FR3087442B1 - Copolymeres hydrocarbones a blocs alternes et groupements terminaux alcoxysilanes - Google Patents

Copolymeres hydrocarbones a blocs alternes et groupements terminaux alcoxysilanes Download PDF

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Publication number
FR3087442B1
FR3087442B1 FR1859622A FR1859622A FR3087442B1 FR 3087442 B1 FR3087442 B1 FR 3087442B1 FR 1859622 A FR1859622 A FR 1859622A FR 1859622 A FR1859622 A FR 1859622A FR 3087442 B1 FR3087442 B1 FR 3087442B1
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Prior art keywords
radical
zero
groups
integer
alcoxysilane
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Expired - Fee Related
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FR1859622A
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FR3087442A1 (fr
Inventor
Stephane Fouquay
Frederic Simon
Guillaume Michaud
Cyril Chauveau
Jean-Francois Carpentier
Sophie Guillaume
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Centre National de la Recherche Scientifique CNRS
Universite de Rennes 1
Bostik SA
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Centre National de la Recherche Scientifique CNRS
Universite de Rennes 1
Bostik SA
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Priority to FR1859622A priority Critical patent/FR3087442B1/fr
Priority to PCT/FR2019/052458 priority patent/WO2020079370A1/fr
Publication of FR3087442A1 publication Critical patent/FR3087442A1/fr
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Publication of FR3087442B1 publication Critical patent/FR3087442B1/fr
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J201/00—Adhesives based on unspecified macromolecular compounds
    • C09J201/02—Adhesives based on unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups
    • C09J201/10—Adhesives based on unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups containing hydrolysable silane groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
    • C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
    • C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J165/00—Adhesives based on macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Adhesives based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/33—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain
    • C08G2261/332—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms
    • C08G2261/3323—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms derived from other monocyclic systems
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/34—Monomer units or repeat units incorporating structural elements in the main chain incorporating partially-aromatic structural elements in the main chain
    • C08G2261/344—Monomer units or repeat units incorporating structural elements in the main chain incorporating partially-aromatic structural elements in the main chain containing heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/40—Polymerisation processes
    • C08G2261/41—Organometallic coupling reactions
    • C08G2261/418—Ring opening metathesis polymerisation [ROMP]
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/40—Polymerisation processes
    • C08G2261/41—Organometallic coupling reactions
    • C08G2261/419—Acyclic diene metathesis [ADMET]
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/70—Post-treatment
    • C08G2261/72—Derivatisation

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Silicon Polymers (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)

Abstract

1)Copolymère à blocs alternés de formule (I): dans laquelle : - F1 et F2 sont 2 groupements de type alcoxysilane ; - R1 à R12 représentent un atome d'hydrogène ou un radical alkyle comprenant de 1 à 22 atomes de carbone ; - A représente O ou le groupe NR14 où R14 est un atome d'hydrogène ou un radical alkyle comprenant de 1 à 20 atomes de carbone ; - X représente un radical divalent comprenant un radical polymérique divalent T qui est relié directement ou indirectement à A, ledit radical T comprenant lui-même au moins un radical polyéther ; - x et y sont des entiers allant de 0 à 6, la somme x + y étant comprise dans une fourchette allant de 0 à 6 ; n1 et n2 sont un nombre entier ou nul ; m est un entier supérieur ou égal à 0 ; p1 et p2 sont un nombre entier ou nul dont la somme p1 + p2 est non nulle 2) Procédé de préparation dudit copolymère à partir de cyclooctadiène, d'un polymère (B) à groupes terminaux diacrylate, et d'un agent de transfert de chaîne (G) comprenant 2 groupements alcoxysilane. 3) Composition adhésive comprenant ledit copolymère et de 0,01 à 3% en poids d'un catalyseur de réticulation.
FR1859622A 2018-10-18 2018-10-18 Copolymeres hydrocarbones a blocs alternes et groupements terminaux alcoxysilanes Expired - Fee Related FR3087442B1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
FR1859622A FR3087442B1 (fr) 2018-10-18 2018-10-18 Copolymeres hydrocarbones a blocs alternes et groupements terminaux alcoxysilanes
PCT/FR2019/052458 WO2020079370A1 (fr) 2018-10-18 2019-10-17 Copolymeres hydrocarbones a blocs alternes et groupements terminaux alcoxysilanes

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Application Number Priority Date Filing Date Title
FR1859622A FR3087442B1 (fr) 2018-10-18 2018-10-18 Copolymeres hydrocarbones a blocs alternes et groupements terminaux alcoxysilanes

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FR3087442A1 FR3087442A1 (fr) 2020-04-24
FR3087442B1 true FR3087442B1 (fr) 2020-10-02

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WO (1) WO2020079370A1 (fr)

Family Cites Families (22)

* Cited by examiner, † Cited by third party
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DE3825637A1 (de) 1988-07-28 1990-03-08 Rwe Dea Ag Sekundaere polyetheramine, ihre herstellung und verwendung zur herstellung von polyharnstoffen
US4994621A (en) 1989-04-17 1991-02-19 Texaco Chemical Company Aminated, alkoxylated hydroxyl-terminated polybutadienes
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GB9111794D0 (en) 1991-05-31 1991-07-24 Robins David J Antifungal compounds
EP1253156A3 (fr) 1992-04-03 2004-01-07 California Institute Of Technology Composé ruthénium et osmium métal-carbène avec haute activité de la méthathèse d'oléfines, et leur préparation et utilisation
US5362913A (en) 1992-11-16 1994-11-08 Huntsman Corporation Saturated, aminated, alkoxylated polybutadienes
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US6175037B1 (en) 1998-10-09 2001-01-16 Ucb, S.A. Process for the preparation of (meth)acrylate esters and polyester (meth)acrylates using microwave energy as a heating source
GB9916235D0 (en) 1999-07-09 1999-09-15 Univ Durham Process for polymerisation of olefins and novel polymerisable olefins
US6943213B2 (en) 2003-08-13 2005-09-13 Acushnet Company Polyalkylacrylate compounds for use in golf balls
WO2001083097A2 (fr) 2000-05-04 2001-11-08 University Of Florida Metathese d'olefines allyliques fonctionnalisees
DE10101387A1 (de) 2001-01-13 2002-07-18 Merck Patent Gmbh Polyester mit Methacrylatendgruppen
DE10228540A1 (de) 2002-06-26 2004-01-22 Ivoclar Vivadent Ag Dentalmaterialien auf der Basis von Hydroxyalkylacrylamiden
CN101253206A (zh) 2005-09-02 2008-08-27 三井化学聚氨酯株式会社 （甲基）丙烯酸酯接枝聚醚型多元醇及其制造方法和用途
ATE437895T1 (de) 2006-02-09 2009-08-15 Sartomer Technology Co Inc Polybutadienzusammensetzungen, verfahren und gegenstände
US8283410B2 (en) 2009-03-30 2012-10-09 Isp Investments Inc. Ring-opening metathesis polymerization of norbornene and oxanorbornene moieties and uses thereof
JP6025476B2 (ja) 2012-09-21 2016-11-16 昭和電工株式会社 エチレン性不飽和基含有イソシアネート化合物の製造方法
FR2997957B1 (fr) 2012-11-12 2015-01-16 Bostik Sa Adhesif de lamination bicomposant d'origine renouvelable
EP2886578A1 (fr) 2013-12-20 2015-06-24 Nitto Denko Corporation Adhésif cutané hydrophile
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WO2018002473A1 (fr) 2016-06-29 2018-01-04 Bostik Sa Nouveaux polymères hydrocarbonés à deux groupements terminaux alcoxysilanes et leurs procédés de préparation

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FR3087442A1 (fr) 2020-04-24

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