FR2683816B1 - Procede d'aromatisation d'hydrocarbures contenant 2 a 4 atomes de carbone en presence d'un catalyseur a structure mfi. - Google Patents

Procede d'aromatisation d'hydrocarbures contenant 2 a 4 atomes de carbone en presence d'un catalyseur a structure mfi.

Info

Publication number
FR2683816B1
FR2683816B1 FR9114206A FR9114206A FR2683816B1 FR 2683816 B1 FR2683816 B1 FR 2683816B1 FR 9114206 A FR9114206 A FR 9114206A FR 9114206 A FR9114206 A FR 9114206A FR 2683816 B1 FR2683816 B1 FR 2683816B1
Authority
FR
France
Prior art keywords
flavoring
catalyst
carbon atoms
hydrocarbons containing
mfi structure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR9114206A
Other languages
English (en)
Other versions
FR2683816A1 (fr
Inventor
Fabio Alario
Jean-Marie Deves
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to FR9114206A priority Critical patent/FR2683816B1/fr
Priority to DE69203211T priority patent/DE69203211T2/de
Priority to EP92403021A priority patent/EP0542613B1/fr
Priority to AT92403021T priority patent/ATE124295T1/de
Priority to ES92403021T priority patent/ES2076718T3/es
Priority to AU28357/92A priority patent/AU655334B2/en
Priority to JP4303678A priority patent/JPH05212289A/ja
Priority to MYPI92002079A priority patent/MY109061A/en
Priority to KR1019920021412A priority patent/KR100245782B1/ko
Priority to TW081109379A priority patent/TW235927B/zh
Publication of FR2683816A1 publication Critical patent/FR2683816A1/fr
Application granted granted Critical
Publication of FR2683816B1 publication Critical patent/FR2683816B1/fr
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/87—Gallosilicates; Aluminogallosilicates; Galloborosilicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44—Noble metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/08—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of gallium, indium or thallium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of germanium, tin or lead
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/26—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/28—Molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/30—Tungsten
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/48—Silver or gold
    • C07C2523/50—Silver
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/48—Silver or gold
    • C07C2523/52—Gold
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/72—Copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/745—Iron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C07C2529/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing iron group metals, noble metals or copper
    • C07C2529/44—Noble metals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
FR9114206A 1991-11-15 1991-11-15 Procede d'aromatisation d'hydrocarbures contenant 2 a 4 atomes de carbone en presence d'un catalyseur a structure mfi. Expired - Fee Related FR2683816B1 (fr)

Priority Applications (10)

Application Number Priority Date Filing Date Title
FR9114206A FR2683816B1 (fr) 1991-11-15 1991-11-15 Procede d'aromatisation d'hydrocarbures contenant 2 a 4 atomes de carbone en presence d'un catalyseur a structure mfi.
EP92403021A EP0542613B1 (fr) 1991-11-15 1992-11-09 Catalyseur à structure MFI et son utilisation en aromatisation d'hydrocarbures comportant 2 à 12 atomes de carbone
AT92403021T ATE124295T1 (de) 1991-11-15 1992-11-09 Katalysator mit mfi-struktur und seine verwendung zum aromatisieren von kohlenwasserstoffen mit 2 bis 12 kohlenstoffatomen.
ES92403021T ES2076718T3 (es) 1991-11-15 1992-11-09 Catalizador con estructura mfi y su utilizacion en aromatizacion de hidrocarburos que incluyen de 2 a 12 atomos de carbono.
DE69203211T DE69203211T2 (de) 1991-11-15 1992-11-09 Katalysator mit MFI-Struktur und seine Verwendung zum Aromatisieren von Kohlenwasserstoffen mit 2 bis 12 Kohlenstoffatomen.
JP4303678A JPH05212289A (ja) 1991-11-15 1992-11-13 Ｍｆｉ構造を有する触媒、および炭素原子数２〜１２の炭化水素の芳香族化におけるこれの使用
AU28357/92A AU655334B2 (en) 1991-11-15 1992-11-13 MFI structure catalyst and its use in the aromatization of hydrocarbons having 5 to 12 carbon atoms
MYPI92002079A MY109061A (en) 1991-11-15 1992-11-14 Mfi structure catalyst and its use in the aromatization of hydrocarbons having 5 to 12 carbon atoms
KR1019920021412A KR100245782B1 (ko) 1991-11-15 1992-11-14 엠에프아이 구조의 촉매, 및 그 촉매를 사용하여 2 내지 12개의 탄소원자를 갖는 탄화수소를 방향족화시키는 방법
TW081109379A TW235927B (fr) 1991-11-15 1992-11-24

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9114206A FR2683816B1 (fr) 1991-11-15 1991-11-15 Procede d'aromatisation d'hydrocarbures contenant 2 a 4 atomes de carbone en presence d'un catalyseur a structure mfi.

Publications (2)

Publication Number Publication Date
FR2683816A1 FR2683816A1 (fr) 1993-05-21
FR2683816B1 true FR2683816B1 (fr) 1994-02-11

Family

ID=9419070

Family Applications (1)

Application Number Title Priority Date Filing Date
FR9114206A Expired - Fee Related FR2683816B1 (fr) 1991-11-15 1991-11-15 Procede d'aromatisation d'hydrocarbures contenant 2 a 4 atomes de carbone en presence d'un catalyseur a structure mfi.

Country Status (1)

Country Link
FR (1) FR2683816B1 (fr)

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4392989A (en) * 1981-05-11 1983-07-12 Mobil Oil Corporation Zinc-gallium zeolite
US4435283A (en) * 1982-02-01 1984-03-06 Chevron Research Company Method of dehydrocyclizing alkanes
US4808763A (en) * 1987-08-05 1989-02-28 Amoco Corporation Process for upgrading light paraffins
FR2634140B1 (fr) * 1988-07-12 1990-09-14 Inst Francais Du Petrole Catalyseur du type aluminosilicate contenant du gallium et son utilisation en aromatisation des gaz legers c2-c4
FR2634139B1 (fr) * 1988-07-12 1990-09-14 Inst Francais Du Petrole Catalyseur du type gallosilicate et son utilisation en aromatisation des gaz legers c2-c4

Also Published As

Publication number Publication date
FR2683816A1 (fr) 1993-05-21

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