FR2680527A1 - PRODUCT FOR POST-TREATMENT OF WASHED TEXTILES. - Google Patents

PRODUCT FOR POST-TREATMENT OF WASHED TEXTILES. Download PDF

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Publication number
FR2680527A1
FR2680527A1 FR9210085A FR9210085A FR2680527A1 FR 2680527 A1 FR2680527 A1 FR 2680527A1 FR 9210085 A FR9210085 A FR 9210085A FR 9210085 A FR9210085 A FR 9210085A FR 2680527 A1 FR2680527 A1 FR 2680527A1
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Prior art keywords
post
products
treatment
product
textiles
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FR9210085A
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French (fr)
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FR2680527B1 (en
Inventor
Kaspar D Hasenclever
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Chemische Fabrik Kreussler and Co GmbH
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Chemische Fabrik Kreussler and Co GmbH
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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/15—Proteins or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C11D3/0015—Softening compositions liquid
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3753—Polyvinylalcohol; Ethers or esters thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
    • D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/45—Shrinking resistance, anti-felting properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

Un produit pour le post-traitement de textiles lavés, qui améliore le toucher des textiles et en diminue le rétrécissement, contient une combinaison de poly(alcool vinylique) et/ou de poly(acétate de vinyle) avec un hydrolysat de protéines cationiques. Application à divers textiles fragiles, comme des articles en laine.A product for the aftertreatment of washed textiles, which improves the feel of textiles and decreases shrinkage, contains a combination of poly (vinyl alcohol) and / or poly (vinyl acetate) with a cationic protein hydrolyzate. Application to various fragile textiles, such as woolen articles.

Description

L'invention concerne un produit pour le traitementThe invention relates to a product for the treatment

ultérieur, ou post-traitement, de textiles lavés.  subsequent, or post-treatment, washed textiles.

Les textiles lavés, notamment des vêtements, subissent, du fait d'une lixiviation d'apprêts hydrosolubles, lors des lavages et nettoyages, des pertes de caractéristique de toucher et des pertes de couleur Il se produit en outre, lors du séchage dans des sèche- linges à tambour un phénomène ou processus de contraction ou rétrécissement et de salissure,qui peut conduire à des variations de mesures telles que des vêtements fragiles ne doivent normalement pas être  Washed textiles, especially garments, are subjected to washing and cleaning due to leaching of water-soluble finishes, loss of touch characteristics and loss of color. - drum cloths a phenomenon or process of contraction or shrinkage and soiling, which can lead to variations in measurements such that fragile clothing normally should not be

séchés dans des sèche-linges à tambour.  dried in tumble dryers.

On sait améliorer le toucher de textiles lavés et diminuer le rétrécissement lors du séchage en soumettant les textiles lavés à un traitement ultérieur à l'aide de produits qui contiennent, comme substances actives, par exemple du chlorure de distéaryldiméthylammonium en combinaison avec le  It is known to improve the feel of washed textiles and decrease the shrinkage during drying by subjecting the washed textiles to further processing with products which contain, as active substances, for example distearyldimethylammonium chloride in combination with the

monolaurate de glycérol ou le dilaurate de glycérol.  glycerol monolaurate or glycerol dilaurate.

L'amélioration que l'on peut obtenir à l'aide de tels produits connus de post-traitement ne suffit cependant pas pour permettre de sécher selon cette méthode des articles textiles, que l'on ne doit normalement pas traiter dans des sèche-linges à tambour, comme par exemple, des pull-overs en laine, des textiles de type angora ou des costumes en pure laine En outre, on ne souhaite également pas utiliser des produits à base de chlorure de distéaryldiméthylammonium (DSDMAC) en raison de leur mauvaise dégradation biologique dans de  The improvement that can be obtained using such known post-treatment products is not sufficient, however, to allow drying by this method of textile articles, which should not normally be treated in dryers such as woolen pullovers, angora-type textiles or pure wool suits. In addition, it is also not desirable to use distearyldimethylammonium chloride (DSDMAC) products because of their poor quality. biological degradation in

l'eau résiduaire.wastewater.

Le problème se trouvant à la base de l'invention a  The problem underlying the invention was

donc consisté à obtenir un produit permettant de post-  therefore consisted in obtaining a product allowing post-

traiter des textiles lavés et qui, par rapport à des produits connus pour des post-traitements, améliore le toucher des textiles et diminue le rétrécissement en cas de séchage dans des sèche-linges à tambour On  to treat washed textiles which, compared to products known for post-treatments, improves the touch of textiles and reduces the shrinkage when drying in tumble dryers On

souhaite en outre obtenir des produits pour post-  additionally wishes to obtain products for post-

traitement qui soient, autant que possible, dégradables  as far as possible, degradable

rapidement et par des processus biologiques.  quickly and through biological processes.

Selon l'invention, on résout ce problème à l'aide d'un produit pour le post-traitement de textiles lavés, ce produit étant caractérisé en ce qu'il contient une combinaison de poly(alcool vinylique) et/ou de poly(acétate de vinyle) comportant au moins un  According to the invention, this problem is solved by means of a product for the post-treatment of washed textiles, this product being characterized in that it contains a combination of polyvinyl alcohol and / or poly ( vinyl acetate) having at least one

hydrolysat cationique de protéines.  cationic hydrolyzate of proteins.

Il vient d'être trouvé que de tels produits pour post-traitement confèrent aux textiles traités un toucher élastique et soyeux extraordinairement agréable et diminuent de plus de la moitié le rétrécissement en cas de séchage dans des sèche-linges à tambour, en  It has just been found that such post-treatment products give the treated textiles an extraordinarily pleasant elastic and silky feel and reduce by more than half the shrinkage when drying in tumble dryers, in particular

comparaison des produits usuels pour un tel post-  comparison of the usual products for such a post-

traitement En outre, les hydrolysats cationiques de protéines sont dégradables rapidement et de manière  In addition, cationic protein hydrolysates are degradable rapidly and

entièrement biologique dans des eaux résiduaires.  entirely organic in waste water.

De préférence, l'hydrolysat de protéines utilisé selon l'invention est un hydrolysat de lauryldiméthylammonium hydroxypropylamino protéine de formule générale: CH 3 H 3 C- (CH 2)11-N±CH 2-CH-CH 2-(NH-CH-C)n-OH I I I Il  Preferably, the protein hydrolyzate used according to the invention is a hydrolyzate of lauryldimethylammonium hydroxypropylamino protein of general formula: ## STR2 ## -C) n-OH III He

CH 3 OH R OCH 3 OH R O

dans laquelle N vaut 1 à 3 et R représente les  in which N is 1 to 3 and R is

restes d'aminoacides du collagène.amino acid residues of collagen.

Lors de l'hydrolyse acide du collagène, il se  During the acid hydrolysis of collagen, it is

forme de la glycine, de la L-proline, de la trans-  form of glycine, L-proline, trans-

hydroxy-L-proline, de l'acide L-glutamique, de la L-  hydroxy-L-proline, L-glutamic acid, L-

arginine, de la L-alanine, de l'acide L-asparagique, de  arginine, L-alanine, L-asparagic acid,

la L-lysine, de la L-leucine, de la L-sérine, de la L-  L-lysine, L-leucine, L-serine, L-

Isoleucine, et de plus faibles quantités d'autres aminoacides, et, habituellement, il n'y a alors pas  Isoleucine, and smaller amounts of other amino acids, and usually then there is no

présence de L-tryptophanne, de L-tyrosine, et de L-  the presence of L-tryptophan, L-tyrosine, and L-

cystine Le symbole R désigne ainsi, essentiellement, dans la formule cidessus les restes des aminoacides cités ci-dessus, qui sont habituellement présents dans l'hydrolysat sous forme de mélange de chaînes latérales  cystine The symbol R thus denotes, essentially, in the formula above the remains of the amino acids mentioned above, which are usually present in the hydrolyzate in the form of a mixture of side chains

fixées sur le squelette de base.fixed on the base skeleton.

Cet hydrolysat de protéines est un liquide limpide, de couleur jaune, légèrement visqueux ayant un  This protein hydrolyzate is a clear, yellow, slightly viscous liquid having a

poids moléculaire moyen de l'ordre de 600 à 700.  average molecular weight of the order of 600 to 700.

Les poly(alcools vinyliques) possèdent des poids moléculaires de l'ordre de 18 000 à 200 000 et on les prépare habituellement par saponification alcaline de poly(acétate de vinyle) Dans le cadre du concept de l'invention, il y a donc aussi présence de poly(alcools vinyliques), qui contiennent encore certaines proportions de groupes acétate De préférence, les poids moléculaires des poly(alcools vinyliques) que l'on utilise dans l'invention sont dans la gamme de  Polyvinyl alcohols have molecular weights in the range of 18,000 to 200,000 and are usually prepared by alkaline saponification of polyvinyl acetate. Within the scope of the concept of the invention, therefore, there is also polyvinyl alcohols, which still contain certain proportions of acetate groups. Preferably, the molecular weights of the polyvinyl alcohols which are used in the invention are in the range of

000 à 100 000.000 to 100,000.

Le poly(acétate de vinyle) possède un poids mo-  Polyvinyl acetate has a moderate weight

léculaire de 10 000 à 1 500 000 On peut préparer du poly(acétate de vinyle) par polymérisation de l'acétate de vinyle en masse, en solution ou en suspension ou en émulsion aqueuse, dans la plupart des cas à l'aide de composés du type peroxyde Les poids moléculaires préférés pour la présente invention sont de 50 000 à  molecular weight 10,000 to 1,500,000 Polyvinyl acetate can be prepared by polymerization of vinyl acetate in bulk, in solution or in aqueous suspension or emulsion, in most cases using compounds The preferred molecular weights for the present invention are from 50,000 to

250 000.250,000.

Il est avantageux que le rapport pondéral entre le poly(acétate de vinyle) et/ou le poly(alcool vinylique) et l'hydrolysat de protéines cationiques se situe dans la gamme de 1:2 à 5, avantageusement dans la gamme de  It is advantageous for the weight ratio of polyvinyl acetate and / or polyvinyl alcohol to cationic protein hydrolyzate to be in the range of 1: 2 to 5, advantageously in the range of

1:3 à 5.1: 3 to 5.

Les exemples et exemples comparatifs qui suivent  The examples and comparative examples that follow

servent à expliciter encore davantage l'invention.  serve to further explain the invention.

Exemples et exemples comparatifs A des fins de comparaison, on a utilisé dans les essais qui suivent, à titre de produits A et B, deux produits connus pour servir un post-traitement de textiles lavés Le produit A consistait en 5 parties en poids de chlorure de distéaryldiméthylammonium, 15 parties en poids de monolaurate de glycérol, 10 parties en poids d'éthanol et 70 parties en poids d'eau Le produit D consistait en 10 parties en poids d'amidon de  EXAMPLES AND COMPARATIVE EXAMPLES For comparison purposes, two products known to be used as a post-treatment of washed textiles as products A and B were used as product A. Product A consisted of 5 parts by weight of chloride of distearyldimethylammonium, 15 parts by weight of glycerol monolaurate, 10 parts by weight of ethanol and 70 parts by weight of water. Product D consisted of 10 parts by weight of

riz, en dissolution dans 90 parties en poids d'eau.  rice, dissolved in 90 parts by weight of water.

Les deux produits C et D selon l'invention avaient la composition suivante, indiquée au tableau I  Both products C and D according to the invention had the following composition, indicated in Table I

Tableau ITable I

C DC D

Poly(alccol vinylique) 10 Poly(acétate de vinyle) 10 Hydrolyse de protéines cationiques 40 50 Eau 50 50 100 Les tissus d'essai ont été traités durant 10 minutes à 30 C dans des solutions aqueuses à 0,5 % de produits A et D, elles ont été centrifugées jusqu'à une humidité résiduelle de 40 %, puis séchées dans un sèche- linge domestique sur un programme "textile d'entretien facile" jusqu'à une humidité résiduelle  Poly (vinyl alcohol) Polyvinyl acetate Cationic protein hydrolysis 40 50 Water 50 50 100 The test tissues were treated for 10 minutes at 30 ° C. in 0.5% aqueous solutions of products A and D, they were centrifuged to a residual moisture of 40%, then dried in a domestic tumble dryer on a program "easy care textile" up to residual moisture

d'environ 3 % (séchage au fer à repasser).  about 3% (drying on an iron).

Après ce post-traitement, les tissus d'essai ont été évalués comme suit: toucher de l'article: tissu d'essai en pure laine, armure unie, 320/m 2 Evaluation sensorie avec la répartition suivante: flasque, souple ou mou, élastique, tissu plein ou volumineux, tissu dur  After this post-treatment, the test fabrics were evaluated as follows: touch of the article: pure wool test fabric, plain weave, 320 / m 2 Sensory evaluation with the following distribution: flaccid, soft or soft , elastic, solid or bulky fabric, hard tissue

ou rigide.or rigid.

Rétrécissement en séchoir: tissu d'essai rétréci  Shrinkage in dryer: shrunken test fabric

et feutré du Secrétariat International de la Laine.  and muffled by the International Wool Secretariat.

Pertes surfaciques en pourcentage de la valeur de départ. Les résultats obtenus se trouvent indiqués sur le  Area losses as a percentage of the starting value. The results obtained are indicated on the

tableau II.Table II.

Tableau IlTable II

îo Toucher de l'article Rétrécissement au séchage Eau sans additif flasque 17 % 0,5 % du produit A souple 12 % 0,5 % du produit B dur 14 % 0,5 % du produit C souple/toucher plein 7 % 0,5 % du produit D élastique/toucher plein 5 % On voit bien que les textiles traités à l'aide des produits pour post-traitement selon l'invention possèdent un meilleur toucher et sont l'objet d'un rétrécissement bien plus faible, au cours du séchage dans un sèche-linge à tambour, que les textiles traités  Touch of the article Shrinkage on drying Water without flask additive 17% 0.5% of the product A soft 12% 0.5% of the product B hard 14% 0.5% of the product C soft / full touch 7% 0, 5% of the product D elastic / full touch 5% It is clearly seen that the textiles treated with the after-treatment products according to the invention have a better feel and are subject to a much smaller shrinkage at drying in a tumble dryer, as treated textiles

par des produits connus pour des post-traitements.  by known products for post-treatments.

Claims (6)

REVENDICATIONS 1 Produits pour le post-traitement de textiles lavés, caractérisés en ce qu'ils contiennent une combinaison de poly(alcool vinylique) et/ou de poly(acétate de vinyle), avec un hydrolysat de  Products for the post-treatment of washed textiles, characterized in that they contain a combination of polyvinyl alcohol and / or polyvinyl acetate, with a hydrolyzate of protéines cationiques.cationic proteins. 2 Produits pour post-traitement selon la revendication 1, caractérisés en ce qu'ils contiennent, comme hydrolysat de protéines cationiques, un hydrolysat répondant à la formule générale: CH 3 H 3 C-(CH 2)ll ±CH-CH 2-(NH-CH-C)n-OH / l I II  Products for post-treatment according to claim 1, characterized in that they contain, as hydrolyzate of cationic proteins, a hydrolyzate corresponding to the general formula: CH 3 H 3 C- (CH 2) 11 + CH-CH 2 (NH-CH-C) n-OH / I I II CH 3 OH R OCH 3 OH R O dans laquelle N vaut 1 à 3 et R représente le reste  in which N is 1 to 3 and R is the remainder d'au moins un aminoacide du collagène.  at least one amino acid of the collagen. 3 Produits pour post-traitement selon la revendication 2, caractérisés en ce que R représente un  Products for post-treatment according to claim 2, characterized in that R represents a mélange de restes d'aminoacides du collagène.  mixture of amino acid residues of the collagen. 4 Produits pour post-traitement selon l'une  4 Products for post-processing according to one quelconque des revendications 1 à 3, caractérisés en ce  any of claims 1 to 3, characterized in that que leur rapport pondéral entre le poly(acétate de vinyle) et/ou le poly(alcool vinylique), d'une part, et l'hydrolysat de protéines cationiques, vaut 1:2 à 5,  that their weight ratio between polyvinyl acetate and / or polyvinyl alcohol on the one hand and the cationic protein hydrolyzate is 1: 2 to 5, avantageusement 1:3 à 5.advantageously 1: 3 to 5. 5 Produits pour post-traitement selon l'une  5 Products for post-processing according to one quelconque des revendications 1 à 4, caractérisés en ce  any of claims 1 to 4, characterized in that qu'on utilise du poly(alcool vinylique) ayant un poids moléculaire de 30 000 à 100 000 et/ou du poly(acétate de vinyle) ayant un poids moléculaire de 50 000 à  poly (vinyl alcohol) having a molecular weight of 30,000 to 100,000 and / or polyvinyl acetate having a molecular weight of 50,000 to 250 000.250,000.
FR9210085A 1991-08-25 1992-08-17 PRODUCT FOR AFTER-TREATMENT OF WASHED TEXTILES. Expired - Fee Related FR2680527B1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19914127944 DE4127944C2 (en) 1991-08-25 1991-08-25 Post-treatment agent for washed textiles

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FR2680527A1 true FR2680527A1 (en) 1993-02-26
FR2680527B1 FR2680527B1 (en) 1994-06-17

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Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10253217A1 (en) * 2002-11-15 2004-05-27 Cognis Deutschland Gmbh & Co. Kg Use of quaternized protein hydrolyzates in washing and cleaning agents
DE102016211701A1 (en) * 2016-06-29 2018-01-04 Henkel Ag & Co. Kgaa Acceleration of laundry drying

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1959651A1 (en) * 1969-11-28 1971-06-03 Henkel & Cie Gmbh Oligopeptide derivs for softening textiles
FR2219271A1 (en) * 1973-02-23 1974-09-20 Barker Graham
DE2712228A1 (en) * 1977-03-19 1978-09-28 Georg Dr Leiderer Protein hydrolysate from collagen by strong acid hydrolysis - useful as additive for tooth-pastes, textile and hair washing compsns.
GB2013221A (en) * 1978-01-27 1979-08-08 Kao Corp Fabric sizing emulsion
JPS57130961A (en) * 1981-02-04 1982-08-13 Seiwa Kasei:Kk Polypeptide derived from quaternary trimethylammonium
DE3536318A1 (en) * 1985-10-11 1987-04-16 Freudenberg Carl Fa Covering nonwoven for absorbent sanitary disposable articles
DE3725868A1 (en) * 1986-08-12 1988-02-18 Unilever Nv Permanent wave shampoo

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1959651A1 (en) * 1969-11-28 1971-06-03 Henkel & Cie Gmbh Oligopeptide derivs for softening textiles
FR2219271A1 (en) * 1973-02-23 1974-09-20 Barker Graham
DE2712228A1 (en) * 1977-03-19 1978-09-28 Georg Dr Leiderer Protein hydrolysate from collagen by strong acid hydrolysis - useful as additive for tooth-pastes, textile and hair washing compsns.
GB2013221A (en) * 1978-01-27 1979-08-08 Kao Corp Fabric sizing emulsion
JPS57130961A (en) * 1981-02-04 1982-08-13 Seiwa Kasei:Kk Polypeptide derived from quaternary trimethylammonium
DE3536318A1 (en) * 1985-10-11 1987-04-16 Freudenberg Carl Fa Covering nonwoven for absorbent sanitary disposable articles
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GB9214822D0 (en) 1992-08-26
DE4127944A1 (en) 1993-03-04
FR2680527B1 (en) 1994-06-17
GB2259094B (en) 1994-11-16
GB2259094A (en) 1993-03-03
DE4127944C2 (en) 1998-07-02

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