FR2856048B1 - PURIFICATION D'UN MELANGE H2/CO PAR CATALYSE DES NOx - Google Patents

PURIFICATION D'UN MELANGE H2/CO PAR CATALYSE DES NOx

Info

Publication number
FR2856048B1
FR2856048B1 FR0307006A FR0307006A FR2856048B1 FR 2856048 B1 FR2856048 B1 FR 2856048B1 FR 0307006 A FR0307006 A FR 0307006A FR 0307006 A FR0307006 A FR 0307006A FR 2856048 B1 FR2856048 B1 FR 2856048B1
Authority
FR
France
Prior art keywords
nox
catalysis
purification
mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR0307006A
Other languages
English (en)
Other versions
FR2856048A1 (fr
Inventor
Beraud Natacha Haik
Serge Moreau
Francois Jantet
Audrey Moulin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Original Assignee
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Air Liquide SA, LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude filed Critical Air Liquide SA
Priority to FR0307006A priority Critical patent/FR2856048B1/fr
Priority to CNB2004800164256A priority patent/CN100503427C/zh
Priority to EP04767312A priority patent/EP1636134A1/fr
Priority to JP2006516281A priority patent/JP2006527297A/ja
Priority to PCT/FR2004/001447 priority patent/WO2004110924A1/fr
Publication of FR2856048A1 publication Critical patent/FR2856048A1/fr
Application granted granted Critical
Publication of FR2856048B1 publication Critical patent/FR2856048B1/fr
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8621Removing nitrogen compounds
    • B01D53/8625Nitrogen oxides
    • B01D53/8628Processes characterised by a specific catalyst
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/56Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/56Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
    • C01B3/58Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids including a catalytic reaction
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44Palladium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72Copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85Chromium, molybdenum or tungsten
    • B01J23/86Chromium
    • B01J23/868Chromium copper and chromium
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/042Purification by adsorption on solids
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/042Purification by adsorption on solids
    • C01B2203/043Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0435Catalytic purification
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • C01B2203/0495Composition of the impurity the impurity being water

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Biomedical Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Industrial Gases (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
FR0307006A 2003-06-11 2003-06-11 PURIFICATION D'UN MELANGE H2/CO PAR CATALYSE DES NOx Expired - Fee Related FR2856048B1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
FR0307006A FR2856048B1 (fr) 2003-06-11 2003-06-11 PURIFICATION D'UN MELANGE H2/CO PAR CATALYSE DES NOx
CNB2004800164256A CN100503427C (zh) 2003-06-11 2004-06-10 通过nox的催化反应的h2/co混合物净化
EP04767312A EP1636134A1 (fr) 2003-06-11 2004-06-10 Purification d'un melange h sb 2 /sb /co par catalyse des no sb x /sb
JP2006516281A JP2006527297A (ja) 2003-06-11 2004-06-10 NOxの触媒反応によるH2/CO混合物の精製
PCT/FR2004/001447 WO2004110924A1 (fr) 2003-06-11 2004-06-10 Purification d’un melange h2/co par catalyse des nox

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0307006A FR2856048B1 (fr) 2003-06-11 2003-06-11 PURIFICATION D'UN MELANGE H2/CO PAR CATALYSE DES NOx

Publications (2)

Publication Number Publication Date
FR2856048A1 FR2856048A1 (fr) 2004-12-17
FR2856048B1 true FR2856048B1 (fr) 2005-08-05

Family

ID=33484344

Family Applications (1)

Application Number Title Priority Date Filing Date
FR0307006A Expired - Fee Related FR2856048B1 (fr) 2003-06-11 2003-06-11 PURIFICATION D'UN MELANGE H2/CO PAR CATALYSE DES NOx

Country Status (5)

Country Link
EP (1) EP1636134A1 (fr)
JP (1) JP2006527297A (fr)
CN (1) CN100503427C (fr)
FR (1) FR2856048B1 (fr)
WO (1) WO2004110924A1 (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101094910A (zh) * 2004-12-30 2007-12-26 国际壳牌研究有限公司 有关煤变为液体的方法的改进
ATE515477T1 (de) 2007-11-20 2011-07-15 Shell Int Research Verfahren zur herstellung eines gereinigten synthesegasstroms
KR101011830B1 (ko) * 2009-09-30 2011-01-31 상명대학교 산학협력단 질소산화물 분해용 혼합금속산화물 촉매
CN106606927B (zh) * 2015-10-22 2019-08-20 中国石油化工股份有限公司 蒸汽裂解生产低碳烯烃产生的裂解烟气的脱硝方法及其脱硝***

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3564816A (en) * 1968-12-30 1971-02-23 Union Carbide Corp Selective adsorption process
US4117081A (en) * 1973-05-28 1978-09-26 Hitachi Shipbuilding & Engineering Co., Ltd. Method of and catalysts for removal of nitrogen oxides
DE2433479C2 (de) * 1974-07-12 1985-01-10 Hitachi Shipbuilding & Engineering Co., Ltd., Osaka Verfahren zur reduktiven Entfernung von Stickstoffoxiden aus Gasen
JPS54126689A (en) * 1978-03-27 1979-10-02 Daiyo Sanso High purity hydrogen gas generating method
JPS54150387A (en) * 1978-05-17 1979-11-26 Osaka Soda Co Ltd Corrosion preventing method for hydrogen gas piping equipment
JPS6257628A (ja) * 1985-09-05 1987-03-13 Kobe Steel Ltd 製鉄所副生ガスの前処理方法
JPH034937A (ja) * 1989-05-31 1991-01-10 Nkk Corp 有機イオウ分、NOx、ジエン類の分解用触媒
JPH04106194A (ja) * 1990-08-27 1992-04-08 Kawasaki Steel Corp コークス炉ガスの精製方法
US5792436A (en) * 1996-05-13 1998-08-11 Engelhard Corporation Method for using a regenerable catalyzed trap
AU6873100A (en) * 1999-09-09 2001-04-17 Kubota Corporation Novel compound and microporous material and method for production thereof
FR2799991B1 (fr) * 1999-10-26 2002-10-11 Air Liquide Procede de production d'hydrogene utilisant un adsorbant carbone a parametres de dubinin selectionnes

Also Published As

Publication number Publication date
JP2006527297A (ja) 2006-11-30
CN1805900A (zh) 2006-07-19
FR2856048A1 (fr) 2004-12-17
EP1636134A1 (fr) 2006-03-22
CN100503427C (zh) 2009-06-24
WO2004110924A1 (fr) 2004-12-23

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Legal Events

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Effective date: 20150227