FR3104576B1 - Dispositif et procédé de conversion de composés aromatiques par alkylation de benzène par l’éthanol - Google Patents

Dispositif et procédé de conversion de composés aromatiques par alkylation de benzène par l’éthanol Download PDF

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Publication number
FR3104576B1
FR3104576B1 FR1914582A FR1914582A FR3104576B1 FR 3104576 B1 FR3104576 B1 FR 3104576B1 FR 1914582 A FR1914582 A FR 1914582A FR 1914582 A FR1914582 A FR 1914582A FR 3104576 B1 FR3104576 B1 FR 3104576B1
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cut
benzene
ethylbenzene
alkylation
ethanol
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FR1914582A
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FR3104576A1 (fr
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Jean-François Joly
Frederic Feugnet
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IFP Energies Nouvelles IFPEN
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IFP Energies Nouvelles IFPEN
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Priority to FR1914582A priority Critical patent/FR3104576B1/fr
Priority to CA3102551A priority patent/CA3102551A1/fr
Priority to BR102020025462-6A priority patent/BR102020025462A2/pt
Priority to US17/124,087 priority patent/US11407696B2/en
Priority to CN202011498481.5A priority patent/CN112979403A/zh
Publication of FR3104576A1 publication Critical patent/FR3104576A1/fr
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/005—Processes comprising at least two steps in series
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/864—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B01D15/08—Selective adsorption, e.g. chromatography
    • B01D15/10—Selective adsorption, e.g. chromatography characterised by constructional or operational features
    • B01D15/18—Selective adsorption, e.g. chromatography characterised by constructional or operational features relating to flow patterns
    • B01D15/1814—Selective adsorption, e.g. chromatography characterised by constructional or operational features relating to flow patterns recycling of the fraction to be distributed
    • B01D15/1821—Simulated moving beds
    • B01D15/185—Simulated moving beds characterized by the components to be separated
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/14—Fractional distillation or use of a fractionation or rectification column
    • B01D3/143—Fractional distillation or use of a fractionation or rectification column by two or more of a fractionation, separation or rectification step
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/245—Stationary reactors without moving elements inside placed in series
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/02—Monocyclic hydrocarbons
    • C07C15/067—C8H10 hydrocarbons
    • C07C15/08—Xylenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2702—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously
    • C07C5/2708—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously with crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2729—Changing the branching point of an open chain or the point of substitution on a ring
    • C07C5/2732—Catalytic processes
    • C07C5/2737—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2767—Changing the number of side-chains
    • C07C5/277—Catalytic processes
    • C07C5/2775—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/126—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of more than one hydrocarbon
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/04—Purification; Separation; Use of additives by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/09—Purification; Separation; Use of additives by fractional condensation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00027—Process aspects
    • B01J2219/0004—Processes in series

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Dispositif et procédé de conversion de composés aromatiques, comprenant/utilisant : un train de fractionnement (4-7) adapté pour extraire au moins une coupe comprenant du benzène (22), une coupe comprenant du toluène (23) et une coupe comprenant des xylènes et de l’éthylbenzène (24) de la charge (2) ; une unité de séparation des xylènes (10) adaptée pour traiter la coupe comprenant des xylènes et de l’éthylbenzène et produire un extrait comprenant du paraxylène (39) et un raffinat (40) comprenant de l’orthoxylène, du métaxylène et de l’éthylbenzène ; une unité d’isomérisation (11) pour traiter le raffinat et produire un isomérat (42) enrichi en paraxylène envoyé vers le train de fractionnement ; et une section réactionnelle d’alkylation (13) pour traiter au moins une partie de la coupe comprenant du benzène avec une source d’éthanol (30) et produire un effluent d’alkylation (31) comprenant de l’éthylbenzène envoyé vers l’unité d’isomérisation. Figure 1 à publier
FR1914582A 2019-12-17 2019-12-17 Dispositif et procédé de conversion de composés aromatiques par alkylation de benzène par l’éthanol Active FR3104576B1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
FR1914582A FR3104576B1 (fr) 2019-12-17 2019-12-17 Dispositif et procédé de conversion de composés aromatiques par alkylation de benzène par l’éthanol
CA3102551A CA3102551A1 (fr) 2019-12-17 2020-12-11 Dispositif et procede de conversion de composes aromatiques par alkylation de benzene par l'ethanol
BR102020025462-6A BR102020025462A2 (pt) 2019-12-17 2020-12-14 Dispositivo e processo de conversão de compostos aromáticos por alquilação de benzeno por etanol
US17/124,087 US11407696B2 (en) 2019-12-17 2020-12-16 Apparatus and process for converting aromatic compounds by benzene alkylation with ethanol
CN202011498481.5A CN112979403A (zh) 2019-12-17 2020-12-17 通过采用乙醇的苯烷基化转化芳族化合物的装置和方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1914582 2019-12-17
FR1914582A FR3104576B1 (fr) 2019-12-17 2019-12-17 Dispositif et procédé de conversion de composés aromatiques par alkylation de benzène par l’éthanol

Publications (2)

Publication Number Publication Date
FR3104576A1 FR3104576A1 (fr) 2021-06-18
FR3104576B1 true FR3104576B1 (fr) 2021-12-31

Family

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FR1914582A Active FR3104576B1 (fr) 2019-12-17 2019-12-17 Dispositif et procédé de conversion de composés aromatiques par alkylation de benzène par l’éthanol

Country Status (5)

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US (1) US11407696B2 (fr)
CN (1) CN112979403A (fr)
BR (1) BR102020025462A2 (fr)
CA (1) CA3102551A1 (fr)
FR (1) FR3104576B1 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
LT3495230T (lt) * 2017-12-08 2022-04-25 Thales Management & Services Deutschland Gmbh Traukinio valdymo tinklas, ryšio palaikymo būdas ir traukinio vientisumo kontrolės būdas
JP2023094259A (ja) * 2021-12-23 2023-07-05 千代田化工建設株式会社 パラキシレンの製造方法
WO2023248499A1 (fr) * 2022-06-21 2023-12-28 Ｅｎｅｏｓ株式会社 Procédés de production d'hydrocarbures aromatiques monocycliques, d'acide téréphtalique et de polyéthylène téréphtalate, et procédés de gestion associés

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2346308A1 (fr) * 1976-03-30 1977-10-28 Inst Francais Du Petrole Procede d'alkylation-transalkylation d'hydrocarbures aromatiques par le methanol
FR2561946B1 (fr) 1984-03-30 1986-10-03 Pro Catalyse Nouveau catalyseur d'hydrocraquage destine a la production de distillats moyens
US4962258A (en) 1988-12-15 1990-10-09 Amoco Corporation Liquid-phase xylene isomerization
US6180550B1 (en) 1998-12-22 2001-01-30 Mobile Oil Corporation Small crystal ZSM-5, its synthesis and use
FR2862638B1 (fr) 2003-11-26 2005-12-30 Inst Francais Du Petrole Procede de production de paraxylene comprenant une etape d'adsorption et deux etapes d'isomerisation
US7371913B2 (en) 2005-06-30 2008-05-13 Uop Llc Selective aromatics isomerization process
US7425659B2 (en) * 2006-01-31 2008-09-16 Exxonmobil Chemical Patents Inc. Alkylaromatics production
EP2110368A1 (fr) * 2008-04-18 2009-10-21 Total Petrochemicals France Alkylation de substrats aromatiques et procédé de transalkylation
CN101618335B (zh) * 2009-08-06 2011-08-03 上海卓悦化工科技有限公司 一种乙苯与乙烯或乙醇烷基化反应合成对二乙苯催化剂的制备方法
KR20140046484A (ko) 2010-04-21 2014-04-18 엑손모빌 케미칼 패턴츠 인코포레이티드 크실렌 이성질화 방법 및 이를 위한 촉매
CN102464559A (zh) * 2010-11-17 2012-05-23 中国石油化工股份有限公司 用于生产烷基化芳烃的方法
US9079816B2 (en) * 2013-11-19 2015-07-14 Uop Llc Process for producing alkylated aromatic compounds
FR3023841B1 (fr) 2014-07-18 2016-07-15 Ifp Energies Now Procede de production de paraxylene comprenant deux unites de separation en lit mobile simule et deux unites d'isomerisation dont l'une en phase gaz
FR3023840B1 (fr) 2014-07-18 2016-07-15 Ifp Energies Now Procede de production de paraxylene a haute purete a partir d'une coupe xylenes, utilisant deux unites de separation en lit mobile simule fonctionnant en serie et deux unites d'isomerisation.

Also Published As

Publication number Publication date
US11407696B2 (en) 2022-08-09
BR102020025462A2 (pt) 2021-09-14
FR3104576A1 (fr) 2021-06-18
CA3102551A1 (fr) 2021-06-17
CN112979403A (zh) 2021-06-18
US20210179513A1 (en) 2021-06-17

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