FR3030302B1 - THERMAL REDUCTION OF SULFUR - Google Patents

THERMAL REDUCTION OF SULFUR Download PDF

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Publication number
FR3030302B1
FR3030302B1 FR1463255A FR1463255A FR3030302B1 FR 3030302 B1 FR3030302 B1 FR 3030302B1 FR 1463255 A FR1463255 A FR 1463255A FR 1463255 A FR1463255 A FR 1463255A FR 3030302 B1 FR3030302 B1 FR 3030302B1
Authority
FR
France
Prior art keywords
sulfur
thermal reduction
thermal
reduction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR1463255A
Other languages
French (fr)
Other versions
FR3030302A1 (en
Inventor
Benoit Grand
Jacques Mulon
Xavier Paubel
Remi Tsiava
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Original Assignee
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Air Liquide SA, LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude filed Critical Air Liquide SA
Priority to FR1463255A priority Critical patent/FR3030302B1/en
Priority to CA2971982A priority patent/CA2971982C/en
Priority to PCT/FR2015/053737 priority patent/WO2016102900A1/en
Priority to RU2017123787A priority patent/RU2696477C2/en
Publication of FR3030302A1 publication Critical patent/FR3030302A1/en
Application granted granted Critical
Publication of FR3030302B1 publication Critical patent/FR3030302B1/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/005—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by heat treatment
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/02—Preparation of sulfur; Purification
    • C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
    • C01B17/0473—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by reaction of sulfur dioxide or sulfur trioxide containing gases with reducing agents other than hydrogen sulfide
    • C01B17/0478—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by reaction of sulfur dioxide or sulfur trioxide containing gases with reducing agents other than hydrogen sulfide with hydrocarbons or mixtures containing them
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/02—Preparation of sulfur; Purification
    • C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
    • C01B17/0473—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by reaction of sulfur dioxide or sulfur trioxide containing gases with reducing agents other than hydrogen sulfide
    • C01B17/0491—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by reaction of sulfur dioxide or sulfur trioxide containing gases with reducing agents other than hydrogen sulfide with hydrogen or hydrogen-containing mixtures, e.g. synthesis gas
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23D—BURNERS
    • F23D14/00—Burners for combustion of a gas, e.g. of a gas stored under pressure as a liquid
    • F23D14/20—Non-premix gas burners, i.e. in which gaseous fuel is mixed with combustion air on arrival at the combustion zone
    • F23D14/22—Non-premix gas burners, i.e. in which gaseous fuel is mixed with combustion air on arrival at the combustion zone with separate air and gas feed ducts, e.g. with ducts running parallel or crossing each other
    • F23D14/24—Non-premix gas burners, i.e. in which gaseous fuel is mixed with combustion air on arrival at the combustion zone with separate air and gas feed ducts, e.g. with ducts running parallel or crossing each other at least one of the fluids being submitted to a swirling motion
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23D—BURNERS
    • F23D14/00—Burners for combustion of a gas, e.g. of a gas stored under pressure as a liquid
    • F23D14/32—Burners for combustion of a gas, e.g. of a gas stored under pressure as a liquid using a mixture of gaseous fuel and pure oxygen or oxygen-enriched air
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • F23G7/06—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases
    • F23G7/061—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases with supplementary heating
    • F23G7/065—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases with supplementary heating using gaseous or liquid fuel
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00—Arrangements of devices for treating smoke or fumes
    • F23J15/06—Arrangements of devices for treating smoke or fumes of coolers
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
    • F23L7/00—Supplying non-combustible liquids or gases, other than air, to the fire, e.g. oxygen, steam
    • F23L7/007—Supplying oxygen or oxygen-enriched air
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/302—Sulfur oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/12—Methods and means for introducing reactants
    • B01D2259/122—Gaseous reactants
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2206/00—Waste heat recuperation
    • F23G2206/20—Waste heat recuperation using the heat in association with another installation
    • F23G2206/203—Waste heat recuperation using the heat in association with another installation with a power/heat generating installation
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2207/00—Control
    • F23G2207/10—Arrangement of sensing devices
    • F23G2207/101—Arrangement of sensing devices for temperature
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2215/00—Preventing emissions
    • F23J2215/20—Sulfur; Compounds thereof
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2219/00—Treatment devices
    • F23J2219/70—Condensing contaminants with coolers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00—Combustion technologies with mitigation potential
    • Y02E20/12—Heat utilisation in combustion or incineration of waste
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00—Combustion technologies with mitigation potential
    • Y02E20/34—Indirect CO2mitigation, i.e. by acting on non CO2directly related matters of the process, e.g. pre-heating or heat recovery
FR1463255A 2014-12-23 2014-12-23 THERMAL REDUCTION OF SULFUR Active FR3030302B1 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
FR1463255A FR3030302B1 (en) 2014-12-23 2014-12-23 THERMAL REDUCTION OF SULFUR
CA2971982A CA2971982C (en) 2014-12-23 2015-12-22 Thermal reduction of sulfur
PCT/FR2015/053737 WO2016102900A1 (en) 2014-12-23 2015-12-22 Thermal reduction of sulfur
RU2017123787A RU2696477C2 (en) 2014-12-23 2015-12-22 Thermal reduction of sulphur

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1463255A FR3030302B1 (en) 2014-12-23 2014-12-23 THERMAL REDUCTION OF SULFUR
FR1463255 2014-12-23

Publications (2)

Publication Number Publication Date
FR3030302A1 FR3030302A1 (en) 2016-06-24
FR3030302B1 true FR3030302B1 (en) 2018-08-10

Family

ID=52692870

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1463255A Active FR3030302B1 (en) 2014-12-23 2014-12-23 THERMAL REDUCTION OF SULFUR

Country Status (4)

Country Link
CA (1) CA2971982C (en)
FR (1) FR3030302B1 (en)
RU (1) RU2696477C2 (en)
WO (1) WO2016102900A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108557774B (en) * 2018-06-27 2023-06-06 山东大学 Device and method for analyzing and reducing sulfur by active coke sulfur dioxide
CN111167274B (en) * 2020-01-19 2021-11-12 中南大学 Method for removing sulfur trioxide from smelting flue gas and removing device thereof

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1406085A (en) * 1972-09-15 1975-09-10 Shell Int Research Process for the recovery of sulphur from hydrogen sulphide and sulphur dioxide
US3947547A (en) * 1972-12-15 1976-03-30 Shell Oil Company Process for reducing total sulfur content of claus off-gases
JPS4998395A (en) 1973-01-02 1974-09-18
US4117101A (en) * 1975-10-16 1978-09-26 Davy Powergas Gmbh Process for reduction of SO2
DE2701920A1 (en) * 1977-01-19 1978-07-27 Bayer Ag METHOD FOR OBTAINING SULFUR FROM RESULTS CONTAINING SULFUR
US4207304A (en) 1977-06-27 1980-06-10 The Ralph M. Parsons Company Process for sulfur production
US4988287A (en) * 1989-06-20 1991-01-29 Phillips Petroleum Company Combustion apparatus and method
GB9814064D0 (en) * 1998-06-29 1998-08-26 Boc Group Plc Partial combustion of hydrogen sulphide
RU2221742C2 (en) * 2002-02-08 2004-01-20 Открытое акционерное общество "Институт Гипроникель" Method for production of elementary sulfur from emission gases containing sulfur dioxide
US7722852B2 (en) * 2007-07-05 2010-05-25 Worleyparsons Group, Inc. Process for the thermal reduction of sulfur dioxide to sulfur
FR2962787B1 (en) * 2010-07-13 2014-05-23 Fives Pillard BURNER FOR TREATING COMBUSTIBLE ACIDIC GAS AND ADAPTIVE REACTION FURNACE
US8465722B2 (en) * 2011-06-20 2013-06-18 Rameshni & Associates Technology & Engineering Thermal reduction of sulfur dioxide to sulfur with temperature controlled furnace
RU2474533C1 (en) * 2011-07-15 2013-02-10 Открытое акционерное общество "Гипрогазоочистка" Method of producing elementary sulphur from sulphur dioxide-containing exhaust gas
RU2012133249A (en) 2012-06-22 2014-02-10 Питер Фрэнк КРОСС ADVANCED SULFUR DIOXIDE CLEANING

Also Published As

Publication number Publication date
RU2017123787A3 (en) 2019-01-11
FR3030302A1 (en) 2016-06-24
WO2016102900A1 (en) 2016-06-30
RU2696477C2 (en) 2019-08-01
CA2971982C (en) 2022-09-27
RU2017123787A (en) 2019-01-10
CA2971982A1 (en) 2016-06-30

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