FR3056983B1 - Copolymere anionique epaississant - Google Patents
Copolymere anionique epaississant Download PDFInfo
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- FR3056983B1 FR3056983B1 FR1659429A FR1659429A FR3056983B1 FR 3056983 B1 FR3056983 B1 FR 3056983B1 FR 1659429 A FR1659429 A FR 1659429A FR 1659429 A FR1659429 A FR 1659429A FR 3056983 B1 FR3056983 B1 FR 3056983B1
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- monomer
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- anionic copolymer
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
- C09D1/10—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances lime
- C09D1/12—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances lime with organic additives
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- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F216/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
- C08F216/12—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
- C08F216/14—Monomers containing only one unsaturated aliphatic radical
- C08F216/1416—Monomers containing oxygen in addition to the ether oxygen, e.g. allyl glycidyl ether
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08F216/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
- C08F216/12—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
- C08F216/14—Monomers containing only one unsaturated aliphatic radical
- C08F216/1416—Monomers containing oxygen in addition to the ether oxygen, e.g. allyl glycidyl ether
- C08F216/1425—Monomers containing side chains of polyether groups
- C08F216/1433—Monomers containing side chains of polyethylene oxide groups
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- C—CHEMISTRY; METALLURGY
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F216/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
- C08F216/12—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
- C08F216/14—Monomers containing only one unsaturated aliphatic radical
- C08F216/1416—Monomers containing oxygen in addition to the ether oxygen, e.g. allyl glycidyl ether
- C08F216/1425—Monomers containing side chains of polyether groups
- C08F216/1441—Monomers containing side chains of polypropylene oxide groups
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
- C08F220/285—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing a polyether chain in the alcohol moiety
- C08F220/288—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing a polyether chain in the alcohol moiety and containing polypropylene-co-ethylene oxide in the alcohol moiety
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- C—CHEMISTRY; METALLURGY
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
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- C—CHEMISTRY; METALLURGY
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K3/34—Silicon-containing compounds
- C08K3/346—Clay
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/41—Compounds containing sulfur bound to oxygen
- C08K5/42—Sulfonic acids; Derivatives thereof
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- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/04—Thixotropic paints
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/43—Thickening agents
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/43—Thickening agents
- C09D7/44—Combinations of two or more thickening agents
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- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
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- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/58—Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/60—Polyalkenylalcohols; Polyalkenylethers; Polyalkenylesters
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- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
- C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
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- C—CHEMISTRY; METALLURGY
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- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
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- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Polymerisation Methods In General (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
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Abstract
L'invention concerne un copolymère obtenu par réaction d'au moins trois comonomères, un premier monomère anionique, un deuxième monomère comprenant une insaturation oléfinique, un troisième monomère comprenant un groupement hydrophobe. L'invention concerne également l'utilisation de ce copolymère comme agent épaississant, notamment dans des suspensions aqueuse de particules minérales à extrait sec élevé. Le copolymère selon l'invention permet d'améliorer le compromis entre la viscosité sous haut gradient de cisaillement et la viscosité sous faible gradient de cisaillement, tout en améliorant la rétention d'eau au sein de la suspension.
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1659429A FR3056983B1 (fr) | 2016-09-30 | 2016-09-30 | Copolymere anionique epaississant |
PCT/FR2017/052670 WO2018060652A1 (fr) | 2016-09-30 | 2017-09-29 | Copolymère anionique épaississant |
US16/327,020 US11214641B2 (en) | 2016-09-30 | 2017-09-29 | Thickening anionic copolymer |
BR112019003508-7A BR112019003508B1 (pt) | 2016-09-30 | 2017-09-29 | Copolímero, composição aquosa, produto, agente espessante, usos de uma composição aquosa e de um agente |
EP17787505.1A EP3519472A1 (fr) | 2016-09-30 | 2017-09-29 | Copolymère anionique épaississant |
CN201780055235.2A CN109689712B (zh) | 2016-09-30 | 2017-09-29 | 增稠阴离子共聚物 |
JP2019507311A JP7312696B2 (ja) | 2016-09-30 | 2017-09-29 | 増粘陰イオンコポリマー |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1659429 | 2016-09-30 | ||
FR1659429A FR3056983B1 (fr) | 2016-09-30 | 2016-09-30 | Copolymere anionique epaississant |
Publications (2)
Publication Number | Publication Date |
---|---|
FR3056983A1 FR3056983A1 (fr) | 2018-04-06 |
FR3056983B1 true FR3056983B1 (fr) | 2020-05-22 |
Family
ID=57796493
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR1659429A Active FR3056983B1 (fr) | 2016-09-30 | 2016-09-30 | Copolymere anionique epaississant |
Country Status (7)
Country | Link |
---|---|
US (1) | US11214641B2 (fr) |
EP (1) | EP3519472A1 (fr) |
JP (1) | JP7312696B2 (fr) |
CN (1) | CN109689712B (fr) |
BR (1) | BR112019003508B1 (fr) |
FR (1) | FR3056983B1 (fr) |
WO (1) | WO2018060652A1 (fr) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3981596A4 (fr) * | 2019-06-07 | 2023-06-07 | Mitsui Chemicals, Inc. | Agent de revêtement et corps stratifié |
CN110172841B (zh) * | 2019-06-08 | 2021-10-22 | 五邑大学 | 一种通用型数码喷墨印花打底浆及其制备方法 |
FR3098822B1 (fr) * | 2019-07-18 | 2022-07-15 | Coatex Sas | Composition aqueuse de revêtement |
FR3104594B1 (fr) * | 2019-12-16 | 2022-06-24 | Coatex Sas | Composition aqueuse thermo-stabilisée |
CN111961212B (zh) * | 2020-08-28 | 2023-02-07 | 浙江九本环保技术有限公司 | 一种造纸用流变增稠保水剂、制备方法及应用 |
CN112708068B (zh) * | 2020-12-21 | 2022-08-09 | 杭州有氧品牌管理有限公司 | 一种水溶性梳状聚合物超分子体系及其应用 |
CN112538169B (zh) * | 2020-12-30 | 2023-12-29 | 杭州诺莘科技有限责任公司 | 同时含有负电荷及疏水基团的聚合物超分子体系及其应用 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3817584B2 (ja) * | 1998-03-04 | 2006-09-06 | サンノプコ株式会社 | 水系コーティング剤用改質剤 |
JP2000319054A (ja) | 1999-03-09 | 2000-11-21 | Nippon Shokubai Co Ltd | セメント添加剤 |
FR2810261B1 (fr) | 2000-06-15 | 2002-08-30 | Coatex Sa | Utilisation de copolymeres faiblement anioniques comme agent dispersant et/ou d'aide au broyage de suspension aqueuse de matieres minerales, suspensions aqueuses obtenues et leurs utilisations |
US7288616B2 (en) | 2002-01-18 | 2007-10-30 | Lubrizol Advanced Materials, Inc. | Multi-purpose polymers, methods and compositions |
FR2956862B1 (fr) | 2010-02-26 | 2013-03-15 | Coatex Sas | Monomere associatif a base d'alcools oxo, polymere acrylique contenant ce monomere, utilisation dudit polymere comme epaississant dans une formulation aqueuse, formulation obtenue. |
EP2591010B1 (fr) | 2010-07-09 | 2014-12-03 | Lubrizol Advanced Materials, Inc. | Mélanges d'épaississants de type copolymères acryliques |
FR2963939B1 (fr) * | 2010-08-19 | 2013-11-15 | Coatex Sas | Utilisation en sauces de couchage papetieres de polymeres (meth)acryliques peignes amphiphiles et non hydrosolubles |
FR2972349B1 (fr) * | 2011-03-07 | 2013-04-05 | Coatex Sas | Formulation cosmetique contenant un copolymere amphiphile non hydrosoluble comme agent epaississant. |
EP2935358A4 (fr) * | 2012-12-21 | 2016-05-11 | Rhodia Operations | Compositions anti-décantation et épaississante et leurs procédés d'utilisation |
EP2933280B1 (fr) | 2014-04-18 | 2016-10-12 | Rhodia Opérations | Polymère modificateur de rhéologie |
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2016
- 2016-09-30 FR FR1659429A patent/FR3056983B1/fr active Active
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2017
- 2017-09-29 JP JP2019507311A patent/JP7312696B2/ja active Active
- 2017-09-29 US US16/327,020 patent/US11214641B2/en active Active
- 2017-09-29 WO PCT/FR2017/052670 patent/WO2018060652A1/fr unknown
- 2017-09-29 EP EP17787505.1A patent/EP3519472A1/fr active Pending
- 2017-09-29 CN CN201780055235.2A patent/CN109689712B/zh active Active
- 2017-09-29 BR BR112019003508-7A patent/BR112019003508B1/pt active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
FR3056983A1 (fr) | 2018-04-06 |
CN109689712A (zh) | 2019-04-26 |
US20190211125A1 (en) | 2019-07-11 |
WO2018060652A1 (fr) | 2018-04-05 |
CN109689712B (zh) | 2022-01-04 |
JP7312696B2 (ja) | 2023-07-21 |
BR112019003508A2 (pt) | 2019-05-21 |
BR112019003508B1 (pt) | 2023-01-10 |
US11214641B2 (en) | 2022-01-04 |
EP3519472A1 (fr) | 2019-08-07 |
JP2020502285A (ja) | 2020-01-23 |
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