FR3080112B1 - Procede de conditionnement de dechets de borates par cimentation - Google Patents
Procede de conditionnement de dechets de borates par cimentation Download PDFInfo
- Publication number
- FR3080112B1 FR3080112B1 FR1853331A FR1853331A FR3080112B1 FR 3080112 B1 FR3080112 B1 FR 3080112B1 FR 1853331 A FR1853331 A FR 1853331A FR 1853331 A FR1853331 A FR 1853331A FR 3080112 B1 FR3080112 B1 FR 3080112B1
- Authority
- FR
- France
- Prior art keywords
- cement
- conditioning
- waste
- borates
- borate waste
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000004568 cement Substances 0.000 title abstract 4
- 239000002699 waste material Substances 0.000 title abstract 4
- 230000003750 conditioning effect Effects 0.000 title abstract 3
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 title 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 abstract 3
- 150000001642 boronic acid derivatives Chemical class 0.000 abstract 2
- 239000001506 calcium phosphate Substances 0.000 abstract 2
- 229910000389 calcium phosphate Inorganic materials 0.000 abstract 2
- 235000011010 calcium phosphates Nutrition 0.000 abstract 2
- 239000003153 chemical reaction reagent Substances 0.000 abstract 2
- 159000000011 group IA salts Chemical class 0.000 abstract 2
- 239000011159 matrix material Substances 0.000 abstract 2
- 235000011007 phosphoric acid Nutrition 0.000 abstract 2
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 abstract 2
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 abstract 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 229910000165 zinc phosphate Inorganic materials 0.000 abstract 1
- 239000002672 zinc phosphate cement Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/34—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing cold phosphate binders
- C04B28/342—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing cold phosphate binders the phosphate binder being present in the starting composition as a mixture of free acid and one or more reactive oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
- B09B3/20—Agglomeration, binding or encapsulation of solid waste
- B09B3/25—Agglomeration, binding or encapsulation of solid waste using mineral binders or matrix
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/04—Treating liquids
- G21F9/06—Processing
- G21F9/16—Processing by fixation in stable solid media
- G21F9/162—Processing by fixation in stable solid media in an inorganic matrix, e.g. clays, zeolites
- G21F9/165—Cement or cement-like matrix
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/28—Treating solids
- G21F9/30—Processing
- G21F9/301—Processing by fixation in stable solid media
- G21F9/302—Processing by fixation in stable solid media in an inorganic matrix
- G21F9/304—Cement or cement-like matrix
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00241—Physical properties of the materials not provided for elsewhere in C04B2111/00
- C04B2111/00258—Electromagnetic wave absorbing or shielding materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00862—Uses not provided for elsewhere in C04B2111/00 for nuclear applications, e.g. ray-absorbing concrete
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- General Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Physics & Mathematics (AREA)
- High Energy & Nuclear Physics (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Environmental & Geological Engineering (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
La présente invention concerne un procédé de conditionnement de déchets à base de borates et sels alcalins par immobilisation dans une matrice de cimentation dans lequel on mélange les dits déchets à des réactifs conduisant à un ciment de phosphate de zinc et/ou de phosphate de calcium, les dits réactifs comprenant de d'acide phosphorique H3PO4 dans de l'eau et ZnO pour le ciment de phosphate de zinc et CaO pour le ciment de phosphate de calcium. La présente invention concerne également une matrice cimentaire comprenant des déchets à base de borates et sels alcalins obtenue par un procédé de conditionnement selon l'invention.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1853331A FR3080112B1 (fr) | 2018-04-17 | 2018-04-17 | Procede de conditionnement de dechets de borates par cimentation |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1853331A FR3080112B1 (fr) | 2018-04-17 | 2018-04-17 | Procede de conditionnement de dechets de borates par cimentation |
FR1853331 | 2018-04-17 |
Publications (2)
Publication Number | Publication Date |
---|---|
FR3080112A1 FR3080112A1 (fr) | 2019-10-18 |
FR3080112B1 true FR3080112B1 (fr) | 2020-05-01 |
Family
ID=63722462
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR1853331A Active FR3080112B1 (fr) | 2018-04-17 | 2018-04-17 | Procede de conditionnement de dechets de borates par cimentation |
Country Status (1)
Country | Link |
---|---|
FR (1) | FR3080112B1 (fr) |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2603116C2 (de) * | 1976-01-28 | 1983-01-27 | Nukem Gmbh, 6450 Hanau | Verfahren zur Verfestigung von radioaktiven borathaltigen wäßrigen Lösungen und Suspensionen |
SE412658B (sv) * | 1977-07-05 | 1980-03-10 | Asea Atom Ab | Sett att i cement bedda in borsyra- eller borathaltigt radioaktivt avfall |
DE3215508C2 (de) * | 1982-04-26 | 1986-11-06 | Kernforschungszentrum Karlsruhe Gmbh, 7500 Karlsruhe | Verfahren zur Verbesserung der Radionuklid-Rückhalteeigenschaften von Verfestigungen radioaktiver Abfälle |
FR2579360B1 (fr) * | 1985-03-21 | 1992-03-06 | Sgn Soc Gen Tech Nouvelle | Procede et dispositif pour le conditionnement, par liants hydrauliques, d'effluents radioactifs de faible et moyenne activite |
FR2623007B1 (fr) * | 1987-11-06 | 1990-03-23 | Lafarge Coppee | Systemes de pre-traitement et de traitement de resines echangeuses d'ions radioactives et procede de traitement correspondant |
FR2901270B1 (fr) * | 2006-05-18 | 2008-08-22 | Commissariat Energie Atomique | Composition a base de ciment pour l'enrobage d'une solution aqueuse contenant du bore, procede d'enrobage et composition de coulis cimentaire |
JP6672014B2 (ja) * | 2015-03-16 | 2020-03-25 | 株式会社東芝 | 放射性廃液の処理方法 |
-
2018
- 2018-04-17 FR FR1853331A patent/FR3080112B1/fr active Active
Also Published As
Publication number | Publication date |
---|---|
FR3080112A1 (fr) | 2019-10-18 |
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