FR2992648A1 - Catalyseur solide pour la polymerisation du propylene et procede de preparation du poly(propylene). - Google Patents
Catalyseur solide pour la polymerisation du propylene et procede de preparation du poly(propylene). Download PDFInfo
- Publication number
- FR2992648A1 FR2992648A1 FR1356146A FR1356146A FR2992648A1 FR 2992648 A1 FR2992648 A1 FR 2992648A1 FR 1356146 A FR1356146 A FR 1356146A FR 1356146 A FR1356146 A FR 1356146A FR 2992648 A1 FR2992648 A1 FR 2992648A1
- Authority
- FR
- France
- Prior art keywords
- dicarboxylic acid
- ester
- hept
- ene
- propylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011949 solid catalyst Substances 0.000 title claims abstract description 39
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 24
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 title claims description 20
- 238000004519 manufacturing process Methods 0.000 title abstract description 17
- 230000000379 polymerizing effect Effects 0.000 title 1
- -1 benzene-1,2-dicarboxylic acid ester Chemical class 0.000 claims abstract description 64
- 239000000203 mixture Substances 0.000 claims abstract description 17
- 239000004743 Polypropylene Substances 0.000 claims abstract description 14
- 238000006116 polymerization reaction Methods 0.000 claims description 31
- 238000000034 method Methods 0.000 claims description 25
- 229910052719 titanium Inorganic materials 0.000 claims description 22
- 239000010936 titanium Substances 0.000 claims description 21
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 19
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 16
- 238000002360 preparation method Methods 0.000 claims description 14
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 8
- 125000003118 aryl group Chemical group 0.000 claims description 8
- 229910052736 halogen Inorganic materials 0.000 claims description 7
- 150000002367 halogens Chemical class 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- 239000001257 hydrogen Substances 0.000 claims description 7
- 239000011777 magnesium Substances 0.000 claims description 7
- 229910052749 magnesium Inorganic materials 0.000 claims description 7
- 125000003342 alkenyl group Chemical group 0.000 claims description 4
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 4
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 4
- 238000007334 copolymerization reaction Methods 0.000 claims description 4
- 239000004711 α-olefin Substances 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims description 2
- 125000006165 cyclic alkyl group Chemical group 0.000 claims description 2
- 125000004122 cyclic group Chemical group 0.000 claims description 2
- 239000003426 co-catalyst Substances 0.000 claims 1
- 239000003054 catalyst Substances 0.000 abstract description 32
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 abstract description 4
- 230000003197 catalytic effect Effects 0.000 abstract description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 39
- 150000002148 esters Chemical class 0.000 description 35
- 239000002253 acid Substances 0.000 description 19
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 17
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical group CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 12
- NRIMHVFWRMABGJ-UHFFFAOYSA-N bicyclo[2.2.1]hepta-2,5-diene-2,3-dicarboxylic acid Chemical compound C1C2C(C(=O)O)=C(C(O)=O)C1C=C2 NRIMHVFWRMABGJ-UHFFFAOYSA-N 0.000 description 11
- UWNADWZGEHDQAB-UHFFFAOYSA-N 2,5-dimethylhexane Chemical group CC(C)CCC(C)C UWNADWZGEHDQAB-UHFFFAOYSA-N 0.000 description 10
- 239000000047 product Substances 0.000 description 10
- OJURWUUOVGOHJZ-UHFFFAOYSA-N methyl 2-[(2-acetyloxyphenyl)methyl-[2-[(2-acetyloxyphenyl)methyl-(2-methoxy-2-oxoethyl)amino]ethyl]amino]acetate Chemical compound C=1C=CC=C(OC(C)=O)C=1CN(CC(=O)OC)CCN(CC(=O)OC)CC1=CC=CC=C1OC(C)=O OJURWUUOVGOHJZ-UHFFFAOYSA-N 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 6
- XDRAKJQFCQVBMP-UHFFFAOYSA-N 2-but-2-enyl-3-methylbutanedioic acid Chemical compound CC=CCC(C(O)=O)C(C)C(O)=O XDRAKJQFCQVBMP-UHFFFAOYSA-N 0.000 description 5
- CUELKJPQZSFUHD-UHFFFAOYSA-N 5-methylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C(C)=CC1C(C(O)=O)C2C(O)=O CUELKJPQZSFUHD-UHFFFAOYSA-N 0.000 description 5
- ZDQWESQEGGJUCH-UHFFFAOYSA-N Diisopropyl adipate Chemical compound CC(C)OC(=O)CCCCC(=O)OC(C)C ZDQWESQEGGJUCH-UHFFFAOYSA-N 0.000 description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 230000037048 polymerization activity Effects 0.000 description 5
- YZJCSKJEZWDNFE-UHFFFAOYSA-N 2,3-dimethylbicyclo[2.2.1]hept-2-ene-5,6-dicarboxylic acid Chemical compound C1C2C(C)=C(C)C1C(C(O)=O)C2C(O)=O YZJCSKJEZWDNFE-UHFFFAOYSA-N 0.000 description 4
- BDVLRSSEIZGSPZ-UHFFFAOYSA-N 2-but-2-enyl-3-methylbut-2-enedioic acid Chemical compound CC=CCC(C(O)=O)=C(C)C(O)=O BDVLRSSEIZGSPZ-UHFFFAOYSA-N 0.000 description 4
- CGEMPWFQTSQCKJ-UHFFFAOYSA-N 2-butyl-3-methylbut-2-enedioic acid Chemical compound CCCCC(C(O)=O)=C(C)C(O)=O CGEMPWFQTSQCKJ-UHFFFAOYSA-N 0.000 description 4
- 239000004808 2-ethylhexylester Substances 0.000 description 4
- NZJOUWZTCUDLQF-UHFFFAOYSA-N 5-methylbicyclo[2.2.1]hept-2-ene-2,3-dicarboxylic acid Chemical compound C1C2C(C)CC1C(C(O)=O)=C2C(O)=O NZJOUWZTCUDLQF-UHFFFAOYSA-N 0.000 description 4
- SWLTXXZJAJWIQH-UHFFFAOYSA-N 5-methylbicyclo[2.2.1]hepta-2,5-diene-2,3-dicarboxylic acid Chemical compound C1C2C(C)=CC1C(C(O)=O)=C2C(O)=O SWLTXXZJAJWIQH-UHFFFAOYSA-N 0.000 description 4
- UQMBSZANGCZQFJ-UHFFFAOYSA-N 5-methylbicyclo[2.2.1]heptane-2,3-dicarboxylic acid Chemical compound C1C2C(C)CC1C(C(O)=O)C2C(O)=O UQMBSZANGCZQFJ-UHFFFAOYSA-N 0.000 description 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 239000006228 supernatant Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 230000032683 aging Effects 0.000 description 3
- 125000005234 alkyl aluminium group Chemical group 0.000 description 3
- DVWBKCSKPCZFDE-UHFFFAOYSA-N bicyclo[2.2.1]hept-2-ene-2,3-dicarboxylic acid Chemical compound C1CC2C(C(=O)O)=C(C(O)=O)C1C2 DVWBKCSKPCZFDE-UHFFFAOYSA-N 0.000 description 3
- JQCXWCOOWVGKMT-UHFFFAOYSA-N diheptyl phthalate Chemical compound CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC JQCXWCOOWVGKMT-UHFFFAOYSA-N 0.000 description 3
- 229910001629 magnesium chloride Inorganic materials 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- WZLHPCMSXVTARD-UHFFFAOYSA-N 2-hex-4-enylpropanedioic acid Chemical compound C(CCCC=CC)(C(=O)O)C(=O)O WZLHPCMSXVTARD-UHFFFAOYSA-N 0.000 description 2
- WYLDCOZZTAUHFQ-UHFFFAOYSA-N 5,6-dimethylbicyclo[2.2.1]hept-2-ene-2,3-dicarboxylic acid Chemical compound C1C2C(C)C(C)C1C(C(O)=O)=C2C(O)=O WYLDCOZZTAUHFQ-UHFFFAOYSA-N 0.000 description 2
- KIIPCDILPHDPGZ-UHFFFAOYSA-N 5,6-dimethylbicyclo[2.2.1]hepta-2,5-diene-2,3-dicarboxylic acid Chemical compound C1C2C(C)=C(C)C1C(C(O)=O)=C2C(O)=O KIIPCDILPHDPGZ-UHFFFAOYSA-N 0.000 description 2
- QFSDNIXBGBXFLN-UHFFFAOYSA-N 7,7-dimethylbicyclo[2.2.1]hept-2-ene Chemical compound C1CC2C=CC1C2(C)C QFSDNIXBGBXFLN-UHFFFAOYSA-N 0.000 description 2
- XOGIDBABTPKZFG-UHFFFAOYSA-N 7,7-dimethylbicyclo[2.2.1]heptane-2,3-dicarboxylic acid Chemical compound C1CC2C(C(O)=O)C(C(O)=O)C1C2(C)C XOGIDBABTPKZFG-UHFFFAOYSA-N 0.000 description 2
- KXJVWNBVRRZEHH-UHFFFAOYSA-N 7,7-dimethylbicyclo[2.2.1]heptane-2,3-dione Chemical compound C1CC2C(=O)C(=O)C1C2(C)C KXJVWNBVRRZEHH-UHFFFAOYSA-N 0.000 description 2
- XWVJOODPZPZFNH-UHFFFAOYSA-N CCCCCCCCOC(=O)C1=C(C2CC1CC2C)C(=O)OCCCCCCCC Chemical compound CCCCCCCCOC(=O)C1=C(C2CC1CC2C)C(=O)OCCCCCCCC XWVJOODPZPZFNH-UHFFFAOYSA-N 0.000 description 2
- KCXZNSGUUQJJTR-UHFFFAOYSA-N Di-n-hexyl phthalate Chemical compound CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCC KCXZNSGUUQJJTR-UHFFFAOYSA-N 0.000 description 2
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 2
- QWDBCIAVABMJPP-UHFFFAOYSA-N Diisopropyl phthalate Chemical compound CC(C)OC(=O)C1=CC=CC=C1C(=O)OC(C)C QWDBCIAVABMJPP-UHFFFAOYSA-N 0.000 description 2
- NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- ZKMAOZRBMWYOPG-UHFFFAOYSA-N dibutyl bicyclo[2.2.1]hept-5-ene-1,2-dicarboxylate Chemical compound CCCCOC(=O)C1CC2CC1(C=C2)C(=O)OCCCC ZKMAOZRBMWYOPG-UHFFFAOYSA-N 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- MNCJAYVXABHLQP-UHFFFAOYSA-N diethyl 5-methylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxylate Chemical compound C1C2C(C(=O)OCC)C(C(=O)OCC)C1C=C2C MNCJAYVXABHLQP-UHFFFAOYSA-N 0.000 description 2
- IPKKHRVROFYTEK-UHFFFAOYSA-N dipentyl phthalate Chemical compound CCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCC IPKKHRVROFYTEK-UHFFFAOYSA-N 0.000 description 2
- XJOXVWSVIQQKGX-UHFFFAOYSA-N dipropan-2-yl 5-methylbicyclo[2.2.1]hepta-2,5-diene-2,3-dicarboxylate Chemical compound C1C2C(C(=O)OC(C)C)=C(C(=O)OC(C)C)C1C(C)=C2 XJOXVWSVIQQKGX-UHFFFAOYSA-N 0.000 description 2
- WOBRYIORYXTKAW-UHFFFAOYSA-N dipropan-2-yl 5-methylbicyclo[2.2.1]heptane-2,3-dicarboxylate Chemical compound C1C(C)C2C(C(=O)OC(C)C)C(C(=O)OC(C)C)C1C2 WOBRYIORYXTKAW-UHFFFAOYSA-N 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000002431 foraging effect Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- XDKQUSKHRIUJEO-UHFFFAOYSA-N magnesium;ethanolate Chemical compound [Mg+2].CC[O-].CC[O-] XDKQUSKHRIUJEO-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 2
- MQHNKCZKNAJROC-UHFFFAOYSA-N phthalic acid dipropyl ester Natural products CCCOC(=O)C1=CC=CC=C1C(=O)OCCC MQHNKCZKNAJROC-UHFFFAOYSA-N 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000012798 spherical particle Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- HQYALQRYBUJWDH-UHFFFAOYSA-N trimethoxy(propyl)silane Chemical compound CCC[Si](OC)(OC)OC HQYALQRYBUJWDH-UHFFFAOYSA-N 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 description 1
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 description 1
- VFWCMGCRMGJXDK-UHFFFAOYSA-N 1-chlorobutane Chemical compound CCCCCl VFWCMGCRMGJXDK-UHFFFAOYSA-N 0.000 description 1
- DZMDPHNGKBEVRE-UHFFFAOYSA-N 1-chloroheptane Chemical compound CCCCCCCCl DZMDPHNGKBEVRE-UHFFFAOYSA-N 0.000 description 1
- MLRVZFYXUZQSRU-UHFFFAOYSA-N 1-chlorohexane Chemical compound CCCCCCCl MLRVZFYXUZQSRU-UHFFFAOYSA-N 0.000 description 1
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 1
- DGBKTJIQJQNAIN-UHFFFAOYSA-N 2-butyl-3-methylbutanedioic acid Chemical compound CCCCC(C(O)=O)C(C)C(O)=O DGBKTJIQJQNAIN-UHFFFAOYSA-N 0.000 description 1
- GTNYCMPSYUDFDV-UHFFFAOYSA-N 2-cycloheptylethyl(diethoxy)silane Chemical compound C1(CCCCCC1)CC[SiH](OCC)OCC GTNYCMPSYUDFDV-UHFFFAOYSA-N 0.000 description 1
- MAJUNVAKKQXKFN-UHFFFAOYSA-N 2-cycloheptylethyl(dimethoxy)silane Chemical compound CO[SiH](OC)CCC1CCCCCC1 MAJUNVAKKQXKFN-UHFFFAOYSA-N 0.000 description 1
- FBXFOZZBULDQCV-UHFFFAOYSA-N 2-cyclohexylethyl(diethoxy)silane Chemical compound CCO[SiH](OCC)CCC1CCCCC1 FBXFOZZBULDQCV-UHFFFAOYSA-N 0.000 description 1
- BODSXKKAYTVVLU-UHFFFAOYSA-N 2-cyclopentylethyl(diethoxy)silane Chemical compound CCO[SiH](OCC)CCC1CCCC1 BODSXKKAYTVVLU-UHFFFAOYSA-N 0.000 description 1
- OEUWCXGBWUORDL-UHFFFAOYSA-N 3-cycloheptylpropyl(diethoxy)silane Chemical compound C1(CCCCCC1)CCC[SiH](OCC)OCC OEUWCXGBWUORDL-UHFFFAOYSA-N 0.000 description 1
- HPIWHAUFTYWYHA-UHFFFAOYSA-N 3-cycloheptylpropyl(dimethoxy)silane Chemical compound CO[SiH](OC)CCCC1CCCCCC1 HPIWHAUFTYWYHA-UHFFFAOYSA-N 0.000 description 1
- OFFWJBZFMPZWMS-UHFFFAOYSA-N 3-cyclohexylpropyl(diethoxy)silane Chemical compound CCO[SiH](OCC)CCCC1CCCCC1 OFFWJBZFMPZWMS-UHFFFAOYSA-N 0.000 description 1
- DCAXPUSXNUDOCD-UHFFFAOYSA-N 3-cyclohexylpropyl(dimethoxy)silane Chemical compound CO[SiH](OC)CCCC1CCCCC1 DCAXPUSXNUDOCD-UHFFFAOYSA-N 0.000 description 1
- XAVIWSKEINLISQ-UHFFFAOYSA-N 3-cyclopentylpropyl(dimethoxy)silane Chemical compound CO[SiH](OC)CCCC1CCCC1 XAVIWSKEINLISQ-UHFFFAOYSA-N 0.000 description 1
- PQMLVDQQBMSJAN-UHFFFAOYSA-N 3-octan-3-yloxycarbonylbicyclo[2.2.1]hept-2-ene-2-carboxylic acid Chemical compound C1CC2C(C(=O)OC(CC)CCCCC)=C(C(O)=O)C1C2 PQMLVDQQBMSJAN-UHFFFAOYSA-N 0.000 description 1
- IMLMDRQQJFUQTC-UHFFFAOYSA-N 3-octan-3-yloxycarbonylbicyclo[2.2.1]heptane-2-carboxylic acid Chemical compound C1CC2C(C(O)=O)C(C(=O)OC(CC)CCCCC)C1C2 IMLMDRQQJFUQTC-UHFFFAOYSA-N 0.000 description 1
- BFPKYGRZERDWLA-UHFFFAOYSA-N 4-methylbicyclo[2.2.1]heptane-2,3-dicarboxylic acid Chemical compound C1CC2C(C(O)=O)C(C(O)=O)C1(C)C2 BFPKYGRZERDWLA-UHFFFAOYSA-N 0.000 description 1
- SIQAZJIEPYIDDS-UHFFFAOYSA-N 5,6-dimethyl-3-octan-3-yloxycarbonylbicyclo[2.2.1]hept-2-ene-2-carboxylic acid Chemical compound C1C2C(C(=O)OC(CC)CCCCC)=C(C(O)=O)C1C(C)C2C SIQAZJIEPYIDDS-UHFFFAOYSA-N 0.000 description 1
- FPEIBCPUXNHDOB-UHFFFAOYSA-N 5,6-dimethyl-3-octan-3-yloxycarbonylbicyclo[2.2.1]heptane-2-carboxylic acid Chemical compound C1C2C(C)C(C)C1C(C(=O)OC(CC)CCCCC)C2C(O)=O FPEIBCPUXNHDOB-UHFFFAOYSA-N 0.000 description 1
- RVVNYEYGEKFPAT-UHFFFAOYSA-N 5-methyl-3-octan-3-yloxycarbonylbicyclo[2.2.1]hept-5-ene-2-carboxylic acid Chemical compound C1C2C=C(C)C1C(C(=O)OC(CC)CCCCC)C2C(O)=O RVVNYEYGEKFPAT-UHFFFAOYSA-N 0.000 description 1
- NOHNHRSLNXKVSX-UHFFFAOYSA-N 5-methyl-3-octan-3-yloxycarbonylbicyclo[2.2.1]heptane-2-carboxylic acid Chemical compound C1C2CC(C)C1C(C(=O)OC(CC)CCCCC)C2C(O)=O NOHNHRSLNXKVSX-UHFFFAOYSA-N 0.000 description 1
- PCBPVYHMZBWMAZ-UHFFFAOYSA-N 5-methylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(C)CC1C=C2 PCBPVYHMZBWMAZ-UHFFFAOYSA-N 0.000 description 1
- RJIHFGJUQQCRRD-UHFFFAOYSA-N 7,7-dimethyl-3-octan-3-yloxycarbonylbicyclo[2.2.1]hepta-2,5-diene-2-carboxylic acid Chemical compound C1=CC2C(C(=O)OC(CC)CCCCC)=C(C(O)=O)C1C2(C)C RJIHFGJUQQCRRD-UHFFFAOYSA-N 0.000 description 1
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- VMPWODPFFNIDSL-UHFFFAOYSA-N dimethyl bicyclo[2.2.1]heptane-2,3-dicarboxylate Chemical compound C1CC2C(C(=O)OC)C(C(=O)OC)C1C2 VMPWODPFFNIDSL-UHFFFAOYSA-N 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- FBSAITBEAPNWJG-UHFFFAOYSA-N dimethyl phthalate Natural products CC(=O)OC1=CC=CC=C1OC(C)=O FBSAITBEAPNWJG-UHFFFAOYSA-N 0.000 description 1
- 229960001826 dimethylphthalate Drugs 0.000 description 1
- RSBBZOWBOZCDJD-UHFFFAOYSA-N dioctyl 5,6-dimethylbicyclo[2.2.1]hepta-2,5-diene-2,3-dicarboxylate Chemical compound CCCCCCCCOC(=O)C1=C(C2CC1C(C)=C2C)C(=O)OCCCCCCCC RSBBZOWBOZCDJD-UHFFFAOYSA-N 0.000 description 1
- HDSIBSUNPNIWRY-UHFFFAOYSA-N dioctyl 5,6-dimethylbicyclo[2.2.1]heptane-2,3-dicarboxylate Chemical compound CCCCCCCCOC(=O)C1C2CC(C(C)C2C)C1C(=O)OCCCCCCCC HDSIBSUNPNIWRY-UHFFFAOYSA-N 0.000 description 1
- IZIYOVJPNXAWMH-UHFFFAOYSA-N dioctyl 5-methylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxylate Chemical compound CCCCCCCCOC(=O)C1C2CC(C1C(=O)OCCCCCCCC)C(C)=C2 IZIYOVJPNXAWMH-UHFFFAOYSA-N 0.000 description 1
- GUPXPZDSZZCMTC-UHFFFAOYSA-N dioctyl 5-methylbicyclo[2.2.1]hepta-2,5-diene-2,3-dicarboxylate Chemical compound CCCCCCCCOC(=O)C1=C(C2CC1C=C2C)C(=O)OCCCCCCCC GUPXPZDSZZCMTC-UHFFFAOYSA-N 0.000 description 1
- OUYSHYXCKHOGKV-UHFFFAOYSA-N dioctyl 5-methylbicyclo[2.2.1]heptane-2,3-dicarboxylate Chemical compound CCCCCCCCOC(=O)C1C2CC(C)C(C2)C1C(=O)OCCCCCCCC OUYSHYXCKHOGKV-UHFFFAOYSA-N 0.000 description 1
- CIVBZWUBNXFMAR-UHFFFAOYSA-N dioctyl 7,7-dimethylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxylate Chemical compound CCCCCCCCOC(=O)C1C(C2C=CC1C2(C)C)C(=O)OCCCCCCCC CIVBZWUBNXFMAR-UHFFFAOYSA-N 0.000 description 1
- LBUOCCRHXQWBJH-UHFFFAOYSA-N dioctyl bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylate Chemical compound CCCCCCCCOC(=O)C1C2CC(C=C2)C1C(=O)OCCCCCCCC LBUOCCRHXQWBJH-UHFFFAOYSA-N 0.000 description 1
- JMCOMNBBBWARHE-UHFFFAOYSA-N dipropan-2-yl 5,6-dimethylbicyclo[2.2.1]hept-2-ene-2,3-dicarboxylate Chemical compound C1C2C(C(=O)OC(C)C)=C(C(=O)OC(C)C)C1C(C)C2C JMCOMNBBBWARHE-UHFFFAOYSA-N 0.000 description 1
- VOWYQETXUWHPTQ-UHFFFAOYSA-N dipropan-2-yl 5,6-dimethylbicyclo[2.2.1]hepta-2,5-diene-2,3-dicarboxylate Chemical compound C1C2C(C(=O)OC(C)C)=C(C(=O)OC(C)C)C1C(C)=C2C VOWYQETXUWHPTQ-UHFFFAOYSA-N 0.000 description 1
- AEQOQXUOGJVBDR-UHFFFAOYSA-N dipropan-2-yl 5-methylbicyclo[2.2.1]hept-2-ene-2,3-dicarboxylate Chemical compound C1C2C(C(=O)OC(C)C)=C(C(=O)OC(C)C)C1C(C)C2 AEQOQXUOGJVBDR-UHFFFAOYSA-N 0.000 description 1
- GSBLRAFKKBNIDX-UHFFFAOYSA-N dipropan-2-yl 5-methylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxylate Chemical compound C1C2C(C(=O)OC(C)C)C(C(=O)OC(C)C)C1C=C2C GSBLRAFKKBNIDX-UHFFFAOYSA-N 0.000 description 1
- WOZVCVACCYXRGN-UHFFFAOYSA-N dipropan-2-yl 7,7-dimethylbicyclo[2.2.1]hept-2-ene-2,3-dicarboxylate Chemical compound C1CC2C(C(=O)OC(C)C)=C(C(=O)OC(C)C)C1C2(C)C WOZVCVACCYXRGN-UHFFFAOYSA-N 0.000 description 1
- ZTMRIYZLYYBJED-UHFFFAOYSA-N dipropan-2-yl 7,7-dimethylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxylate Chemical compound C1=CC2C(C(=O)OC(C)C)C(C(=O)OC(C)C)C1C2(C)C ZTMRIYZLYYBJED-UHFFFAOYSA-N 0.000 description 1
- CIWXDYPMNUIEJM-UHFFFAOYSA-N dipropan-2-yl 7,7-dimethylbicyclo[2.2.1]heptane-2,3-dicarboxylate Chemical compound C1CC2C(C(=O)OC(C)C)C(C(=O)OC(C)C)C1C2(C)C CIWXDYPMNUIEJM-UHFFFAOYSA-N 0.000 description 1
- XWEPLDYBUJVFKM-UHFFFAOYSA-N dipropan-2-yl bicyclo[2.2.1]heptane-2,3-dicarboxylate Chemical compound C1CC2C(C(=O)OC(C)C)C(C(=O)OC(C)C)C1C2 XWEPLDYBUJVFKM-UHFFFAOYSA-N 0.000 description 1
- QCVXBQKBEZTKTR-UHFFFAOYSA-N dipropyl 5,6-dimethylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxylate Chemical compound CCCOC(=O)C1C2CC(C1C(=O)OCCC)C(C)=C2C QCVXBQKBEZTKTR-UHFFFAOYSA-N 0.000 description 1
- VVBZDQJTBMQLGZ-UHFFFAOYSA-N dipropyl 5,6-dimethylbicyclo[2.2.1]heptane-2,3-dicarboxylate Chemical compound CCCOC(=O)C1C2CC(C(C)C2C)C1C(=O)OCCC VVBZDQJTBMQLGZ-UHFFFAOYSA-N 0.000 description 1
- XRIUGHSVBHDTJQ-UHFFFAOYSA-N dipropyl 5-methylbicyclo[2.2.1]heptane-2,3-dicarboxylate Chemical compound CCCOC(=O)C1C2CC(C)C(C2)C1C(=O)OCCC XRIUGHSVBHDTJQ-UHFFFAOYSA-N 0.000 description 1
- GUMOXHOAVYNMFI-UHFFFAOYSA-N dipropyl bicyclo[2.2.1]heptane-2,3-dicarboxylate Chemical compound CCCOC(=O)C1C2CCC(C2)C1C(=O)OCCC GUMOXHOAVYNMFI-UHFFFAOYSA-N 0.000 description 1
- GWCASPKBFBALDG-UHFFFAOYSA-N ditert-butyl(diethoxy)silane Chemical compound CCO[Si](C(C)(C)C)(C(C)(C)C)OCC GWCASPKBFBALDG-UHFFFAOYSA-N 0.000 description 1
- OANIYCQMEVXZCJ-UHFFFAOYSA-N ditert-butyl(dimethoxy)silane Chemical compound CO[Si](OC)(C(C)(C)C)C(C)(C)C OANIYCQMEVXZCJ-UHFFFAOYSA-N 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- JAGYXYUAYDLKNO-UHFFFAOYSA-N hepta-2,5-diene Chemical compound CC=CCC=CC JAGYXYUAYDLKNO-UHFFFAOYSA-N 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 125000004491 isohexyl group Chemical group C(CCC(C)C)* 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011859 microparticle Substances 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- SJYNFBVQFBRSIB-UHFFFAOYSA-N norbornadiene Chemical compound C1=CC2C=CC1C2 SJYNFBVQFBRSIB-UHFFFAOYSA-N 0.000 description 1
- JFNLZVQOOSMTJK-UHFFFAOYSA-N norbornene Chemical compound C1C2CCC1C=C2 JFNLZVQOOSMTJK-UHFFFAOYSA-N 0.000 description 1
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229920000576 tactic polymer Polymers 0.000 description 1
- ASEHKQZNVUOPRW-UHFFFAOYSA-N tert-butyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C(C)(C)C ASEHKQZNVUOPRW-UHFFFAOYSA-N 0.000 description 1
- HXLWJGIPGJFBEZ-UHFFFAOYSA-N tert-butyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C(C)(C)C HXLWJGIPGJFBEZ-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 1
- ALVYUZIFSCKIFP-UHFFFAOYSA-N triethoxy(2-methylpropyl)silane Chemical compound CCO[Si](CC(C)C)(OCC)OCC ALVYUZIFSCKIFP-UHFFFAOYSA-N 0.000 description 1
- FHVAUDREWWXPRW-UHFFFAOYSA-N triethoxy(pentyl)silane Chemical compound CCCCC[Si](OCC)(OCC)OCC FHVAUDREWWXPRW-UHFFFAOYSA-N 0.000 description 1
- JCVQKRGIASEUKR-UHFFFAOYSA-N triethoxy(phenyl)silane Chemical compound CCO[Si](OCC)(OCC)C1=CC=CC=C1 JCVQKRGIASEUKR-UHFFFAOYSA-N 0.000 description 1
- BJDLPDPRMYAOCM-UHFFFAOYSA-N triethoxy(propan-2-yl)silane Chemical compound CCO[Si](OCC)(OCC)C(C)C BJDLPDPRMYAOCM-UHFFFAOYSA-N 0.000 description 1
- NBXZNTLFQLUFES-UHFFFAOYSA-N triethoxy(propyl)silane Chemical compound CCC[Si](OCC)(OCC)OCC NBXZNTLFQLUFES-UHFFFAOYSA-N 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- XYJRNCYWTVGEEG-UHFFFAOYSA-N trimethoxy(2-methylpropyl)silane Chemical compound CO[Si](OC)(OC)CC(C)C XYJRNCYWTVGEEG-UHFFFAOYSA-N 0.000 description 1
- HILHCDFHSDUYNX-UHFFFAOYSA-N trimethoxy(pentyl)silane Chemical compound CCCCC[Si](OC)(OC)OC HILHCDFHSDUYNX-UHFFFAOYSA-N 0.000 description 1
- ZNOCGWVLWPVKAO-UHFFFAOYSA-N trimethoxy(phenyl)silane Chemical compound CO[Si](OC)(OC)C1=CC=CC=C1 ZNOCGWVLWPVKAO-UHFFFAOYSA-N 0.000 description 1
- LGROXJWYRXANBB-UHFFFAOYSA-N trimethoxy(propan-2-yl)silane Chemical compound CO[Si](OC)(OC)C(C)C LGROXJWYRXANBB-UHFFFAOYSA-N 0.000 description 1
- GBXQPDCOMJJCMJ-UHFFFAOYSA-M trimethyl-[6-(trimethylazaniumyl)hexyl]azanium;bromide Chemical class [Br-].C[N+](C)(C)CCCCCC[N+](C)(C)C GBXQPDCOMJJCMJ-UHFFFAOYSA-M 0.000 description 1
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
- CNWZYDSEVLFSMS-UHFFFAOYSA-N tripropylalumane Chemical compound CCC[Al](CCC)CCC CNWZYDSEVLFSMS-UHFFFAOYSA-N 0.000 description 1
- 150000003738 xylenes Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Description
Claims (3)
- REVENDICATIONS1. Catalyseur solide pour la polymérisation du propylène comprenant du titane, du magnésium, un halogène et un mélange de donneurs d'électrons internes, dans lequel le mélange de donneurs 5 d'électrons internes comprend au moins un élément choisi parmi les bicycloalcane dicarboxylates et les bicycloalcène dicarboxylates représentés par les formule (II), formule (III), formule (IV) et formule (V) suivantes, et un ester d'acide benzène-1,210 dicarboxylique :S54924 PA -T 35 (IV) (V) dans identiques alcényle, cyclique, respectivement ; R3, R4, R5 et R6, qui peuvent être un groupe linéaire, en C1 à 20, lesquelles, R1 et R2, qui peuvent être ou différents, sont un groupe alkyle, arylalkyle ou alkylaryle linéaire, ramifié ou ou un groupe aryle, en Ci à 20, identiques ou différents, sont un hydrogène, alkyle, alcényle, arylalkyle ou alkylaryle 10 ramifié ou cyclique, ou un groupe aryle, respectivement.
- 2. Catalyseur solide pour la polymérisation du propylène selon la revendication 1, comprenant de 5 à 15 40 % en poids de magnésium, de 0,5 à 10 % en poids de titane, de 50 à 85 % en poids d'un halogène et de 2,5 à 30 % en poids du mélange de donneurs d'électrons internes.S54924 PA-T 36
- 3. Procédé de préparation du poly(propylène) comprenant la polymérisation du propylène ou la copolymérisation du propylène avec d'autres alpha-oléfines, en présence d'un catalyseur solide selon la 5 revendication 1 ou 2, d'A1R3, où R est un groupe alkyle en C1à8 en tant que cocatalyseur et de R1mR2nSi(OR3) (4-m-n), où R1 et R2, qui sont identiques ou différents, sont un groupe alkyle linéaire, ramifié ou cyclique, ou un groupe aryle, en C1 à C12 ; R3 est un groupe alkyle en 10 Clà 6 linéaire ou ramifié ; et m et n valent 0 ou 1, respectivement, à condition que m + n vaille 1 ou 2, en tant que donneur d'électrons externe.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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KR1020120069222A KR101395471B1 (ko) | 2012-06-27 | 2012-06-27 | 프로필렌 중합용 고체촉매 및 이를 이용한 폴리프로필렌 제조방법 |
Publications (2)
Publication Number | Publication Date |
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FR2992648A1 true FR2992648A1 (fr) | 2014-01-03 |
FR2992648B1 FR2992648B1 (fr) | 2016-12-30 |
Family
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Application Number | Title | Priority Date | Filing Date |
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FR1356146A Active FR2992648B1 (fr) | 2012-06-27 | 2013-06-26 | Catalyseur solide pour la polymerisation du propylene et procede de preparation du poly(propylene). |
Country Status (5)
Country | Link |
---|---|
US (1) | US20140005345A1 (fr) |
JP (1) | JP5671580B2 (fr) |
KR (1) | KR101395471B1 (fr) |
CN (1) | CN103509142A (fr) |
FR (1) | FR2992648B1 (fr) |
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KR101963009B1 (ko) * | 2016-12-15 | 2019-03-27 | 한화토탈 주식회사 | 에틸렌 올리고머화 방법 |
KR101853569B1 (ko) * | 2016-12-15 | 2018-04-30 | 한화토탈 주식회사 | 에틸렌 올리고머화 반응용 촉매계 및 이를 이용한 에틸렌 올리고머화 방법 |
CN106905452B (zh) * | 2017-01-07 | 2019-12-24 | 北京化工大学 | α-烯烃聚合催化剂及制备方法与应用 |
KR101908866B1 (ko) * | 2017-11-29 | 2018-10-16 | 한화토탈 주식회사 | 프로필렌 중합용 고체촉매 및 이를 이용한 폴리프로필렌 제조방법 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5883006A (ja) * | 1981-11-13 | 1983-05-18 | Mitsui Petrochem Ind Ltd | オレフインの重合方法 |
CA2011188C (fr) | 1989-03-02 | 2000-01-18 | Naoshi Ishimaru | Procede et catalyseur de polymerisation d'olefines |
DE3932553A1 (de) * | 1989-09-29 | 1991-04-11 | Basf Ag | Katalysatorsysteme vom typ der ziegler-natta-katalysatoren |
US6005049A (en) | 1993-07-19 | 1999-12-21 | Union Carbide Chemicals & Plastics Technology Corporation | Process for the production of polypropylene |
CN101117364A (zh) * | 2003-03-26 | 2008-02-06 | Bp北美公司 | 含有作为电子给体的环烷二元羧酸酯的烯烃聚合催化剂 |
KR100523474B1 (ko) * | 2005-03-29 | 2005-10-24 | 삼성토탈 주식회사 | 매우 높은 용융흐름성을 갖는 프로필렌 중합체의 제조방법 |
CN101735346B (zh) * | 2008-11-07 | 2012-05-30 | 中国石油天然气股份有限公司 | 一种丙烯均聚和共聚的催化剂及其制备方法和应用 |
KR101207628B1 (ko) * | 2010-01-13 | 2012-12-03 | 삼성토탈 주식회사 | 프로필렌 중합용 고체촉매 및 그 제조 방법 |
-
2012
- 2012-06-27 KR KR1020120069222A patent/KR101395471B1/ko active IP Right Grant
-
2013
- 2013-06-12 JP JP2013123457A patent/JP5671580B2/ja active Active
- 2013-06-18 US US13/920,349 patent/US20140005345A1/en not_active Abandoned
- 2013-06-26 FR FR1356146A patent/FR2992648B1/fr active Active
- 2013-06-26 CN CN201310257545.6A patent/CN103509142A/zh active Pending
Also Published As
Publication number | Publication date |
---|---|
KR101395471B1 (ko) | 2014-05-14 |
KR20140001493A (ko) | 2014-01-07 |
CN103509142A (zh) | 2014-01-15 |
FR2992648B1 (fr) | 2016-12-30 |
US20140005345A1 (en) | 2014-01-02 |
JP2014009359A (ja) | 2014-01-20 |
JP5671580B2 (ja) | 2015-02-18 |
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