FR3076558B1 - SCINTILLATOR INCLUDING A CRYSTALLINE CATION HALOGENIDE DOPED BY EU2 + AND CO-DOPE BY SM2 + - Google Patents

SCINTILLATOR INCLUDING A CRYSTALLINE CATION HALOGENIDE DOPED BY EU2 + AND CO-DOPE BY SM2 + Download PDF

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Publication number
FR3076558B1
FR3076558B1 FR1850234A FR1850234A FR3076558B1 FR 3076558 B1 FR3076558 B1 FR 3076558B1 FR 1850234 A FR1850234 A FR 1850234A FR 1850234 A FR1850234 A FR 1850234A FR 3076558 B1 FR3076558 B1 FR 3076558B1
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FR
France
Prior art keywords
doped
halogenide
dope
scintillator including
crystalline
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR1850234A
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French (fr)
Other versions
FR3076558A1 (en
Inventor
Pieter Dorenbos
Karl Kramer
Mikhail Alekhin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Universitaet Bern
STICHTING TECHNISCHE WETENSCHAPPEN
Stichting voor de Technische Wetenschappen STW
Original Assignee
Universitaet Bern
STICHTING TECHNISCHE WETENSCHAPPEN
Stichting voor de Technische Wetenschappen STW
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Universitaet Bern, STICHTING TECHNISCHE WETENSCHAPPEN, Stichting voor de Technische Wetenschappen STW filed Critical Universitaet Bern
Priority to FR1850234A priority Critical patent/FR3076558B1/en
Priority to PCT/EP2019/050455 priority patent/WO2019137962A1/en
Priority to EP19700654.7A priority patent/EP3737731B1/en
Priority to EP19708231.6A priority patent/EP3737732B1/en
Priority to PCT/EP2019/050454 priority patent/WO2019137961A1/en
Publication of FR3076558A1 publication Critical patent/FR3076558A1/en
Priority to US16/926,548 priority patent/US11326100B2/en
Application granted granted Critical
Publication of FR3076558B1 publication Critical patent/FR3076558B1/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00Luminescent, e.g. electroluminescent, chemiluminescent materials
    • C09K11/08Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
    • C09K11/77Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals
    • C09K11/7783Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals containing two or more rare earth metals one of which being europium
    • C09K11/779Halogenides
    • C09K11/7791Halogenides with alkali or alkaline earth metals

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Luminescent Compositions (AREA)
  • Measurement Of Radiation (AREA)

Abstract

L'invention concerne un matériau scintillateur comprenant un halogénure de cation cristallin dopé par Eu2+ et co-dopé par Sm2+. Le co-dopage par Sm déplace le pic d'émission de lumière de scintillation vers un domaine de faible auto-absorbance du matériauThe invention relates to a scintillator material comprising a crystalline cation halide doped with Eu2 + and co-doped with Sm2 +. Sm co-doping shifts the scintillation light emission peak to a low self-absorbance domain of the material

FR1850234A 2018-01-11 2018-01-11 SCINTILLATOR INCLUDING A CRYSTALLINE CATION HALOGENIDE DOPED BY EU2 + AND CO-DOPE BY SM2 + Active FR3076558B1 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
FR1850234A FR3076558B1 (en) 2018-01-11 2018-01-11 SCINTILLATOR INCLUDING A CRYSTALLINE CATION HALOGENIDE DOPED BY EU2 + AND CO-DOPE BY SM2 +
PCT/EP2019/050455 WO2019137962A1 (en) 2018-01-11 2019-01-09 Scintillator material comprising a crystalline cation halide doped by eu2+ and co-doped by sm2+
EP19700654.7A EP3737731B1 (en) 2018-01-11 2019-01-09 Scintillator material comprising a crystalline cation halide doped by eu2+ and co-doped by sm2+
EP19708231.6A EP3737732B1 (en) 2018-01-11 2019-01-09 Scintillator material comprising a crystalline alkaline-earth halide doped with an activator and co-doped with sm2+
PCT/EP2019/050454 WO2019137961A1 (en) 2018-01-11 2019-01-09 Scintillator material comprising a crystalline alkaline-earth halide doped with an activator and co-doped with sm2+
US16/926,548 US11326100B2 (en) 2018-01-11 2020-07-10 Scintillator including a material doped with an activator and co-dopant and radiation detector including the scintillator

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1850234A FR3076558B1 (en) 2018-01-11 2018-01-11 SCINTILLATOR INCLUDING A CRYSTALLINE CATION HALOGENIDE DOPED BY EU2 + AND CO-DOPE BY SM2 +
FR1850234 2018-01-11

Publications (2)

Publication Number Publication Date
FR3076558A1 FR3076558A1 (en) 2019-07-12
FR3076558B1 true FR3076558B1 (en) 2020-08-28

Family

ID=62528531

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1850234A Active FR3076558B1 (en) 2018-01-11 2018-01-11 SCINTILLATOR INCLUDING A CRYSTALLINE CATION HALOGENIDE DOPED BY EU2 + AND CO-DOPE BY SM2 +

Country Status (1)

Country Link
FR (1) FR3076558B1 (en)

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL176618C (en) * 1974-10-01 1985-05-01 Philips Nv LUMINESCENT SCREEN, PROCESS FOR THE PREPARATION OF A LUMINESCENT NATURAL ALKALINE METAL FLUORIDE HALOGENIDE ACTIVATED WITH TWO-VALUE EUROPE.
US3988252A (en) * 1974-11-11 1976-10-26 E. I. Du Pont De Nemours And Company Process for the production of Ba(Sr)FCl:Eu phosphors
JPS5944334B2 (en) * 1978-12-21 1984-10-29 富士写真フイルム株式会社 fluorescent material
ATE513940T1 (en) * 2004-04-12 2011-07-15 Stella Chemifa Corp MIXED CRYSTAL MATERIAL OF RARE EARTH ELEMENT FLUORIDE (POLYCRYSTAL AND SINGLE CRYSTAL) AND RADIATION DETECTOR AND TEST APPARATUS

Also Published As

Publication number Publication date
FR3076558A1 (en) 2019-07-12

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