medium, an aqueous phase comprising at least one water-soluble salt of monovalent or divalent cation.
Description
La présente invention concerne un procédé cosmétique de démaquillage et/ou de nettoyage de matières kératiniques colorées, de préférence de la peau, comprenant l’application sur des matières kératiniques, d’une composition de maquillage aqueuse comprenant au moins un colorant direct acide et l’application sur lesdites matières kératiniques colorées d’une composition démaquillante comprenant une phase aqueuse contenant au moins un sel hydrosoluble de cation monovalent ou divalent.The present invention relates to a cosmetic process for removing make-up and/or cleaning colored keratin materials, preferably the skin, comprising the application to keratin materials of an aqueous make-up composition comprising at least one acid direct dye and the application to said colored keratin materials of a makeup-removing composition comprising an aqueous phase containing at least one water-soluble salt of a monovalent or divalent cation.
L’offre des produits de maquillage semi permanents est de plus en plus importante : il s’agit de compositions aqueuses à base de colorants acides directs qui colorent les matières kératiniques comme la peau en faisant pénétrer lesdits colorants dans le stratum cornéum avec des solvants pro pénétrants. Cependant ces produits nécessitent une maitrise de l’application pour avoir un geste précis et ne permettent pas les corrections ou les retouches en cas de débordements.The offer of semi-permanent make-up products is increasingly important: these are aqueous compositions based on direct acid dyes which color keratin materials such as the skin by causing said dyes to penetrate into the stratum corneum with professional solvents. penetrating. However, these products require mastery of the application to have a precise gesture and do not allow corrections or touch-ups in the event of overflows.
En effet, la couleur sur la peau est apportée par les colorants qui sont dans le stratum cornéum. A l’inverse de produits de maquillage classiques qui colorent la peau avec un dépôt de matière à la surface de la peau, les produits semi permanents sont très confortables car ils ne laissent pas de dépôt en surface de la peau. Mais lorsque que le colorant a pénétré dans la matière kératinique, il devient tenace et par conséquent difficile à retirer : il faut bien frotter ou beaucoup de temps au risque de s’irriter la peau par les frottements répétés du coton ou parfois d’étaler sous forme de tache hétérogène la coloration sur la peau plutôt que de la retirer.Indeed, the color on the skin is brought by the dyes which are in the stratum corneum. Unlike conventional make-up products that color the skin with a deposit of matter on the surface of the skin, semi-permanent products are very comfortable because they do not leave a deposit on the surface of the skin. But when the dye has penetrated into the keratinous material, it becomes tenacious and therefore difficult to remove: it is necessary to rub well or for a long time at the risk of irritating the skin by the repeated rubbing of the cotton or sometimes to spread under heterogeneous patch forms the coloring on the skin rather than removing it.
Il subsiste un besoin de trouver de nouvelles formulations de démaquillage pour des produits de maquillage semi permanent à base de colorants directs acides.There remains a need to find new make-up removal formulations for semi-permanent make-up products based on direct acid dyes.
L’objectif recherché est d’offrir à la consommatrice un produit de démaquillage qui lui permettra de retirer quand elle le souhaite un produit de maquillage semi permanent qui tient plusieurs jours soit parce qu’elle a fait une erreur soit parce qu’elle souhaite changer de look en modifiant la teinte ou la forme du contour.The desired objective is to offer the consumer a make-up removal product which will enable her to remove, when she wishes, a semi-permanent make-up product which lasts for several days, either because she has made a mistake or because she wishes to change look by modifying the shade or shape of the outline.
La demanderesse a découvert de manière surprenante que cet objectif pouvait être atteint avec un procédé de démaquillage et/ou de nettoyage des matières kératiniques colorées, de préférence la peau colorée, comprenant :
- l’application sur des matières kératiniques d’une composition de maquillage (A) comprenant une phase aqueuse comprenant au moins un colorant direct acide et
- l’application sur les matières kératiniques colorées d’une composition comprenant une phase aqueuse comprenant au moins un sel hydrosoluble de cation monovalent ou divalent à une concentration supérieure ou égale à 0,5% en poids par rapport au poids total de la composition (B).The Applicant has discovered, surprisingly, that this objective could be achieved with a process for removing make-up and/or for cleaning colored keratin materials, preferably colored skin, comprising:
- the application to keratin materials of a makeup composition (A) comprising an aqueous phase comprising at least one acid direct dye and
- the application to the colored keratin materials of a composition comprising an aqueous phase comprising at least one water-soluble salt of a monovalent or divalent cation at a concentration greater than or equal to 0.5% by weight relative to the total weight of the composition ( B).
Le procédé de l’invention de démaquillage et/ou de nettoyage des matières kératiniques colorées, de préférence la peau colorée, permet de retirer efficacement les colorants directs acides qui ont diffusé dans lesdites matières kératiniques sans pour autant étaler la tâche de colorant sur toute la surface desdites matières kératiniques.The method of the invention for removing make-up and/or cleaning colored keratin materials, preferably colored skin, makes it possible to effectively remove the direct acid dyes which have diffused into said keratin materials without however spreading the stain of dye over the entire skin. surface of said keratin materials.
Cette découverte est la base de l’invention.This discovery is the basis of the invention.
Objets de l’inventionObjects of the invention
Ainsi, un premier objet de la présente invention est un procédé de démaquillage et/ou de nettoyage de matières kératiniques colorées, de préférence de la peau colorée, comprenant :
- l’application sur des matières kératiniques d’une composition (A) comprenant au moins, de préférence dans un milieu physiologiquement acceptable, une phase aqueuse comprenant au moins un colorant direct acide et
- l’application sur lesdites matières kératiniques colorées d’une composition (B), comprenant au moins, de préférence dans un milieu physiologiquement acceptable, une phase aqueuse comprenant au moins un sel hydrosoluble de cation monovalent ou divalent à une concentration supérieure ou égale à 0,5% en poids par rapport au poids total de la composition (B).Thus, a first object of the present invention is a process for removing make-up and/or cleaning colored keratin materials, preferably colored skin, comprising:
- the application to keratin materials of a composition (A) comprising at least, preferably in a physiologically acceptable medium, an aqueous phase comprising at least one acid direct dye and
- the application to said colored keratin materials of a composition (B), comprising at least, preferably in a physiologically acceptable medium, an aqueous phase comprising at least one water-soluble salt of a monovalent or divalent cation at a concentration greater than or equal to 0.5% by weight relative to the total weight of composition (B).
Un deuxième objet de la présente invention est un kit de maquillage et de démaquillage et/ou de nettoyage de matières kératiniques colorées, de préférence de la peau colorée , comprenant au moins :
a) une première composition (A) de maquillage telle que définie précédemment et
b) une deuxième composition (B) démaquillante telle que définie précédemment.A second object of the present invention is a kit for making up and removing make-up and/or cleaning colored keratin materials, preferably colored skin, comprising at least:
a) a first make-up composition (A) as defined previously and
b) a second makeup-removing composition (B) as defined previously.
L’invention concerne également l’utilisation d’une composition (B) telle que définie précédemment pour le démaquillage et/ou le nettoyage de matières kératiniques colorées, de préférence de la peau colorée par une composition (A) telle que définie précédemment.The invention also relates to the use of a composition (B) as defined above for removing make-up and/or cleansing colored keratin materials, preferably skin colored with a composition (A) as defined above.
DéfinitionsDefinitions
Dans le cadre de la présente invention, on entend notamment par « matières kératiniques », la peau (ie : visage, corps, paupières, contour des yeux), les fibres kératiniques telles que les cils et les sourcils, et plus particulièrement la peau.In the context of the present invention, the term “keratin materials” is understood to mean in particular the skin (ie: face, body, eyelids, eye contour), keratin fibers such as the eyelashes and the eyebrows, and more particularly the skin.
Par « matières kératiniques colorées », on entend celles qui ont été définies précédemment et qui ont été colorées artificiellement par une composition de coloration des matières kératiniques, notamment par une composition de maquillage des matières kératiniques.By “dyed keratin materials”, is meant those which have been defined above and which have been artificially colored by a composition for coloring keratin materials, in particular by a makeup composition for keratin materials.
Par "physiologiquement acceptable", on entend compatible avec la peau et ses phanères, qui présente une couleur, une odeur et un toucher agréables et qui ne génère pas d'inconforts inacceptables (picotements, tiraillements), susceptibles de détourner la consommatrice d'utiliser cette composition.By "physiologically acceptable" is meant compatible with the skin and its appendages, which has a pleasant color, smell and touch and which does not cause unacceptable discomfort (tingling, tightness), likely to deter the consumer from using this composition.
Composition de maquillage (A)Make-up composition (A)
Selon la présente invention, la composition (A) de maquillage semi-permanent, comprend au moins une phase aqueuse contenant au moins un colorant direct acide.
Colorant direct acide According to the present invention, semi-permanent makeup composition (A) comprises at least one aqueous phase containing at least one acidic direct dye.
Acid Direct Dye
Une composition (A) conforme à l’invention comporte au moins un colorant direct acide.A composition (A) in accordance with the invention comprises at least one acid direct dye.
Par « colorant direct acide », on entend un colorant acide qui est présent sous forme libre dans la composition. En particulier, il n’est pas supporté par un support, tel que l’alumine. Ainsi, de préférence, le colorant direct acide est solubilisé dans la phase aqueuse.By "direct acid dye" is meant an acid dye which is present in the free form in the composition. In particular, it is not supported by a support, such as alumina. Thus, preferably, the acid direct dye is dissolved in the aqueous phase.
Notamment, le colorant direct acide est différent d’une laque.In particular, the acid direct dye is different from a lacquer.
En outre, il est compatible avec une application autour/sur les yeux.In addition, it is compatible with an application around/on the eyes.
Le colorant direct acide est avantageusement présent une teneur totale comprise de 0,1 à 10% en poids, mieux de 0,1 à 5% en poids par rapport au poids total de la composition(A).The acid direct dye is advantageously present in a total content of from 0.1 to 10% by weight, better still from 0.1 to 5% by weight relative to the total weight of composition (A) .
Il est choisi parmi les colorants présentant un noyau anthraquinone, azine, azoïque, polyméthine, triarylméthane ou xanthène, et les colorants comprenant au moins un groupe –NO2.It is chosen from dyes having an anthraquinone, azine, azo, polymethine, triarylmethane or xanthene nucleus, and dyes comprising at least one –NO 2 group.
Les colorants présentant un noyau anthraquinone sont de préférence ceux de formules suivantes :The dyes having an anthraquinone nucleus are preferably those of the following formulas:
Le colorant présentant un noyau azine est de préférence celui de formule suivante :The dye having an azine nucleus is preferably that of the following formula:
Les colorants présentant un noyau azoïque sont de préférence ceux de formules suivantes :The dyes having an azo nucleus are preferably those of the following formulas:
Le colorant présentant un noyau polyméthine est de préférence celui de formule suivante :The dye having a polymethine nucleus is preferably that of the following formula:
Les colorants présentant un noyau triarylméthane sont de préférence ceux de formules suivantes :The dyes having a triarylmethane nucleus are preferably those of the following formulas:
Les colorants présentant un noyau xanthène sont de préférence ceux de formules suivantes :The dyes having a xanthene nucleus are preferably those of the following formulas:
Enfin, le colorant comprenant au moins un groupe –NO2est de préférence celui de formule suivante :Finally, the dye comprising at least one –NO 2 group is preferably that of the following formula:
De préférence, le colorant est choisi parmi les colorants présentant un noyau anthraquinone, azoïque, triarylméthane ou xanthène.Preferably, the dye is chosen from dyes having an anthraquinone, azo, triarylmethane or xanthene nucleus.
De préférence, le colorant est choisi parmi :Preferably, the dye is chosen from:
et leurs mélanges.
and their mixtures.
De préférence, le colorant est choisi parmi les colorants présentant un noyau anthraquinone, azoïque ou triarylméthane.Preferably, the dye is chosen from dyes having an anthraquinone, azo or triarylmethane nucleus.
Plus préférentiellement, de tels colorants sont décrits ci-dessus.More preferably, such dyes are described above.
De préférence, le colorant est choisi parmi :Preferably, the dye is chosen from:
et leurs mélanges.
and their mixtures.
Outre les composés décrits ci-dessus, la composition (A) selon l’invention peut également comprendre les différents ingrédients tels que décrits ci-après.
Phase aqueuse In addition to the compounds described above, composition (A) according to the invention may also comprise the various ingredients as described below.
Aqueous phase
La composition (A) de maquillage selon l’invention comprend une phase aqueuse, de préférence, qui peut former une phase continue de la composition.The make-up composition (A) according to the invention preferably comprises an aqueous phase, which can form a continuous phase of the composition.
De préférence, la composition (A) selon l'invention comprend une phase aqueuse continue. Par composition à phase aqueuse « continue », on entend que la composition présente une conductivité, mesurée à 25°C, supérieure à 23 µS/cm (microSiemens/cm), la conductivité étant mesurée par exemple à l'aide d'un conductimètre MPC227® de Mettler Toledo et d'une cellule de mesure de conductivité Inlab730®. La cellule de mesure est immergée dans la composition, de façon à éliminer les bulles d'air susceptibles de se former entre les deux électrodes de la cellule. La lecture de la conductivité est faite dès que la valeur du conductimètre est stabilisée. Une moyenne est réalisée sur au moins trois mesures successives.Preferably, composition (A) according to the invention comprises a continuous aqueous phase. By “continuous” aqueous phase composition, it is meant that the composition has a conductivity, measured at 25° C., greater than 23 μS/cm (microSiemens/cm), the conductivity being measured for example using a conductivity meter MPC227® from Mettler Toledo and an Inlab730® conductivity measuring cell. The measurement cell is immersed in the composition, so as to eliminate the air bubbles liable to form between the two electrodes of the cell. The conductivity reading is taken as soon as the conductivity meter value has stabilized. An average is calculated over at least three successive measurements.
La phase aqueuse comprend de l’eau. Elle peut également comprendre au moins un solvant hydrosoluble.The aqueous phase includes water. It can also comprise at least one water-soluble solvent.
Par "solvant hydrosoluble", on désigne dans la présente invention un composé liquide à température ambiante et miscible à l’eau.By “water-soluble solvent”, is meant in the present invention a compound that is liquid at room temperature and miscible with water.
Les solvants hydrosolubles utilisables dans les compositions selon l’invention peuvent en outre être volatils.The water-soluble solvents that can be used in the compositions according to the invention can also be volatile.
Parmi les solvants hydrosolubles pouvant être utilisés dans les compositions conformes à l’invention, on peut citer notamment les mono-alcools inférieurs ayant de 1 à 5 atomes de carbone tels que l’éthanol et l’isopropanol, les glycols ayant de 3 à 8 atomes de carbone tels que le propylène glycol, le 1,3-butylène glycol et le dipropylène glycol, et leurs mélangesAmong the water-soluble solvents which can be used in the compositions in accordance with the invention, mention may in particular be made of lower mono-alcohols having from 1 to 5 carbon atoms, such as ethanol and isopropanol, glycols having from 3 to 8 carbon atoms such as propylene glycol, 1,3-butylene glycol and dipropylene glycol, and mixtures thereof
L’eau est de préférence présente dans la composition (A) selon la présente demande en une teneur supérieure ou égale à 70 % en poids, plus préférentiellement allant de 75 à 98 % en poids, en particulier allant de 80 à 95 % en poids par rapport au poids total de la composition (A). Cette teneur en phase aqueuse inclut non seulement l’eau délibérément ajoutée à la composition, mais aussi l’eau éventuellement amenée par d’autres ingrédients.The water is preferably present in the composition (A) according to the present application in a content greater than or equal to 70% by weight, more preferably ranging from 75 to 98% by weight, in particular ranging from 80 to 95% by weight relative to the total weight of composition (A). This aqueous phase content includes not only the water deliberately added to the composition, but also the water possibly brought in by other ingredients.
La phase aqueuse (eau et éventuellement le solvant miscible à l'eau) est de préférence présente dans la composition selon la présente demande en une teneur supérieure ou égale à 70 % en poids, plus préférentiellement allant de 75 à 98 % en poids, en particulier allant de 80 à 95 % en poids par rapport au poids total de la composition (A).The aqueous phase (water and optionally the water-miscible solvent) is preferably present in the composition according to the present application in a content greater than or equal to 70% by weight, more preferably ranging from 75 to 98% by weight, in particular ranging from 80 to 95% by weight relative to the total weight of composition (A).
Le pH de la composition (A) de maquillage selon l’invention est de préférence inférieur à 6, plus préférentiellement inférieur à 5, et mieux encore allant de 2 à 4,5.The pH of the makeup composition (A) according to the invention is preferably less than 6, more preferably less than 5, and better still ranging from 2 to 4.5.
Le pH peut être obtenu et/ou ajusté classiquement par ajout d'agents alcalins, tels que l'ammoniaque, la monoéthanolamine, la diéthanolamine, la triéthanolamine, l'isopropanolamine, le 2-amino 2-méthyl 1-propanol, la propanediamine-1,3, un carbonate ou un bicarbonate alcalin ou d'ammonium, par exemple la bicarbonate de sodium, un carbonate organique tel que le carbonate de guanidine, ou bien encore un hydroxyde alcalin comme la soude ou la potasse, tous ces composés pouvant bien entendu être pris seuls ou en mélange.The pH can be obtained and/or adjusted conventionally by adding alkaline agents, such as ammonia, monoethanolamine, diethanolamine, triethanolamine, isopropanolamine, 2-amino 2-methyl 1-propanol, propanediamine- 1,3, an alkaline or ammonium carbonate or bicarbonate, for example sodium bicarbonate, an organic carbonate such as guanidine carbonate, or even an alkaline hydroxide such as soda or potash, all these compounds possibly heard to be taken alone or in mixture.
On peut également utiliser pour l’obtention et/ou l’ajustement des agents acidifiants tels que l'acide chlorhydrique, l'acide acétique, l'acide lactique, l'acide borique, l’acide citrique et l’acide phosphorique.Acidifying agents such as hydrochloric acid, acetic acid, lactic acid, boric acid, citric acid and phosphoric acid can also be used for obtaining and/or adjusting.
On utilisera de préférence l’acide citrique et/ou la soude.
Gélifiant hydrophile Preferably, citric acid and/or sodium hydroxide will be used.
Hydrophilic gelling agent
Selon une forme particulière de l’invention, la composition (A) de maquillage selon l’invention comprend en plus un ou plusieurs gélifiant(s) hydrophile(s).According to a particular form of the invention, the makeup composition (A) according to the invention also comprises one or more hydrophilic gelling agent(s).
On entend par "gélifiant hydrophile" au sens de la présente invention, un composé apte à gélifier la phase aqueuse des compositions selon l’invention. Plus particulièrement la fonction tenue par ces gélifiants hydrophiles est de structurer la phase aqueuse de la composition. Le gélifiant est avantageusement soluble dans la phase aqueuse de la composition. Le gélifiant utilisable selon l’invention, peut notamment à être caractérisé par sa capacité à former dans l’eau, au-delà d’une certaine concentration C*, un gel caractérisé par rhéologie oscillatoire (μ = 1 Hz) par un seuil d’écoulement τc au moins égal à 10 Pa. Cette concentration C* peut varier largement selon la nature du gélifiant considéré.The term "hydrophilic gelling agent" within the meaning of the present invention means a compound capable of gelling the aqueous phase of the compositions according to the invention. More particularly, the function performed by these hydrophilic gelling agents is to structure the aqueous phase of the composition. The gelling agent is advantageously soluble in the aqueous phase of the composition. The gelling agent which can be used according to the invention can in particular be characterized by its ability to form in water, above a certain concentration C*, a gel characterized by oscillatory rheology (μ=1 Hz) by a threshold of flow τc at least equal to 10 Pa. This concentration C* can vary widely depending on the nature of the gelling agent considered.
Les gélifiants hydrophiles peuvent être choisis parmi les polymères carboxyvinyliques tels que les Carbopols® (Carbomers) et les Pemulen® (Copolymère Acrylates/C10-C30Alkylacrylate) ; les polyacrylamides comme par exemple les copolymères réticulés vendus sous les noms Sepigel 305® (nom INCI. : Polyacrylamide/C13-C14 Isoparaffin/Laureth 7) ou Simulgel 600® (nom INCI. : Acrylamide / Sodium Acryloyldimethyltaurate Copolymer / Isohexadecane / Polysorbate 80) par la société Seppic ; les polymères et copolymères d’acide 2-acrylamido 2-méthylpropane sulfonique, éventuellement réticulés et/ou neutralisés, comme le poly(acide 2-acrylamido 2-méthylpropane sulfonique) commercialisé par la société Hoechst sous la dénomination commerciale « Hostacerin AMPS® » (nom INCI: Ammonium Polyacryloyldimethyl Taurate ou le SIMULGEL 800® commercialisé par la société SEPPIC (nom INCI : Sodium Polyacryolyldimethyl Taurate / Polysorbate 80 / Sorbitan Oleate) ; les copolymères d’acide 2-acrylamido 2-méthylpropane sulfonique et d’hydroxyethyl acrylate comme le SIMULGEL NS® et le SEPINOV EMT 10® commercialisés par la société SEPPIC ; les composés cellulosiques tels que l’hydroxyéthylcellulose; les polysaccharides et notamment les gommes telles que la gomme de Xanthane, les gommes de guar hydroxypropylée.The hydrophilic gelling agents can be chosen from carboxyvinyl polymers such as Carbopols® (Carbomers) and Pemulen® (Acrylates/C10-C30Alkylacrylate copolymer); polyacrylamides such as for example cross-linked copolymers sold under the names Sepigel 305® (INCI name: Polyacrylamide/C13-C14 Isoparaffin/Laureth 7) or Simulgel 600® (INCI name: Acrylamide / Sodium Acryloyldimethyltaurate Copolymer / Isohexadecane / Polysorbate 80) by Seppic; polymers and copolymers of 2-acrylamido 2-methylpropane sulfonic acid, optionally crosslinked and/or neutralized, such as poly(2-acrylamido 2-methylpropane sulfonic acid) marketed by the company Hoechst under the trade name “Hostacerin AMPS®” ( INCI name: Ammonium Polyacryloyldimethyl Taurate or SIMULGEL 800® marketed by the company SEPPIC (INCI name: Sodium Polyacryolyldimethyl Taurate / Polysorbate 80 / Sorbitan Oleate); copolymers of 2-acrylamido 2-methylpropane sulphonic acid and hydroxyethyl acrylate such as SIMULGEL NS® and SEPINOV EMT 10® marketed by the company SEPPIC; cellulose compounds such as hydroxyethylcellulose; polysaccharides and in particular gums such as xanthan gum, hydroxypropyl guar gums.
De préférence, on utilisera les composés cellulosiques, en particulier l’hydroxyéthylcellulose.Preferably, cellulosic compounds will be used, in particular hydroxyethylcellulose.
Le ou les gélifiants hydrophiles sont de préférence présents dans la composition en une teneur totale allant de 0,1 à 10%, mieux de 0,5 à 5% en poids par rapport au poids total de ladite composition (A).The hydrophilic gelling agent(s) are preferably present in the composition in a total content ranging from 0.1 to 10%, better still from 0.5 to 5% by weight relative to the total weight of said composition (A).
Les compositions (A) de maquillage sont de préférence des produits de maquillage semi-permanent des matières kératiniques telles que la peau, les cils ou les sourcils.The make-up compositions (A) are preferably semi-permanent make-up products for keratin materials such as the skin, the eyelashes or the eyebrows.
Composition (B) démaquillanteMakeup-removing composition (B)
La composition (B) démaquillante selon l’invention, comprend au moins, de préférence dans un milieu physiologiquement acceptable, une phase aqueuse contenant au moins un sel hydrosoluble de cation monovalent ou divalent à une concentration supérieure ou égale à 0,5% en poids par rapport au poids total de la composition (B).
Phase aqueuse The makeup-removing composition (B) according to the invention comprises at least, preferably in a physiologically acceptable medium, an aqueous phase containing at least one water-soluble salt of a monovalent or divalent cation at a concentration greater than or equal to 0.5% by weight relative to the total weight of composition (B).
Aqueous phase
La composition (B) démaquillante selon l’invention comprend une phase aqueuse, de préférence, qui peut former une phase continue de la composition.The makeup-removing composition (B) according to the invention preferably comprises an aqueous phase, which can form a continuous phase of the composition.
De préférence, la composition (B) selon l'invention comprend une phase aqueuse continue. Par composition à phase aqueuse « continue », on entend que la composition présente une conductivité, mesurée à 25°C, supérieure à 23 µS/cm (microSiemens/cm), la conductivité étant mesurée par exemple à l'aide d'un conductimètre MPC227® de Mettler Toledo et d'une cellule de mesure de conductivité Inlab730. La cellule de mesure est immergée dans la composition, de façon à éliminer les bulles d'air susceptibles de se former entre les deux électrodes de la cellule. La lecture de la conductivité est faite dès que la valeur du conductimètre est stabilisée. Une moyenne est réalisée sur au moins trois mesures successives.Preferably, composition (B) according to the invention comprises a continuous aqueous phase. By “continuous” aqueous phase composition, it is meant that the composition has a conductivity, measured at 25° C., greater than 23 μS/cm (microSiemens/cm), the conductivity being measured for example using a conductivity meter MPC227® from Mettler Toledo and an Inlab730 conductivity measuring cell. The measurement cell is immersed in the composition, so as to eliminate the air bubbles liable to form between the two electrodes of the cell. The conductivity reading is taken as soon as the conductivity meter value has stabilized. An average is calculated over at least three successive measurements.
L’eau est de préférence présente dans la composition en une teneur allant de 30 à 90 % en poids, plus préférentiellement allant de 35 à 90 % en poids, en particulier allant de 40 à 85 % en poids par rapport au poids total de la composition (B).The water is preferably present in the composition in a content ranging from 30 to 90% by weight, more preferably ranging from 35 to 90% by weight, in particular ranging from 40 to 85% by weight relative to the total weight of the composition (B).
La phase aqueuse comprend de l’eau. Elle peut également comprendre au moins un solvant hydrosoluble.The aqueous phase includes water. It can also comprise at least one water-soluble solvent.
Par "solvant hydrosoluble", on désigne dans la présente invention un composé liquide à température ambiante et miscible à l’eau.By “water-soluble solvent”, is meant in the present invention a compound that is liquid at room temperature and miscible with water.
Les solvants hydrosolubles utilisables dans les compositions selon l’invention peuvent en outre être volatils.The water-soluble solvents that can be used in the compositions according to the invention can also be volatile.
Parmi les solvants hydrosolubles pouvant être utilisés dans les compositions conformes à l’invention, on peut citer notamment les mono-alcools inférieurs ayant de 1 à 5 atomes de carbone tels que l’éthanol et l’isopropanol, les glycols ayant de 3 à 8 atomes de carbone tels que le propylène glycol, le 1,3-butylène glycol et le dipropylène glycol, et leurs mélanges.Among the water-soluble solvents which can be used in the compositions in accordance with the invention, mention may in particular be made of lower mono-alcohols having from 1 to 5 carbon atoms, such as ethanol and isopropanol, glycols having from 3 to 8 carbon atoms such as propylene glycol, 1,3-butylene glycol and dipropylene glycol, and mixtures thereof.
La phase aqueuse (eau et éventuellement le solvant miscible à l'eau) est de préférence présente dans la composition (B) en une teneur allant de 30 à 90 % en poids, plus préférentiellement allant de 35 à 90 % en poids, en particulier allant de 40 à 85 % en poids par rapport au poids total de la composition (B). Cette teneur en phase aqueuse inclut non seulement l’eau délibérément ajoutée à la composition (B), mais aussi l’eau éventuellement amenée par d’autres ingrédients.The aqueous phase (water and optionally the water-miscible solvent) is preferably present in composition (B) in a content ranging from 30 to 90% by weight, more preferably ranging from 35 to 90% by weight, in particular ranging from 40 to 85% by weight relative to the total weight of composition (B). This aqueous phase content includes not only the water deliberately added to the composition (B), but also the water possibly brought in by other ingredients.
Selon un mode préférentiel de l’invention, la composition démaquillante (B) selon l’invention contient moins de 5 % en poids d’huile volatile, voire moins de 2 % d’huile volatile par rapport au poids total de la composition (B), voire est exempte d’huile volatile.According to a preferred embodiment of the invention, the makeup-removing composition (B) according to the invention contains less than 5% by weight of volatile oil, or even less than 2% of volatile oil relative to the total weight of the composition (B ), or even is free of volatile oil.
Par « huile », on entend un composé non aqueux, non miscible à l’eau, liquide à température ambiante (25°C) et pression atmosphérique (760 mm de Hg).By "oil" is meant a non-aqueous compound, immiscible with water, liquid at room temperature (25°C) and atmospheric pressure (760 mm Hg).
Par "huile volatile", on entend une huile (ou milieu non aqueux) susceptible de s'évaporer au contact de la peau en moins d'une heure, à température ambiante et pression atmosphérique. L'huile volatile est une huile cosmétique volatile, liquide à température ambiante. Plus précisément, une huile volatile présente une vitesse d’évaporation comprise entre 0.01 et 200 mg/cm2/min, bornes incluses. La (Les) huile(s) volatile(s) peut (peuvent) être choisie(s) parmi les huiles hydrocarbonées, les huiles siliconées et leurs mélanges.By "volatile oil" is meant an oil (or non-aqueous medium) capable of evaporating on contact with the skin in less than one hour, at ambient temperature and atmospheric pressure. Volatile oil is a volatile cosmetic oil, liquid at room temperature. More specifically, a volatile oil has an evaporation rate of between 0.01 and 200 mg/cm 2 /min, limits included. The volatile oil(s) may be chosen from hydrocarbon oils, silicone oils and mixtures thereof.
Selon un mode préférentiel de l’invention, la composition (B) contient moins de 5 % en poids de cire, voire moins de 2 % en poids de cire par rapport au poids total de la composition (B), voire est exempte de cire. Par cire on entend un corps gras ayant un point de fusion compris entre 40° et 120 °C d’origine végétal ou minéral.According to a preferred embodiment of the invention, composition (B) contains less than 5% by weight of wax, or even less than 2% by weight of wax relative to the total weight of composition (B), or is even free of wax. . By wax is meant a fatty substance having a melting point between 40° and 120°C of vegetable or mineral origin.
Selon un mode préférentiel de l’invention, la composition (B) contient moins de 5% en poids de tensioactif non ionique de HLB > 8, voire moins de 2% en poids de tensioactif non ionique par rapport au poids total de la composition (B), voire est exempte de tensioactif non ionique de haute HLB > 8.According to a preferred embodiment of the invention, composition (B) contains less than 5% by weight of nonionic surfactant with an HLB > 8, or even less than 2% by weight of nonionic surfactant relative to the total weight of the composition ( B), or even is free of nonionic surfactant with a high HLB > 8.
Au sens de la présente invention, on entend par « tensioactif », tout composé chimique amphiphile, c'est-à-dire présentant dans sa structure deux parties de polarité différente. En général, l'une est lipophile (soluble ou dispersible dans une phase huileuse. L’autre est hydrophile (soluble ou dispersible dans l’eau). Les tensioactifs sont caractérisés par la valeur de leur HLB (Hydrophilic Lipophilic Balance ou Balance Hydrophile-Lipophile), le HLB étant le rapport entre la partie hydrophile et la partie lipophile dans la molécule. Le terme HLB est bien connu de l’homme du métier et est décrit par exemple dans ”The HLB system. A time-saving guide to Emulsifier Selection” (published by ICI Americas Inc ; 1984).Within the meaning of the present invention, the term "surfactant" means any amphiphilic chemical compound, that is to say having in its structure two parts of different polarity. In general, one is lipophilic (soluble or dispersible in an oily phase. The other is hydrophilic (soluble or dispersible in water). Surfactants are characterized by the value of their HLB (Hydrophilic Lipophilic Balance or Hydrophilic Balance). Lipophilic), the HLB being the ratio between the hydrophilic part and the lipophilic part in the molecule. The term HLB is well known to those skilled in the art and is described for example in "The HLB system. A time-saving guide to Emulsifier Selection” (published by ICI Americas Inc; 1984).
On entend par « tensioactif non ionique », », tout composé chimique amphiphile qui ne comprend pas de groupe ionique dans sa structure.
Sel hydrosoluble de cation monovalent ou divalent The term “nonionic surfactant” is understood to mean any amphiphilic chemical compound which does not comprise an ionic group in its structure.
Water-soluble salt of monovalent or divalent cation
Les sels hydrosolubles de cation monovalent ou divalent conformes à l’invention sont de préférence physiologiquement acceptables.The water-soluble monovalent or divalent cation salts in accordance with the invention are preferably physiologically acceptable.
Par "sel hydrosoluble", on entend au sens de la présente invention un sel présentant une solubilité dans l'eau à 25°C supérieure à 1%, c'est-à-dire formant à cette concentration un milieu macroscopiquement homogène, transparent et isotrope.By "water-soluble salt" is meant within the meaning of the present invention a salt having a solubility in water at 25 ° C greater than 1%, that is to say forming at this concentration a macroscopically homogeneous medium, transparent and isotropic.
Par « sel physiologiquement acceptable », on entend tout sel compatible avec la peau et notamment le contour de l’œil et avec ses phanères comme les cils et les sourcils, qui ne génère pas d'inconforts inacceptables (picotements, tiraillements), susceptibles de détourner la consommatrice d'utiliser ce sel.By "physiologically acceptable salt" is meant any salt compatible with the skin and in particular the contour of the eye and with its appendages such as the eyelashes and eyebrows, which does not generate unacceptable discomfort (tingling, tightness), likely to dissuade the consumer from using this salt.
Par « cation monovalent », on entend tout atome ou groupe d’atomes chargé positivement de valence +1.By “monovalent cation”, we mean any positively charged atom or group of atoms with a valence of +1.
Par « cation divalent », on entend tout atome ou groupe d’atomes chargé positivement de valence +2.By "divalent cation" is meant any positively charged atom or group of atoms of valence +2.
Le cation monovalent du sel hydrosoluble conforme à l’invention est de préférence choisi parmi les métaux alcalins comme le sodium (Na+) et le potassium (K+) ou le groupe ammonium (NH4 +), et plus particulièrement le sodium.The monovalent cation of the water-soluble salt in accordance with the invention is preferably chosen from alkali metals such as sodium (Na+) and potassium (K+) or the ammonium group (NH 4 + ), and more particularly sodium.
Le cation divalent du sel hydrosoluble conforme à l’invention est de préférence choisi parmi les métaux alcalino-terreux comme le Berylium (Be2+), le Magnésium (Mg2+), le Calcium (Ca2+), le Strontium (Sr2+), le Barium (Ba2+). On utilisera plus particulièrement le calcium et le magnésium.The divalent cation of the water-soluble salt in accordance with the invention is preferably chosen from alkaline-earth metals such as Berylium (Be 2+ ), Magnesium (Mg 2+ ), Calcium (Ca 2+ ), Strontium (Sr 2+ ), Barium (Ba 2+ ). More particularly, calcium and magnesium will be used.
Les contre-ions anioniques peuvent être choisis parmi les halogénures. Les halogènes sont une série chimique constituée des éléments chimiques du groupe 17 du tableau périodique aussi appelé groupe VII ou VIIA. On utilisera plus particulièrement les chlorures.The anionic counterions can be chosen from halides. The halogens are a chemical series made up of the chemical elements of group 17 of the periodic table also called group VII or VIIA. Chlorides will be used more particularly.
On peut citer également les sels d’acide carboxylique comme les acétates, les propionates, les pyrrolidone carboxylates (ou pidolates), les phytates, les sorbates ; les sels d’acide carboxylique polyhydroxylé comme les gluconates, les heptagluconates,, les céto-gluconates, les lactates gluconates, les ascorbates, les pantothénates ; les sels d’hydroxyacide mono ou polycarboxyliques comme les citrates, les lactates ; les sels d’acides aminés comme les aspartates, les glutamates ; les sels de fulvates.Mention may also be made of carboxylic acid salts such as acetates, propionates, pyrrolidone carboxylates (or pidolates), phytates, sorbates; polyhydroxylated carboxylic acid salts such as gluconates, heptagluconates, keto-gluconates, lactate gluconates, ascorbates, pantothenates; mono or polycarboxylic hydroxy acid salts such as citrates, lactates; amino acid salts such as aspartates, glutamates; fulvate salts.
On utilisera plus particulièrement les sels de phytate comme le phytate de sodium.More particularly, phytate salts such as sodium phytate will be used.
On peut également citer :
- les sels de bicarbonate appelés encore hydrogénocarbonates ;
- les sels de sulfate (SO4 2-) comme le sulfate de Magnésium et le sulfate de Calcium, ;
- les sels de sulfonate (SO3 2-) ;
_ les sels d’hydrogénosulfate (HSO4 -) ;
- les sels d’ hydrogénosulfonate (HSO3 -) ;
- les sels de nitrate comme le nitrates de Calcium ; Ca(NO3)2.We can also mention:
- bicarbonate salts also called hydrogen carbonates;
- sulphate salts (SO 4 2- ) such as magnesium sulphate and calcium sulphate;
- sulphonate salts (SO 3 2- );
_ hydrogen sulphate salts (HSO 4 - );
- hydrogen sulphonate salts (HSO 3 - );
- nitrate salts such as calcium nitrate; Ca(NO 3 ) 2 .
On utilisera de préférence choisi le chlorure de sodium, le sulfate de magnésium, le phytate de sodium, et leurs mélanges.Sodium chloride, magnesium sulphate, sodium phytate, and mixtures thereof will preferably be used.
Le ou les sels hydrosolubles de cation monovalent ou divalent sont présents, de préférence, à une concentration allant de 0,5 et 8 % en poids par rapport au poids total de la composition (B).
Solvant hydrotrope The water-soluble salt(s) of monovalent or divalent cation are preferably present at a concentration ranging from 0.5 and 8% by weight relative to the total weight of composition (B).
hydrotropic solvent
Une composition (B) conforme à l’invention peut contenir un solvant hydrotrope de formule (I) :A composition (B) in accordance with the invention may contain a hydrotropic solvent of formula (I):
où R1 représente un atome d’hydrogène ou un groupement alkyle en C1-C4linéaire ou ramifié.
where R1 represents a hydrogen atom or a linear or branched C 1 -C 4 alkyl group.
En particulier le solvant est le carbonate d’éthylène ou le carbonate de propylène, de préférence le carbonate de propylène.In particular the solvent is ethylene carbonate or propylene carbonate, preferably propylene carbonate.
Le solvant hydrotrope est présent en une teneur totale supérieure ou égale à 3% en poids, de préférence supérieure ou égale à 5%, en particulier de 5 à 35% en poids, mieux de 8 à 25% en poids par rapport au poids total de la composition. (B)
Agents hydratants The hydrotropic solvent is present in a total content greater than or equal to 3% by weight, preferably greater than or equal to 5%, in particular from 5 to 35% by weight, better still from 8 to 25% by weight relative to the total weight of composition. (B)
Moisturizing agents
Une composition (B) conforme à l’invention peut contenir au moins un agent hydratant.A composition (B) in accordance with the invention may contain at least one moisturizing agent.
Par « agent hydratant », on entend selon la présente invention tout composé susceptible de pénétrer dans le stratum corneum et de maintenir celui-ci hydraté. Les agents hydratants utilisables selon l’invention sont notamment choisis parmi les polyols, l’urée et ses dérivés tels que notamment les hydroxyalkyle urée en particulier l’hydroxyéthylurée comme le produit vendu sous le nom commercial HYDROVANCE® par la société AKZO NOBEL, l’acide hyaluronique, la glycine, la β-alanine, la taurine, la triméthyle glycine et leurs mélanges.By “hydrating agent”, is meant according to the present invention any compound capable of penetrating into the stratum corneum and of keeping it hydrated. The moisturizing agents that can be used according to the invention are chosen in particular from polyols, urea and its derivatives such as in particular hydroxyalkyl ureas, in particular hydroxyethyl urea, such as the product sold under the trade name HYDROVANCE® by the company AKZO NOBEL, the hyaluronic acid, glycine, β-alanine, taurine, trimethyl glycine and mixtures thereof.
Par « polyol », il faut comprendre, au sens de la présente invention, toute molécule organique comportant au moins deux groupements hydroxyle libres.By “polyol”, it is necessary to understand, within the meaning of the present invention, any organic molecule comprising at least two free hydroxyl groups.
Selon une forme particulière, le polyol peut être choisi parmi les sucres tels que le thréhalose, le mannitol, le xylitol, le sorbitol, et leurs mélanges. De préférence, un polyol conforme à la présente invention est présent sous forme liquide à température ambiante.According to a particular form, the polyol can be chosen from sugars such as threhalose, mannitol, xylitol, sorbitol, and mixtures thereof. Preferably, a polyol in accordance with the present invention is present in liquid form at room temperature.
Un polyol convenant à l’invention peut être un composé de type alkyle, linéaire, ramifié ou cyclique, saturé ou insaturé, portant sur la chaîne alkyle au moins deux fonctions –OH, en particulier au moins trois fonctions –OH, et plus particulièrement au moins quatre fonctions –OH.A polyol suitable for the invention may be a compound of the alkyl type, linear, branched or cyclic, saturated or unsaturated, carrying on the alkyl chain at least two –OH functions, in particular at least three –OH functions, and more particularly minus four –OH functions.
Les polyols convenant avantageusement pour la formulation d’une composition selon la présente invention sont ceux présentant notamment de 2 à 32 atomes de carbone, de préférence 3 à 16 atomes de carbone.The polyols which are advantageously suitable for the formulation of a composition according to the present invention are those having in particular from 2 to 32 carbon atoms, preferably 3 to 16 carbon atoms.
Avantageusement, le polyol peut être par exemple choisi parmi le pentaérythritol, le triméthylolpropane, la glycérine, les polyglycérols, tels que les oligomères du glycérol comme le diglycérol, les polyéthylènes glycols, et leurs mélanges.Advantageously, the polyol can be chosen, for example, from pentaerythritol, trimethylolpropane, glycerin, polyglycerols, such as glycerol oligomers such as diglycerol, polyethylene glycols, and mixtures thereof.
Selon un mode de réalisation préféré de l’invention, ledit polyol est choisi parmi, le pentaérythritol, le triméthylolpropane, la glycérine, les polyglycérols, les polyéthylènes glycols, et leurs mélanges.According to a preferred embodiment of the invention, said polyol is chosen from pentaerythritol, trimethylolpropane, glycerin, polyglycerols, polyethylene glycols, and mixtures thereof.
Le ou les agents hydratants sont de préférence présents dans la composition en une teneur allant de 1 à 60%, mieux de 3 à 55% en poids, de préférence de 5 à 50% en poids, par rapport au poids total de ladite composition (B).The hydrating agent(s) are preferably present in the composition in a content ranging from 1 to 60%, better still from 3 to 55% by weight, preferably from 5 to 50% by weight, relative to the total weight of said composition ( B).
Conditionnements et applicateursConditioners and applicators
Les compositions (A) et (B) selon l’invention peuvent être conditionnées chacune dans un récipient délimitant au moins un compartiment qui comprend ladite composition (A) ou (B), ledit récipient étant fermé par un élément de fermeture.Compositions (A) and (B) according to the invention can each be packaged in a container delimiting at least one compartment which comprises said composition (A) or (B), said container being closed by a closure element.
Le récipient peut être sous toute forme adéquate. Il peut être notamment sous forme d’un flacon, d’un tube, d’un pot, d’un étui.The container may be in any suitable form. It may in particular be in the form of a bottle, a tube, a jar or a case.
L’élément de fermeture peut être sous forme d’un bouchon amovible, d’un couvercle, d’un opercule, notamment du type comportant un corps fixé au récipient et une casquette articulée au corps. Il peut être également sous forme d’un élément assurant la fermeture sélective du récipient, notamment une pompe, une valve, ou un clapet.The closure element can be in the form of a removable cap, a lid, a lid, in particular of the type comprising a body fixed to the container and a cap hinged to the body. It can also be in the form of an element ensuring the selective closure of the container, in particular a pump, a valve, or a valve.
Le récipient peut être associé à un applicateur, notamment sous forme d’une brosse comportant un arrangement de poils maintenus par un fil torsadé. Une telle brosse torsadée est décrite notamment dans le brevet US 4,887,622. Il peut être également sous forme d’un peigne comportant une pluralité d’éléments d’application, obtenus notamment de moulage. De tels peignes sont décrits par exemple dans le brevet FR 2 796 529. L’applicateur peut être sous forme d’un pinceau, tel que décrit par exemple dans le brevet FR 2 722 380. L’applicateur peut être sous forme d’un bloc de mousse ou d’élastomère. L’applicateur peut être libre (éponge) ou solidaire d’une tige portée par l’élément de fermeture, tel que décrit par exemple dans le brevet US 5,492,426. L’applicateur peut être solidaire du récipient, tel que décrit par exemple dans le brevet FR 2 761 959.The container can be associated with an applicator, in particular in the form of a brush comprising an arrangement of bristles held by a twisted wire. Such a twisted brush is described in particular in US Patent 4,887,622. It can also be in the form of a comb comprising a plurality of application elements, obtained in particular by molding. Such combs are described for example in patent FR 2 796 529. The applicator can be in the form of a brush, as described for example in patent FR 2 722 380. The applicator can be in the form of a block of foam or elastomer. The applicator can be free (sponge) or attached to a rod carried by the closure element, as described for example in US Pat. No. 5,492,426. The applicator can be attached to the container, as described for example in patent FR 2 761 959.
Le produit peut être contenu directement dans le récipient, ou indirectement.The product can be contained directly in the container, or indirectly.
L’élément de fermeture peut être couplé au récipient par vissage. Alternativement, le couplage entre l’élément de fermeture et le récipient se fait autrement que par vissage, notamment via un mécanisme à baïonnette, par encliquetage, ou par serrage. Par « encliquetage » on entend en particulier tout système impliquant le franchissement d’un bourrelet ou d’un cordon de matière par déformation élastique d’une portion, notamment de l’élément de fermeture, puis par retour en position non contrainte élastiquement de ladite portion après le franchissement du bourrelet ou du cordon.The closing element can be coupled to the container by screwing. Alternatively, the coupling between the closure element and the container is done other than by screwing, in particular via a bayonet mechanism, by snap-fastening, or by tightening. By “snap-on” is meant in particular any system involving the crossing of a bead or a bead of material by elastic deformation of a portion, in particular of the closure element, then by return to the elastically unconstrained position of said portion after crossing the bead or bead.
Le récipient peut être au moins pour partie réalisé en matériau thermoplastique. A titre d’exemples de matériaux thermoplastiques, on peut citer le polypropylène ou le polyéthylène.The container may be at least partly made of thermoplastic material. Examples of thermoplastic materials include polypropylene or polyethylene.
Le récipient peut être à parois rigides ou à parois déformables, notamment sous forme d’un tube ou d’un flacon tube.The container may have rigid walls or deformable walls, in particular in the form of a tube or a tube bottle.
Le récipient peut comprendre des moyens destinés à provoquer ou faciliter la distribution de la composition. A titre d’exemple, le récipient peut être à parois déformables de manière à provoquer la sortie de la composition en réponse à une surpression à l’intérieur du récipient, laquelle surpression est provoquée par écrasement élastique (ou non élastique) des parois du récipient.The container may include means to cause or facilitate dispensing of the composition. By way of example, the container may have deformable walls so as to cause the composition to come out in response to an overpressure inside the container, which overpressure is caused by elastic (or inelastic) crushing of the walls of the container .
Le récipient peut être équipé d’un essoreur disposé au voisinage de l’ouverture du récipient. Un tel essoreur permet d’essuyer l’applicateur et éventuellement, la tige dont il peut être solidaire. Un tel essoreur est décrit par exemple dans le brevet FR 2 792 618.The container can be equipped with a wiper placed near the opening of the container. Such a wiper makes it possible to wipe the applicator and possibly the rod to which it may be attached. Such a wiper is described for example in patent FR 2 792 618.
Dans toute la description, y compris les revendications, l’expression « comportant un » doit être comprise comme étant synonyme de « comportant au moins un », sauf si le contraire est spécifié.Throughout the description, including the claims, the expression "comprising a" must be understood as being synonymous with "comprising at least one", unless otherwise specified.
Les expressions « compris entre … et … » et « allant de … à … » doivent se comprendre bornes incluses, sauf si le contraire est spécifié.The expressions “between … and …” and “ranging from … to …” must be understood as limits included, unless the contrary is specified.
L’invention est illustrée plus en détail par les exemples et figures présentés ci-après. Sauf indication contraire, les quantités indiquées sont exprimées en pourcentage massique.The invention is illustrated in more detail by the examples and figures presented below. Unless otherwise indicated, the quantities indicated are expressed in percentage by mass.
Exemple A : Composition de maquillageExample A: Makeup composition
On a réalisé l’exemple A de composition de maquillage.Example A of makeup composition was produced.
CI 42090ACID BLUE 9
CI 42090
CI 16035FD&C RED40
CI 16035
CI 19040ACID YELLOW 23
CI 19040
Protocole de préparation de l’exemple AExample A preparation protocol
On dissout l’acide citrique et les colorants dans l’eau sous agitation à température ambiante. On ajoute ensuite le polysorbate 80 et l’alcool. On ajuste ensuite le pH à une valeur de 4 avec la quantité nécessaire de d’hydroxyde de sodium.
Exemples B 1 , B 2 , B 3 , B 4 , B 5 , B 6 : Compositions démaquillantes The citric acid and the dyes are dissolved in water with stirring at room temperature. The polysorbate 80 and the alcohol are then added. The pH is then adjusted to a value of 4 with the necessary quantity of sodium hydroxide.
Examples B 1 , B 2 , B 3 , B 4 , B 5 , B 6 : Makeup-removing compositions
On a réalisé les compositions démaquillantes B1, B2, B3, B4, B5, B6.The makeup-removing compositions B 1 , B 2 , B 3 , B 4 , B 5 , B 6 were produced.
(hors invention)(excluding invention)
(hors invention)(excluding invention)
(hors invention)(excluding invention)
inventioninvention
inventioninvention
inventioninvention
Protocole de préparation des compostions B2 à B6Preparation protocol for compositions B2 to B6
On commence par dissoudre le chlorure de sodium ou le sulfate de magnésium dans l’eau sous agitation et température ambiante. On ajoute ensuite l’alcool, la glycérine et le propylène glycol.Start by dissolving sodium chloride or magnesium sulfate in water with stirring and room temperature. Then add alcohol, glycerin and propylene glycol.
La composition A de coloration de la peau a été appliquée sur l’avant-bras avec un coton tige de manière à faire un rectangle de 1 cm sur 2 cm. On a laissé sécher cette composition 30 minutes. On a rincé l’avant-bras avec un jet d’eau pour retirer tout excès de colorant. La peau est ainsi colorée. On a déposé ensuite 0,5 ml de solution Bi démaquillante sur un coton démaquillant avec lequel on a effectué 10 passages pour retirer cette coloration. On a refait une deuxième série de 10 passages sur la même surface colorée. On regarde ensuite la quantité de couleur prélevée par les cotons. On a observé qu’avec la composition B1 à base uniquement d’eau, la composition B2à base de chlorure de sodium à 0,4% en poids et la composition B3à base sulfate de magnésium à 0,4%, la couleur prélevée par les cotons restait faible. Tandis qu’avec les compostions démaquillantes B4, B5et B6selon l’invention comprenant au moins 0,5% en poids de sel hydrosoluble de cation monovalent ou divalent, la couleur était sensiblement plus intense sur les deux cotons et l’intensité de la couleur restée sur la peau était sensiblement plus faible.The skin coloring composition A was applied to the forearm with a cotton swab so as to make a rectangle of 1 cm by 2 cm. This composition was left to dry for 30 minutes. The forearm was rinsed with a stream of water to remove any excess dye. The skin is thus colored. 0.5 ml of makeup-removing solution Bi was then deposited on a makeup-removing cotton ball with which 10 passes were made to remove this coloration. A second series of 10 passages was repeated on the same colored surface. We then look at the quantity of color taken up by the cottons. It was observed that with composition B1 based solely on water, composition B 2 based on sodium chloride at 0.4% by weight and composition B 3 based on magnesium sulphate at 0.4%, the color picked up by the cottons remained weak. Whereas with the makeup-removing compositions B 4 , B 5 and B 6 according to the invention comprising at least 0.5% by weight of water-soluble salt of monovalent or divalent cation, the color was significantly more intense on the two cottons and the intensity of the color left on the skin was noticeably lower.
Claims (27)
- l’application sur des matières kératiniques d’une composition (A) comprenant au moins, de préférence dans un milieu physiologiquement acceptable, une phase aqueuse comprenant au moins un colorant direct acide et
- l’application sur lesdites matières kératiniques colorées d’une composition (B) comprenant au moins, de préférence dans un milieu physiologiquement acceptable, une phase aqueuse comprenant au moins un sel hydrosoluble de cation monovalent ou divalent.Method for removing make-up and/or cleaning colored keratin materials, preferably colored skin, comprising:
- the application to keratin materials of a composition (A) comprising at least, preferably in a physiologically acceptable medium, an aqueous phase comprising at least one acid direct dye and
- the application to said colored keratin materials of a composition (B) comprising at least, preferably in a physiologically acceptable medium, an aqueous phase comprising at least one water-soluble salt of a monovalent or divalent cation.
FOOD BLACK 2 (CI 27755), FOOD BLACK 1 (CI 28440), ACID BLACK 2 (CI 50420), ACID YELLOW 9 (CI 13015), ACID YELLOW 11 (CI 18820), ACID YELLOW 17 (CI 18965), ACID YELLOW 23 (CI 19140), BETANIN, ACID, BROMOCRESOL GREEN , FOOD GREEN 3 (CI 42053), ACID GREEN 9 (CI 42100), ACID GREEN 22 (CI 42170), ACID GREEN 50 (CI 44090), BROMOTHYLOL BLUE, ACID BLUE 1 (CI 42045), ACID BLUE 7 (CI 42080), ACID BLUE 9 (CI 42090), ACID BLUE 104 (CI 42735), ACID VIOLET 9 (CI 45190), ACID RED 52 (CI 45100), ACID RED 50 (CI 45220), ACID RED 87 (CI 45380), ACID RED 98 (CI 45405), ACID RED 92 (CI 45410), ACID RED 95 (CI 45425), ACID RED 51 (CI 45430), ACID ORANGE 11 (CI 45370), SOLVENT ORANGE 16 (CI 45396), ACID YELLOW 73 (CI 45350), ACID YELLOW 73 FLUOROSCEIN (CI 45340), ACID YELLOW 1 (CI 10316).Process according to any one of Claims 1 to 4 , in which the acid direct dye is chosen from ACID VIOLET 43 (CI 60730), ACID GREEN 25 (CI 61570), ACID BLUE 80 (CI 61785), ACID BLUE 62 (CI 62045 ), ACID VIOLET 50 (CI 50325), FD&C RED 4 (CI 14700), ACID RED 4 (CI 14720), ACID RED 88 (CI 15620), D&C RED 7 (CI 15850), FD&C RED 40 (CI 16035), ACID RED 27 (CI 16185), ACID RED 28 (CI 16255), ACID RED 41 (CI 16290), ACID RED 33 (CI 17200), ACID RED 1 (CI 18050), ACID RED 155 (CI 18130), ACID RED 180 (CI 18736), ACID RED 163 (CI 24790), ACID RED 73 (CI 27290), ACID ORANGE 6 (CI 14270), ACID ORANGE 7 (CI 15510), FOOD ORANGE 2 (CI 15980) , FOOD YELLOW 3 (CI 15985), ACID ORANGE 10 (CI 16230), ACID ORANGE 24 (CI 20170), ACID BLACK 1 (CI 20470),
FOOD BLACK 2 (CI 27755), FOOD BLACK 1 (CI 28440), ACID BLACK 2 (CI 50420), ACID YELLOW 9 (CI 13015), ACID YELLOW 11 (CI 18820), ACID YELLOW 17 (CI 18965), ACID YELLOW 23 (CI 19140), BETANIN, ACID, BROMOCRESOL GREEN , FOOD GREEN 3 (CI 42053), ACID GREEN 9 (CI 42100), ACID GREEN 22 (CI 42170), ACID GREEN 50 (CI 44090), BROMOTHYLOL BLUE, ACID BLUE 1 (CI 42045), ACID BLUE 7 (CI 42080), ACID BLUE 9 (CI 42090), ACID BLUE 104 (CI 42735), ACID VIOLET 9 (CI 45190), ACID RED 52 (CI 45100), ACID RED 50 ( CI 45220), ACID RED 87 (CI 45380), ACID RED 98 (CI 45405), ACID RED 92 (CI 45410), ACID RED 95 (CI 45425), ACID RED 51 (CI 45430), ACID ORANGE 11 (CI 45370) ), SOLVENT ORANGE 16 (CI 45396), ACID YELLOW 73 (CI 45350), ACID YELLOW 73 FLUOROSCEIN (CI 45340), ACID YELLOW 1 (CI 10316).
- le cation monovalent du sel hydrosoluble est choisi parmi les métaux alcalins comme le sodium (Na+) et le potassium (K+) ou le groupe ammonium (NH4 +), et plus particulièrement le sodium ;
- le cation divalent du sel hydrosoluble est choisi parmi les métaux alcalino-terreux comme le Berylium (Be2+), le Magnésium (Mg2+), le Calcium (Ca2+), le Strontium (Sr2+), le Barium (Ba2+), et plus particulièrement choisi parmi le calcium et le magnésium.Process according to any one of claims 1 to 15 , where in composition (B):
- the monovalent cation of the water-soluble salt is chosen from alkali metals such as sodium (Na + ) and potassium (K + ) or the ammonium group (NH 4 + ), and more particularly sodium;
- the divalent cation of the water-soluble salt is chosen from alkaline-earth metals such as Berylium (Be 2+ ), Magnesium (Mg 2+ ), Calcium (Ca 2+ ), Strontium (Sr 2+ ), Barium (Ba 2+ ), and more particularly chosen from calcium and magnesium.
(I)
où R1 représente un atome d’hydrogène ou un groupement alkyle en C1-C4 linéaire ou ramifié, et plus particulièrement choisi parmi le carbonate d’éthylène ou le carbonate de propylène, et encore mieux, le carbonate de propylène.Process according to any one of Claims 1 to 18 , in which composition (B) comprises at least one hydrotropic solvent, preferably chosen from those of formula (I) below:
(I)
where R1 represents a hydrogen atom or a linear or branched C1-C4 alkyl group, and more particularly chosen from ethylene carbonate or propylene carbonate, and even better, propylene carbonate.
a) une première composition (A) telle que définie dans l’une quelconque des revendications1 à 12;
b) une deuxième composition (B) telle que définie dans l’une quelconque des revendications1, 13 à 25.Kit for making up and removing make-up and/or cleaning colored keratin materials, preferably colored skin, comprising at least:
a) a first composition (A) as defined in any one of claims 1 to 12 ;
b) a second composition (B) as defined in any one of claims 1, 13 to 25 .
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR2009931A FR3114502B1 (en) | 2020-09-29 | 2020-09-29 | Process for removing make-up from colored keratin materials using an aqueous composition containing a water-soluble salt of a monovalent or divalent cation. |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR2009931 | 2020-09-29 | ||
| FR2009931A FR3114502B1 (en) | 2020-09-29 | 2020-09-29 | Process for removing make-up from colored keratin materials using an aqueous composition containing a water-soluble salt of a monovalent or divalent cation. |
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| Publication Number | Publication Date |
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| FR3114502A1 true FR3114502A1 (en) | 2022-04-01 |
| FR3114502B1 FR3114502B1 (en) | 2024-02-16 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115594987A (en) * | 2022-09-28 | 2023-01-13 | 金华恒利康化工有限公司（Cn） | Acid orange disazo dye and preparation method thereof |
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|---|---|
| FR3114502B1 (en) | 2024-02-16 |
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