FR2989972B1 - Copolymerisation radicalaire controlee a partir de trifluoroethylene - Google Patents

Copolymerisation radicalaire controlee a partir de trifluoroethylene

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Publication number
FR2989972B1
FR2989972B1 FR1253838A FR1253838A FR2989972B1 FR 2989972 B1 FR2989972 B1 FR 2989972B1 FR 1253838 A FR1253838 A FR 1253838A FR 1253838 A FR1253838 A FR 1253838A FR 2989972 B1 FR2989972 B1 FR 2989972B1
Authority
FR
France
Prior art keywords
trifluoroethylene
radical controlled
controlled copolymerization
copolymerization
radical
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR1253838A
Other languages
English (en)
Other versions
FR2989972A1 (fr
Inventor
Bruno Ameduri
Ali Alaaeddine
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
Ecole Nationale Superieure de Chimie de Montpellier ENSCM
Original Assignee
Arkema France SA
Ecole Nationale Superieure de Chimie de Montpellier ENSCM
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR1253838A priority Critical patent/FR2989972B1/fr
Application filed by Arkema France SA, Ecole Nationale Superieure de Chimie de Montpellier ENSCM filed Critical Arkema France SA
Priority to EP13723870.5A priority patent/EP2841474A1/fr
Priority to JP2015507585A priority patent/JP6212542B2/ja
Priority to PCT/FR2013/050920 priority patent/WO2013160621A1/fr
Priority to US14/396,528 priority patent/US9708419B2/en
Priority to CN201380033739.6A priority patent/CN104540861B/zh
Priority to KR1020147033297A priority patent/KR20150006865A/ko
Publication of FR2989972A1 publication Critical patent/FR2989972A1/fr
Application granted granted Critical
Publication of FR2989972B1 publication Critical patent/FR2989972B1/fr
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C08F214/182—Monomers containing fluorine not covered by the groups C08F214/20 - C08F214/28
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C08F214/22—Vinylidene fluoride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
    • C08J5/2231—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
    • C08J5/2237—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C09D127/16—Homopolymers or copolymers of vinylidene fluoride
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D153/00—Coating compositions based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N15/00—Thermoelectric devices without a junction of dissimilar materials; Thermomagnetic devices, e.g. using the Nernst-Ettingshausen effect
    • H10N15/10—Thermoelectric devices using thermal change of the dielectric constant, e.g. working above and below the Curie point
    • H10N15/15—Thermoelectric active materials
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N30/00—Piezoelectric or electrostrictive devices
    • H10N30/80—Constructional details
    • H10N30/85—Piezoelectric or electrostrictive active materials
    • H10N30/857—Macromolecular compositions
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/03—Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Graft Or Block Polymers (AREA)
  • Polymerisation Methods In General (AREA)
FR1253838A 2012-04-26 2012-04-26 Copolymerisation radicalaire controlee a partir de trifluoroethylene Expired - Fee Related FR2989972B1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR1253838A FR2989972B1 (fr) 2012-04-26 2012-04-26 Copolymerisation radicalaire controlee a partir de trifluoroethylene
JP2015507585A JP6212542B2 (ja) 2012-04-26 2013-04-25 トリフルオロエチレンの制御フリーラジカル共重合
PCT/FR2013/050920 WO2013160621A1 (fr) 2012-04-26 2013-04-25 Copolymerisation radicalaire controlee a partir de trifluoroethylene
US14/396,528 US9708419B2 (en) 2012-04-26 2013-04-25 Controlled free-radical copolymerization of trifluoroethylene
EP13723870.5A EP2841474A1 (fr) 2012-04-26 2013-04-25 Copolymerisation radicalaire controlee a partir de trifluoroethylene
CN201380033739.6A CN104540861B (zh) 2012-04-26 2013-04-25 三氟乙烯的受控自由基共聚合反应
KR1020147033297A KR20150006865A (ko) 2012-04-26 2013-04-25 트리플루오로에틸렌의 제어된 자유―라디칼 공중합

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1253838A FR2989972B1 (fr) 2012-04-26 2012-04-26 Copolymerisation radicalaire controlee a partir de trifluoroethylene

Publications (2)

Publication Number Publication Date
FR2989972A1 FR2989972A1 (fr) 2013-11-01
FR2989972B1 true FR2989972B1 (fr) 2015-03-27

Family

ID=47002947

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1253838A Expired - Fee Related FR2989972B1 (fr) 2012-04-26 2012-04-26 Copolymerisation radicalaire controlee a partir de trifluoroethylene

Country Status (7)

Country Link
US (1) US9708419B2 (fr)
EP (1) EP2841474A1 (fr)
JP (1) JP6212542B2 (fr)
KR (1) KR20150006865A (fr)
CN (1) CN104540861B (fr)
FR (1) FR2989972B1 (fr)
WO (1) WO2013160621A1 (fr)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3004185B1 (fr) * 2013-04-03 2017-10-13 Arkema France Terpolymeres contenant du fluorure de vinylidene et du trifluoroethylene
WO2015173194A1 (fr) * 2014-05-12 2015-11-19 Solvay Specialty Polymers Italy S.P.A. Fluoroélastomères
US10377843B2 (en) * 2014-05-12 2019-08-13 Solvay Specialty Polymers Italy S.P.A. Method for the controlled polymerization of fluoromonomers
WO2016149238A1 (fr) * 2015-03-16 2016-09-22 Arkema Inc. Fluoropolymères modifiés
CN108368193B (zh) * 2015-08-05 2021-05-25 施乐公司 改变PVDF-TrFE共聚物末端基团的方法、具有改进铁电性质的PVDF-TrFE共聚物和形成含PVDF-TrFE共聚物的电子装置的方法
FR3041348B1 (fr) * 2015-09-23 2019-05-03 Arkema France Terpolymeres du fluorure de vinylidene, du trifluoroethylene et du 1,3,3,3-tetrafluoropropene
FR3042502B1 (fr) * 2015-10-19 2019-04-05 Arkema France Copolymeres fluores fonctionnalises
JP6733807B2 (ja) 2017-03-09 2020-08-05 Ａｇｃ株式会社 ポリマーの製造方法
FR3065217B1 (fr) * 2017-04-14 2020-02-28 Arkema France Compositions reticulables a base de copolymeres fluores electroactifs
ES2909846T3 (es) 2017-06-16 2022-05-10 Carrier Corp Sistema electrocalórico de transferencia de calor que comprende copolímeros
CA3077026A1 (fr) * 2017-09-27 2019-04-04 Arkema Inc. Copolymeres d'olefines halogenees et de comonomeres halogenes
FR3071500B1 (fr) * 2017-09-27 2020-05-15 Arkema France Synthese de latex de poly(fluorure de vinylidene) sans tensioactif par polymerisation en emulsion raft
KR20210107019A (ko) 2018-12-20 2021-08-31 솔베이 스페셜티 폴리머스 이태리 에스.피.에이. 비닐리덴 플루오라이드 중합체 분산물
CN109851705A (zh) * 2019-03-20 2019-06-07 济南大学 一种一锅法制备分子量可控的四氟乙烯共聚物的方法
JP7406129B2 (ja) * 2019-05-08 2023-12-27 ダイキン工業株式会社 フルオロポリマーの製造方法及びフルオロポリマー
CN114174362A (zh) * 2019-09-04 2022-03-11 大金工业株式会社 含氟共聚物
EP4190828A1 (fr) * 2020-07-30 2023-06-07 Daikin Industries, Ltd. Procédé de production de dispersion aqueuse d'élastomère contenant du fluor, élastomère contenant du fluor ainsi que dispersion aqueuse
CN112226119A (zh) * 2020-09-19 2021-01-15 复旦大学 一种发光防水聚合物涂层的制备方法
KR102526902B1 (ko) 2021-07-02 2023-04-28 정세진 고내열 유연성 정온도계수 자율제어형 히팅케이블 제조방법
FR3125957A1 (fr) 2021-08-04 2023-02-10 Piezomedic Dispositif et système de localisation d’un implant ou d’un organe dans un corps humain ou animal, par émission-réception de signaux ultrasons via des transducteurs piézoélectriques et/ou capacitifs
WO2023110696A1 (fr) * 2021-12-17 2023-06-22 Solvay Specialty Polymers Italy S.P.A. Procédé de polymérisation en émulsion de fluoromonomère

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US9193810B2 (en) * 2012-02-23 2015-11-24 University Of Connecticut Free radical and controlled radical polymerization processes using hypervalent iodide radical initiators

Also Published As

Publication number Publication date
WO2013160621A1 (fr) 2013-10-31
EP2841474A1 (fr) 2015-03-04
JP2015514854A (ja) 2015-05-21
US20150119523A1 (en) 2015-04-30
CN104540861B (zh) 2016-08-24
KR20150006865A (ko) 2015-01-19
US9708419B2 (en) 2017-07-18
CN104540861A (zh) 2015-04-22
FR2989972A1 (fr) 2013-11-01
JP6212542B2 (ja) 2017-10-11

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