FR3008697B1 - Procede de dimerisation selective de l'ethylene en butene-1 utilisant une composition catalytique comprenant un complexe a base de titane additive en association avec un ligand alcoxy fonctionnalise par un hetero-atome - Google Patents
Procede de dimerisation selective de l'ethylene en butene-1 utilisant une composition catalytique comprenant un complexe a base de titane additive en association avec un ligand alcoxy fonctionnalise par un hetero-atomeInfo
- Publication number
- FR3008697B1 FR3008697B1 FR1357139A FR1357139A FR3008697B1 FR 3008697 B1 FR3008697 B1 FR 3008697B1 FR 1357139 A FR1357139 A FR 1357139A FR 1357139 A FR1357139 A FR 1357139A FR 3008697 B1 FR3008697 B1 FR 3008697B1
- Authority
- FR
- France
- Prior art keywords
- alcoxy
- functionalized
- butene
- hetero
- ligand
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 title 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title 1
- 239000005977 Ethylene Substances 0.000 title 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title 1
- 239000000654 additive Substances 0.000 title 1
- 230000000996 additive effect Effects 0.000 title 1
- 230000003197 catalytic effect Effects 0.000 title 1
- 230000000447 dimerizing effect Effects 0.000 title 1
- 239000003446 ligand Substances 0.000 title 1
- 229910052719 titanium Inorganic materials 0.000 title 1
- 239000010936 titanium Substances 0.000 title 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
- B01J31/0212—Alkoxylates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/26—Catalytic processes with hydrides or organic compounds
- C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/26—Catalytic processes with hydrides or organic compounds
- C07C2/36—Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/20—Olefin oligomerisation or telomerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/46—Titanium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- C07C2531/22—Organic complexes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- C07C2531/24—Phosphines
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1357139A FR3008697B1 (fr) | 2013-07-19 | 2013-07-19 | Procede de dimerisation selective de l'ethylene en butene-1 utilisant une composition catalytique comprenant un complexe a base de titane additive en association avec un ligand alcoxy fonctionnalise par un hetero-atome |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1357139A FR3008697B1 (fr) | 2013-07-19 | 2013-07-19 | Procede de dimerisation selective de l'ethylene en butene-1 utilisant une composition catalytique comprenant un complexe a base de titane additive en association avec un ligand alcoxy fonctionnalise par un hetero-atome |
Publications (2)
Publication Number | Publication Date |
---|---|
FR3008697A1 FR3008697A1 (fr) | 2015-01-23 |
FR3008697B1 true FR3008697B1 (fr) | 2015-07-31 |
Family
ID=49293739
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR1357139A Active FR3008697B1 (fr) | 2013-07-19 | 2013-07-19 | Procede de dimerisation selective de l'ethylene en butene-1 utilisant une composition catalytique comprenant un complexe a base de titane additive en association avec un ligand alcoxy fonctionnalise par un hetero-atome |
Country Status (1)
Country | Link |
---|---|
FR (1) | FR3008697B1 (fr) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111408412B (zh) * | 2019-01-04 | 2023-05-09 | 中国石油化工股份有限公司 | 一种催化剂组合物、其制备方法及其在乙烯选择性二聚化合成1-丁烯的反应中的应用 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2274583A1 (fr) * | 1974-06-14 | 1976-01-09 | Otdel I | Procede de preparation du butene-1 |
FR2552079B1 (fr) * | 1983-09-20 | 1986-10-03 | Inst Francais Du Petrole | Procede ameliore de synthese du butene-1 par dimerisation de l'ethylene |
FR2960234B1 (fr) * | 2010-05-18 | 2013-11-01 | Inst Francais Du Petrole | Procede de dimerisation de l'ethylene en butene-1 utilisant une composition comprenant un complexe a base de titane et un ligand alcoxy fonctionnalise par un hetero-atome. |
FR2960235B1 (fr) * | 2010-05-18 | 2013-11-01 | Inst Francais Du Petrole | Procede d'oligomerisation des olefines utilisant une composition comprenant un complexe organometallique contenant un ligand alcoxy fonctionnalise par un hetero-atome. |
-
2013
- 2013-07-19 FR FR1357139A patent/FR3008697B1/fr active Active
Also Published As
Publication number | Publication date |
---|---|
FR3008697A1 (fr) | 2015-01-23 |
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