FR2986234B1 - LIVE POLY (N-VINYL LACTAM) REAGENT STABILIZERS FOR DISPERSE PHASE POLYMERIZATION - Google Patents

LIVE POLY (N-VINYL LACTAM) REAGENT STABILIZERS FOR DISPERSE PHASE POLYMERIZATION

Info

Publication number
FR2986234B1
FR2986234B1 FR1200291A FR1200291A FR2986234B1 FR 2986234 B1 FR2986234 B1 FR 2986234B1 FR 1200291 A FR1200291 A FR 1200291A FR 1200291 A FR1200291 A FR 1200291A FR 2986234 B1 FR2986234 B1 FR 2986234B1
Authority
FR
France
Prior art keywords
phase polymerization
disperse phase
vinyl lactam
live poly
stabilizers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR1200291A
Other languages
French (fr)
Other versions
FR2986234A1 (en
Inventor
Mathias Destarac
James Wilson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhodia Operations SAS
Original Assignee
Rhodia Operations SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhodia Operations SAS filed Critical Rhodia Operations SAS
Priority to FR1200291A priority Critical patent/FR2986234B1/en
Priority to PCT/EP2013/051788 priority patent/WO2013113750A1/en
Priority to JP2014553759A priority patent/JP2015504959A/en
Priority to US14/375,328 priority patent/US9487598B2/en
Priority to CN201380013435.3A priority patent/CN104144957B/en
Priority to EP13701788.5A priority patent/EP2809697B1/en
Publication of FR2986234A1 publication Critical patent/FR2986234A1/en
Application granted granted Critical
Publication of FR2986234B1 publication Critical patent/FR2986234B1/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/02Monomers containing chlorine
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/02Monomers containing chlorine
    • C08F14/04Monomers containing two carbon atoms
    • C08F14/08Vinylidene chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/18Monomers containing fluorine
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/18Monomers containing fluorine
    • C08F14/20Vinyl fluoride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/18Monomers containing fluorine
    • C08F14/22Vinylidene fluoride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/12Polymerisation in non-solvents
    • C08F2/16Aqueous medium
    • C08F2/20Aqueous medium with the aid of macromolecular dispersing agents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F26/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
    • C08F26/06Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a heterocyclic ring containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00Living radical polymerisation
    • C08F2438/03Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polymerisation Methods In General (AREA)
  • Polymerization Catalysts (AREA)
  • Graft Or Block Polymers (AREA)
FR1200291A 2012-01-31 2012-01-31 LIVE POLY (N-VINYL LACTAM) REAGENT STABILIZERS FOR DISPERSE PHASE POLYMERIZATION Expired - Fee Related FR2986234B1 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
FR1200291A FR2986234B1 (en) 2012-01-31 2012-01-31 LIVE POLY (N-VINYL LACTAM) REAGENT STABILIZERS FOR DISPERSE PHASE POLYMERIZATION
PCT/EP2013/051788 WO2013113750A1 (en) 2012-01-31 2013-01-30 Live poly(n-vinyl lactam) reactive stabilisers for dispersed phase polymerisation
JP2014553759A JP2015504959A (en) 2012-01-31 2013-01-30 Living poly (N-vinyl lactam) reaction stabilizer for dispersed phase polymerization
US14/375,328 US9487598B2 (en) 2012-01-31 2013-01-30 Live poly(n-vinyl lactam) reactive stabilizers for dispersed phase polymerization
CN201380013435.3A CN104144957B (en) 2012-01-31 2013-01-30 The reactive stabilizer of activity poly-(N-vinyl lactam) for dispersion phase polymerization
EP13701788.5A EP2809697B1 (en) 2012-01-31 2013-01-30 Live poly(n-vinyl lactam) reactive stabilisers for dispersed phase polymerisation

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1200291A FR2986234B1 (en) 2012-01-31 2012-01-31 LIVE POLY (N-VINYL LACTAM) REAGENT STABILIZERS FOR DISPERSE PHASE POLYMERIZATION

Publications (2)

Publication Number Publication Date
FR2986234A1 FR2986234A1 (en) 2013-08-02
FR2986234B1 true FR2986234B1 (en) 2014-06-13

Family

ID=45954836

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1200291A Expired - Fee Related FR2986234B1 (en) 2012-01-31 2012-01-31 LIVE POLY (N-VINYL LACTAM) REAGENT STABILIZERS FOR DISPERSE PHASE POLYMERIZATION

Country Status (2)

Country Link
JP (1) JP2015504959A (en)
FR (1) FR2986234B1 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10377843B2 (en) * 2014-05-12 2019-08-13 Solvay Specialty Polymers Italy S.P.A. Method for the controlled polymerization of fluoromonomers

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3773408B2 (en) * 2000-06-15 2006-05-10 第一工業製薬株式会社 Method for producing vinylpyrrolidone polymer
RU2003128869A (en) * 2001-02-26 2005-04-10 Родиа Шими (Fr) SYNTHESIS OF BLOCK COPOLIMERS WITH AMPHILIC PROPERTIES AS ADHESIVE PROMOTORS OF WATER FILM-FORMING COMPOSITIONS ON A LOW-ENERGY SURFACE AND A WATER FILM-FORMING COMPOSITION
JP4744783B2 (en) * 2001-05-04 2011-08-10 ロディア・シミ Surfactant block copolymers made by controlled radical polymerization
JP4405807B2 (en) * 2001-12-21 2010-01-27 ユニバーシティ オブ シドニー Aqueous dispersion of polymer particles
FR2839723B1 (en) * 2002-05-14 2004-07-23 Rhodia Chimie Sa POLYMER OBTAINED BY CONTROLLED RADICAL POLYMERIZATION COMPRISING AT LEAST ONE BORONATE FUNCTION, ASSOCIATION WITH A LIGAND COMPOUND AND USES
FR2859210B1 (en) * 2003-09-01 2008-05-09 Oreal ETHYLENIC COPOLYMER SEQUENCES COMPRISING A VINYLLACTAM SEQUENCE, COSMETIC COMPOSITIONS CONTAINING THEM, AND THE USE OF THESE COPOLYMERS IN COSMETICS
FR2859727B1 (en) * 2003-09-15 2008-06-27 Oreal ETHYLENIC COPOLYMER SEQUENCES COMPRISING A VINYLLACTAM SEQUENCE, COSMETIC OR PHARMACEUTICAL COMPOSITIONS CONTAINING THEM, AND THE USE OF THESE COPOLYMERS IN COSMETICS
FR2868072B1 (en) * 2004-07-28 2006-06-30 Coatex Soc Par Actions Simplif POLYMERS OBTAINED BY THE USE OF SULFUR COMPOUNDS AS TRANSFER AGENTS FOR THE CONTROLLED RADICAL CONTROLLED ACRYLIC ACID POLYMERIZATION AND THEIR APPLICATIONS
WO2010083569A1 (en) * 2009-01-23 2010-07-29 Commonwealth Scientific And Industrial Research Organisation Raft polymerisation
FR2965264B1 (en) * 2010-09-27 2013-11-29 Rhodia Operations CONTROLLED RADICAL POLYMERIZATION OF N-VINYL LACTAMS IN AQUEOUS MEDIUM

Also Published As

Publication number Publication date
JP2015504959A (en) 2015-02-16
FR2986234A1 (en) 2013-08-02

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