FR3037951B1 - Nouveau procede de transformation de sucres et sucres alcools en composes mono- et polyoxygenes en presence d'un catalyseur heterogene - Google Patents

Nouveau procede de transformation de sucres et sucres alcools en composes mono- et polyoxygenes en presence d'un catalyseur heterogene Download PDF

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FR3037951B1
FR3037951B1 FR1555966A FR1555966A FR3037951B1 FR 3037951 B1 FR3037951 B1 FR 3037951B1 FR 1555966 A FR1555966 A FR 1555966A FR 1555966 A FR1555966 A FR 1555966A FR 3037951 B1 FR3037951 B1 FR 3037951B1
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chosen
mono
sugar alcohols
heterogeneous catalyst
new process
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FR1555966A
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FR3037951A1 (fr
Inventor
Emilie BRULE
Etienne Girard
Amandine Cabiac
Damien Delcroix
Marc Jacquin
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IFP Energies Nouvelles IFPEN
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IFP Energies Nouvelles IFPEN
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Priority to FR1555966A priority Critical patent/FR3037951B1/fr
Priority to US15/739,921 priority patent/US10252960B2/en
Priority to CN201680037587.0A priority patent/CN107709280B/zh
Priority to PCT/EP2016/058820 priority patent/WO2016206826A1/fr
Publication of FR3037951A1 publication Critical patent/FR3037951A1/fr
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C27/00—Processes involving the simultaneous production of more than one class of oxygen-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B01J23/34—Manganese
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G23/00—Compounds of titanium
    • C01G23/003—Titanates
    • C01G23/006—Alkaline earth titanates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G25/00—Compounds of zirconium
    • C01G25/02—Oxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C01G45/12—Manganates manganites or permanganates
    • C01G45/1221—Manganates or manganites with a manganese oxidation state of Mn(III), Mn(IV) or mixtures thereof
    • C01G45/125—Manganates or manganites with a manganese oxidation state of Mn(III), Mn(IV) or mixtures thereof of the type[MnO3]n-, e.g. Li2MnO3, Li2[MxMn1-xO3], (La,Sr)MnO3
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by elimination of -OH groups, e.g. by dehydration
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/18—Polyhydroxylic acyclic alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
    • C07H3/00—Compounds containing only hydrogen atoms and saccharide radicals having only carbon, hydrogen, and oxygen atoms
    • C07H3/02—Monosaccharides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
    • C07H3/00—Compounds containing only hydrogen atoms and saccharide radicals having only carbon, hydrogen, and oxygen atoms
    • C07H3/06—Oligosaccharides, i.e. having three to five saccharide radicals attached to each other by glycosidic linkages
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/30—Three-dimensional structures
    • C01P2002/34—Three-dimensional structures perovskite-type (ABO3)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00—Formation or introduction of functional groups containing oxygen
    • C07B41/06—Formation or introduction of functional groups containing oxygen of carbonyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00—Formation or introduction of functional groups containing oxygen
    • C07B41/08—Formation or introduction of functional groups containing oxygen of carboxyl groups or salts, halides or anhydrides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00—Formation or introduction of functional groups containing oxygen
    • C07B41/12—Formation or introduction of functional groups containing oxygen of carboxylic acid ester groups
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Molecular Biology (AREA)
  • Biotechnology (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

L'invention concerne un procédé de transformation d'une charge choisie parmi les sucres ou les sucres alcools, seuls ou en mélange, en composés mono- ou polyoxygénés, dans lequel la charge est mise en contact avec au moins un catalyseur hétérogène comprenant un support choisi parmi les pérovskites de formule ABO3 dans laquelle A est choisi parmi les éléments Mg, Ca, Sr et Ba, et B est choisi parmi les éléments Fe, Mn, Ti et Zr, et les oxydes des éléments choisis parmi le lanthane, le néodyme, l'yttrium, le cérium, seuls ou en mélange, lesdits oxydes pouvant être dopés par au moins un élément choisi parmi les métaux alcalins, les alcalino-terreux et les terres rares, sous atmosphère réductrice, et à une température comprise entre 100°C et 300°C, et à une pression comprise entre 0,1 MPa et 50 MPa.
FR1555966A 2015-06-26 2015-06-26 Nouveau procede de transformation de sucres et sucres alcools en composes mono- et polyoxygenes en presence d'un catalyseur heterogene Active FR3037951B1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
FR1555966A FR3037951B1 (fr) 2015-06-26 2015-06-26 Nouveau procede de transformation de sucres et sucres alcools en composes mono- et polyoxygenes en presence d'un catalyseur heterogene
US15/739,921 US10252960B2 (en) 2015-06-26 2016-04-21 Method for transforming sugars and sugar alcohols into mono- and poly-oxidized compounds in the presence of a heterogeneous catalyst
CN201680037587.0A CN107709280B (zh) 2015-06-26 2016-04-21 在多相催化剂存在下将糖和糖醇转化为单氧化和多氧化化合物的方法
PCT/EP2016/058820 WO2016206826A1 (fr) 2015-06-26 2016-04-21 Nouveau procede de transformation de sucres et sucres alcools en composes mono- et polyoxygenes en presence d'un catalyseur heterogene

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1555966A FR3037951B1 (fr) 2015-06-26 2015-06-26 Nouveau procede de transformation de sucres et sucres alcools en composes mono- et polyoxygenes en presence d'un catalyseur heterogene
FR1555966 2015-06-26

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FR3037951A1 FR3037951A1 (fr) 2016-12-30
FR3037951B1 true FR3037951B1 (fr) 2019-05-10

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FR1555966A Active FR3037951B1 (fr) 2015-06-26 2015-06-26 Nouveau procede de transformation de sucres et sucres alcools en composes mono- et polyoxygenes en presence d'un catalyseur heterogene

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US (1) US10252960B2 (fr)
CN (1) CN107709280B (fr)
FR (1) FR3037951B1 (fr)
WO (1) WO2016206826A1 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107020102B (zh) * 2017-04-26 2019-05-31 浙江大学 一种镍-铬酸镁催化剂及其制备方法以及在甘油制备乙醇中的应用
CN109046379A (zh) * 2018-06-29 2018-12-21 华东师范大学 一种钙钛矿复合氧化物负载铂催化剂及其制备和应用
CN109806886B (zh) * 2019-03-15 2021-07-20 中国科学院山西煤炭化学研究所 一种甘油氧化制备二羟基丙酮的催化剂及其制备方法和应用

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4366332A (en) 1981-01-21 1982-12-28 Hydrocarbon Research, Inc. Catalytic hydrogenolysis of alditols to product glycerol and polyols
US4496780A (en) * 1983-06-22 1985-01-29 Uop Inc. Hydrocracking of polyols
US4880758A (en) * 1987-08-24 1989-11-14 The Dow Chemical Company Preparation of ABO3 compounds from mixed metal aromatic coordination complexes
KR20120098584A (ko) * 2009-06-30 2012-09-05 바이렌트, 아이엔씨. 당분 및 당알코올을 변환하기 위한 공정 및 반응기 시스템
FR3004182B1 (fr) * 2013-04-09 2015-03-27 IFP Energies Nouvelles Procede de transformation de biomasses lignocellulosiques en molecules mono ou poly-oxygenees
ITTO20130833A1 (it) 2013-10-16 2015-04-17 Biochemtex Spa Procedimento per la produzione di polioli
FR3026407B1 (fr) * 2014-09-26 2016-10-28 Ifp Energies Now Procede de transformation d'une charge comprenant une biomasse lignocellulosique utilisant un catalyseur homogene acide en combinaison avec un catalyseur heterogene comprenant un support specifique

Also Published As

Publication number Publication date
CN107709280B (zh) 2021-08-03
FR3037951A1 (fr) 2016-12-30
US20180179131A1 (en) 2018-06-28
CN107709280A (zh) 2018-02-16
WO2016206826A1 (fr) 2016-12-29
US10252960B2 (en) 2019-04-09

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