FR2880346B1 - Procede de preparation d'acide acrylique a partir du propane en absence de vapeur d'eau - Google Patents

Procede de preparation d'acide acrylique a partir du propane en absence de vapeur d'eau

Info

Publication number
FR2880346B1
FR2880346B1 FR0414082A FR0414082A FR2880346B1 FR 2880346 B1 FR2880346 B1 FR 2880346B1 FR 0414082 A FR0414082 A FR 0414082A FR 0414082 A FR0414082 A FR 0414082A FR 2880346 B1 FR2880346 B1 FR 2880346B1
Authority
FR
France
Prior art keywords
propane
absence
preparation
acrylic acid
water vapor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR0414082A
Other languages
English (en)
Other versions
FR2880346A1 (fr
Inventor
Jean Luc Dubois
Dominique Garrait
Anne Legall
Guy Bazin
Stephanie Serreau
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema SA
Original Assignee
Arkema SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR0414082A priority Critical patent/FR2880346B1/fr
Application filed by Arkema SA filed Critical Arkema SA
Priority to JP2007548861A priority patent/JP2008526718A/ja
Priority to KR1020077013311A priority patent/KR20070095899A/ko
Priority to CNA2005800444181A priority patent/CN101087648A/zh
Priority to US11/813,148 priority patent/US20080139844A1/en
Priority to EP05826593A priority patent/EP1833603A1/fr
Priority to PCT/FR2005/003168 priority patent/WO2006072682A1/fr
Publication of FR2880346A1 publication Critical patent/FR2880346A1/fr
Application granted granted Critical
Publication of FR2880346B1 publication Critical patent/FR2880346B1/fr
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/92—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/057—Selenium or tellurium; Compounds thereof
    • B01J27/0576—Tellurium; Compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/28—Regeneration or reactivation
    • B01J27/30—Regeneration or reactivation of catalysts comprising compounds of sulfur, selenium or tellurium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/12—Treating with free oxygen-containing gas
    • B01J38/30—Treating with free oxygen-containing gas in gaseous suspension, e.g. fluidised bed
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/03—Monocarboxylic acids
    • C07C57/04—Acrylic acid; Methacrylic acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/18—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
FR0414082A 2004-12-30 2004-12-30 Procede de preparation d'acide acrylique a partir du propane en absence de vapeur d'eau Expired - Fee Related FR2880346B1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR0414082A FR2880346B1 (fr) 2004-12-30 2004-12-30 Procede de preparation d'acide acrylique a partir du propane en absence de vapeur d'eau
KR1020077013311A KR20070095899A (ko) 2004-12-30 2005-12-16 수증기 없이 프로페인으로부터 아크릴산을 제조하는 방법
CNA2005800444181A CN101087648A (zh) 2004-12-30 2005-12-16 在不存在水蒸汽的情况下由丙烷制备丙烯酸的方法
US11/813,148 US20080139844A1 (en) 2004-12-30 2005-12-16 Method Of Preparing Acrylic Acid From Propane In The Absence
JP2007548861A JP2008526718A (ja) 2004-12-30 2005-12-16 水蒸気の非存在下でのプロパンからアクリル酸の調製方法
EP05826593A EP1833603A1 (fr) 2004-12-30 2005-12-16 Procede de preparation d'acide acrylique a partir du propane, en absence de vapeur d'eau
PCT/FR2005/003168 WO2006072682A1 (fr) 2004-12-30 2005-12-16 Procede de preparation d'acide acrylique a partir du propane, en absence de vapeur d’eau

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0414082A FR2880346B1 (fr) 2004-12-30 2004-12-30 Procede de preparation d'acide acrylique a partir du propane en absence de vapeur d'eau

Publications (2)

Publication Number Publication Date
FR2880346A1 FR2880346A1 (fr) 2006-07-07
FR2880346B1 true FR2880346B1 (fr) 2007-02-23

Family

ID=34954132

Family Applications (1)

Application Number Title Priority Date Filing Date
FR0414082A Expired - Fee Related FR2880346B1 (fr) 2004-12-30 2004-12-30 Procede de preparation d'acide acrylique a partir du propane en absence de vapeur d'eau

Country Status (7)

Country Link
US (1) US20080139844A1 (fr)
EP (1) EP1833603A1 (fr)
JP (1) JP2008526718A (fr)
KR (1) KR20070095899A (fr)
CN (1) CN101087648A (fr)
FR (1) FR2880346B1 (fr)
WO (1) WO2006072682A1 (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7538059B2 (en) * 2006-01-31 2009-05-26 Rohm And Haas Company Regeneration of mixed metal oxide catalysts
CN100439313C (zh) * 2006-10-27 2008-12-03 清华大学 一种丙烯氧化制备丙烯酸的多级流化床反应器及制备方法
US20130267735A1 (en) * 2010-12-29 2013-10-10 Scott Han Propane Oxidation Process Using Reduced Amounts of Steam
KR20150143596A (ko) 2013-04-08 2015-12-23 사우디 베이식 인더스트리즈 코포레이션 프로필렌을 카르복실산 모이어티를 포함하는 생성물로 변환하는 촉매
US9856200B2 (en) 2013-04-24 2018-01-02 Saudi Basic Industries Corporation Supported catalyst for production of unsaturated carboxylic acids from alkanes
CN105209167A (zh) 2013-04-24 2015-12-30 沙特基础工业公司 用于将烷烃氧化成不饱和羧酸和烯烃的高生产率催化剂

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0608838B1 (fr) * 1993-01-28 1997-04-16 Mitsubishi Chemical Corporation Procédé pour la préparation d'un acide carboxylique insaturé
JP3334296B2 (ja) * 1993-01-28 2002-10-15 三菱化学株式会社 不飽和カルボン酸の製造方法
FR2754817B1 (fr) * 1996-10-21 2000-03-17 Toagosei Co Ltd Procede de production d'acide acrylique a partir de propane et d'oxygene gazeux
JP2000513384A (ja) * 1997-07-15 2000-10-10 イー・アイ・デユポン・ドウ・ヌムール・アンド・カンパニー プロピレンのアクロレインへの改良された気相酸化
US6437193B1 (en) * 1997-07-15 2002-08-20 E. I. Du Pont De Nemours And Company Vapor phase oxidation of propylene to acrolein
US6114278A (en) * 1998-11-16 2000-09-05 Saudi Basic Industries Corporation Catalysts for catalytic oxidation of propane to acrylic acid, methods of making and using the same
TWI268806B (en) * 1999-09-15 2006-12-21 Rohm & Haas A catalyst useful for oxidation of alkanes
US6646156B2 (en) * 2000-04-17 2003-11-11 Showa Denko Kabushiki Kaisha (Meth)acryloyl-group-containing carbamoyl halides and production process therefor
US6867328B2 (en) * 2000-07-18 2005-03-15 Basf Aktiengesellschaft Method for producing acrylic acid by the heterogeneously catalysed gas-phase oxidation of propane
FR2821840B1 (fr) * 2001-03-07 2004-07-16 Atofina Procede de fabrication d'acide acrylique a partir de propane, en l'absence d'oxygene moleculaire

Also Published As

Publication number Publication date
WO2006072682A1 (fr) 2006-07-13
FR2880346A1 (fr) 2006-07-07
US20080139844A1 (en) 2008-06-12
EP1833603A1 (fr) 2007-09-19
KR20070095899A (ko) 2007-10-01
CN101087648A (zh) 2007-12-12
JP2008526718A (ja) 2008-07-24

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Effective date: 20100831