FR2566791A2 - Luminescent product, luminescent device employing this product and process for the manufacture of the said device - Google Patents

Luminescent product, luminescent device employing this product and process for the manufacture of the said device Download PDF

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Publication number
FR2566791A2
FR2566791A2 FR8306571A FR8306571A FR2566791A2 FR 2566791 A2 FR2566791 A2 FR 2566791A2 FR 8306571 A FR8306571 A FR 8306571A FR 8306571 A FR8306571 A FR 8306571A FR 2566791 A2 FR2566791 A2 FR 2566791A2
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France
Prior art keywords
component
product
mixture
pigment
resin
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Granted
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FR8306571A
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French (fr)
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FR2566791B2 (en
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Individual
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Individual
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Publication date
Priority claimed from FR8220207A external-priority patent/FR2569197B1/en
Application filed by Individual filed Critical Individual
Priority to FR8306571A priority Critical patent/FR2566791B2/en
Publication of FR2566791A2 publication Critical patent/FR2566791A2/en
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Publication of FR2566791B2 publication Critical patent/FR2566791B2/en
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
    • C09K11/02—Use of particular materials as binders, particle coatings or suspension media therefor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02—Organic and inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/22—Luminous paints

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Luminescent Compositions (AREA)

Abstract

Luminescent product consisting of a cured mixture comprising a resin which may be acrylic-based, a transparent liquid, a pigment which may be phosphorescent and a substance known per se at least partially absorbing ultraviolet rays, no radioactive substance being incorporated in the said mixture, the said product being stable and nonflammable, noteworthy in that the said product comprises: i. a resin which may be acrylic-based and an acrylic liquid; ii. a pigment comprising at least one of the following components: - component of the kind Zn S: Cu, - component of the kind Zn S; O: Mn, - component of the kind <2)<Zn, Mg) O: Zn S, the ratio of the various constituents of each of the said components being determined as a function of the desired result; iii. a substance at least partially absorbing ultraviolet rays; iv. optionally, a stabilising substance for the mixture and more particularly for the mixture of the acrylic-based substances and of the pigment. f

Description

PRODUIT LUMINESCENT, DISPOSITIF LUMINESCENT UTILISANT CE PRODUIT
ET PROCEDE DE FABRICATION DUDIT DISPOSITIF
Dans la demande de brevet principal N 82 20 207 du 2 Décembre 1982, au nom du déposant, il a été décrit un produit luminescent qui se distingue en ce qu'il est constitué par un mélange durci comprenant une résine pouvant être à base d'acryl , un liquide acrylique transparent, un pigment pouvant être phosphorescent et une matière connue en soi absorbant ou au moins filtrant les rayons ultraviolets ; sans qu'il y ait adjonction de matières radioactives; ledit produit étant stable et non inflammable.LUMINESCENT PRODUCT, LUMINESCENT DEVICE USING THE SAME
AND METHOD FOR MANUFACTURING THE DEVICE
In main patent application N 82 20 207 of December 2, 1982, in the name of the applicant, a luminescent product has been described which is distinguished in that it consists of a hardened mixture comprising a resin which may be based on acryl, a transparent acrylic liquid, a pigment which can be phosphorescent and a material known per se which absorbs or at least filters ultraviolet rays; without the addition of radioactive material; said product being stable and non-flammable.

Le présent certificat d'addition a pour objet de donner des précisions concernant diverses compositions du produit conforme à l'invention. The purpose of this addition certificate is to give details concerning various compositions of the product according to the invention.

Le produit comporte, en générat :
(i) - une résine pouvant être à base d'acryl et un liquide
acrylique ;
(ii)- un pigment comportant au moins l'un des composants
suivants :
- composant du genre Zn S : Cu
- composant du genre Zn2 S : O : Mn
- composant du genre (Zn , Mg) O : Zn S
le rapport entre les diverss constitutifs de chacun desdits
composants étant déterminé en fonction du résultat désiré ;
(iii)- une matière absorbant au moins partiellement les rayons
ultraviolets ;
(iv) - éventuellement, une matière stabilisatrice du mélange
et, plus particulièrement , du mélange entre les matières
à base d'acryl et du pigment.The product includes, in general:
(i) - a resin which may be based on acryl and a liquid
acrylic;
(ii) - a pigment comprising at least one of the components
following:
- component of genus Zn S: Cu
- component of the genus Zn2 S: O: Mn
- component of the genus (Zn, Mg) O: Zn S
the relationship between the various constituents of each of said
components being determined according to the desired result;
(iii) - a material which at least partially absorbs the rays
ultraviolet;
(iv) - optionally, a material stabilizing the mixture
and, more particularly, of the mixture between the materials
based on acryl and pigment.

Une telle matière stabilisatrice est connue en soi et vendue, par exemple, par la Sté RIEDEL DE HAEN A.G. de SEELZE en R.F.A. Such a stabilizing material is known per se and sold, for example, by RIEDEL DE HAEN A.G. of SEELZE in R.F.A.

Un certain nombre de mélanges seia indiqué ci-aprés, à titre d'exemples. A number of mixtures are indicated below, by way of examples.

Ainsi, selon un premier exemple, la composition du mélange constitutif dudit produit peut être la suivante :
(i) - Résine et liquide acrylique ... 35 % à 45 % ;
(ii) - Pigment comportant
- un premier composant Zn S : Cu ... 35 % à 45 %
- un deuxième composant Zn2 S : O : Mn.. 4 % à 6 % ;
- un troisième composant (Zn, Mg) O : Zn S ..3 % à 5 % ;
(iii) - Matière absorbant au moins partiellement
les rayons UV : ......... 5 % à 7 %
(iv) - Matière stabilisatrice ..... 1 % à 3 %
Selon un deuxième exemple, la composition du mélange peut être la suivante :
(i) - Résine et liquide acrylique ...35 % à 45 %
(ii) - Pigment compottont
- un premier composant
Zn S : Cu .................. 35 % à 45 %
- un deuxième composant
Zn2 S : O : Mn ........... 8 % à 12 % ;
(iii)- Matière absorbant au moins partiellement
les rayons UV :............ 8 % à 12 % ;
On trouve ci-après un troisième exemple d'un mélange dont la composition peut être la suivante :
(i) - Résine et liquide acrylique.. 25 % à 35 % ;
(ii) - Pigment comportant :
- un premier composant
Zn S : Cu ............... 45 % a 55 % ;
- un deuxième composant
Zn2 : S : O : Mn ......... 4 % à 6 % ;
- un troisième composant
(Zn, Mg) O : Zn S ....... 5 % à 7 % ;
(iii)- Matière stabilisatrice .... 9 % à 11 % ;
(iv) - Eventuellement, des traces de la matière absor
bant au moins partiellement les rayons UV.Thus, according to a first example, the composition of the constituent mixture of said product can be as follows:
(i) - Resin and acrylic liquid ... 35% to 45%;
(ii) - Pigment comprising
- a first component Zn S: Cu ... 35% to 45%
- a second component Zn2 S: O: Mn .. 4% to 6%;
- a third component (Zn, Mg) O: Zn S. 3% to 5%;
(iii) - At least partially absorbent material
UV rays: ......... 5% to 7%
(iv) - Stabilizing material ..... 1% to 3%
According to a second example, the composition of the mixture can be as follows:
(i) - Resin and acrylic liquid ... 35% to 45%
(ii) - Pigment compound
- a first component
Zn S: Cu .................. 35% to 45%
- a second component
Zn2 S: O: Mn ........... 8% to 12%;
(iii) - At least partially absorbent material
UV rays: ............ 8% to 12%;
Below is a third example of a mixture, the composition of which can be as follows:
(i) - Acrylic resin and liquid .. 25% to 35%;
(ii) - Pigment comprising:
- a first component
Zn S: Cu ............... 45% to 55%;
- a second component
Zn2: S: O: Mn ......... 4% to 6%;
- a third component
(Zn, Mg) O: Zn S ....... 5% to 7%;
(iii) - Stabilizing material .... 9% to 11%;
(iv) - Possibly traces of the absorbed material
bant at least partially UV rays.

Un quatrième exemple de la composition du mélange est précisé ci-après :
(i) - Résine et liquide
acrylique .............. 30 % à 40 % ;
(ii) - Pigment comportant :
- un premier comporant
Zn S : Cu ........... 45 % à 55 % ;
- un deuxième composant
(Zn, Mg) O : Zn S .... 5 % à 7 % ;
(iii) - Matière absorbant au moins
partiellement les rayons UV.. 4 % à 6 % ;
(iv) - Matière stabilisatrice ... 5 % à 7 % ;
D'autres compositions du mélange constitutif du produit selon l'invention peuvent être imaginées sans pour autant sortir du cadre de l'invention. A fourth example of the composition of the mixture is specified below:
(i) - Resin and liquid
acrylic .............. 30% to 40%;
(ii) - Pigment comprising:
- a first component
Zn S: Cu ........... 45% to 55%;
- a second component
(Zn, Mg) O: Zn S .... 5% to 7%;
(iii) - Absorbent material at least
partially UV rays. 4% to 6%;
(iv) - Stabilizing material ... 5% to 7%;
Other compositions of the constituent mixture of the product according to the invention can be imagined without departing from the scope of the invention.

Claims (5)

REVENDICATIONS --------------CLAIMS -------------- 1.) - Produit luminescent selon la revendication 1 du brevet principal constitué p@  1.) - Luminescent product according to claim 1 of the main patent constituted p @ un mélange durci comprenant une résine pouvant être à base d'acryl,un liquide acrylique transparent, un pigment pouvant être phosphorescent et une matière connue en soi absorbant au moins partiellement les rayons ultraviolets aucune matière radioactive n'étant incorporée dans ledit mélange, ledit produit étant stable et non inflammable, caractérisé en ce que ledit produit comporte : a hardened mixture comprising a resin which can be based on acryl, a transparent acrylic liquid, a pigment which can be phosphorescent and a material known per se absorbing at least partially the ultraviolet rays no radioactive material being incorporated in said mixture, said product being stable and non-flammable, characterized in that said product comprises: (i) - une résine pouvant être à base d'acryl et un liquide (i) - a resin which may be based on acryl and a liquid acrylique ; acrylic; (ii)- un pigment comportant au moins l'un des composants (ii) - a pigment comprising at least one of the components suivants : following: - composant du genre Zn S : Cu - component of genus Zn S: Cu - composant du gente Zn2 S; O : Mn - component of the gente Zn2 S; O: Mn - composant du gente (Zn , Mg) O :Zn S - component of the gente (Zn, Mg) O: Zn S le rapport entre les divers constitutifs de chacun desdits the relationship between the various constituents of each of said composants étant déterminé en fonction du résultat désiré ; components being determined according to the desired result; (iii)- une matière absorbant au moins partiellement les rayons (iii) - a material which at least partially absorbs the rays ultraviolets ; ultraviolet; (iv) - éventuellement, une matière stabilisatrice du mélange (iv) - optionally, a material stabilizing the mixture et plus particulièrement du mélange entre les matières and more particularly of the mixture between the materials à base d'acryl et du pigment. based on acryl and pigment. 2.) - Produit selon la revendication 1, caractérisé en ce que la composition du mélange constitutif du produit est :2.) - Product according to claim 1, characterized in that the composition of the constituent mixture of the product is: (i) - Résine et liquide acrylique ... 35 % à 45 % ; (i) - Resin and acrylic liquid ... 35% to 45%; (ii)- Pigment comportant : (ii) - Pigment comprising: - un premier composant - a first component Zn S : Cu ................... 35 % à 45 % ; Zn S: Cu ................... 35% to 45%; - un deuxième composant - a second component Zn2 S : O : Mn ............. 4 % à 6 % ; Zn2 S: O: Mn ............. 4% to 6%; - un troisième composant - a third component (Zn, Mg) O : Zn S ........ (Zn, Mg) O: Zn S ........ 3 % à 5 % ;3% to 5%; (iii)-Matière absorbant au moins partiellement les rayons (iii) -Material at least partially absorbing rays UV ........................ 5 % à 7 % ; UV ........................ 5% to 7%; (iv) -Matière stabilisatrice ....... 1 % à 3 % ; 3.) - Produit selon la revendication 1, caractérisé en ce que la composition du mélange constitutif du produit est : (iv) -Stabilizing material ....... 1% to 3%; 3.) - Product according to claim 1, characterized in that the composition of the constituent mixture of the product is: (i) - Résine et liquide acrylique ..... 35 % à 45 % ;  (i) - Resin and acrylic liquid ..... 35% to 45%; (ii) - Pigment comportant : (ii) - Pigment comprising: - un premier composant - a first component Zn S : Cu , 35 % à 45 % Zn S: Cu, 35% to 45% - un deuxième composant - a second component Zn2 S : O :Mn ...... 8 % à 12 % ; Zn2 S: O: Mn ...... 8% to 12%; (iii)- Matière absorbant au moins partiellement (iii) - At least partially absorbent material les rayons UV : .......... 8 % à 12 % ; 4.) - Produit selon la revendication 1, caractérisé en ce que la composition du mélange constitutif du produit est : UV rays: .......... 8% to 12%; 4.) - Product according to claim 1, characterized in that the composition of the constituent mixture of the product is: (i) - Résine et liquide acrylique.. 25 % à 35 % ; (i) - Acrylic resin and liquid .. 25% to 35%; (ii)- Pigment comportant : (ii) - Pigment comprising: - un premier composant - a first component Zn S : Cu ............. 45 % à 55 % ; Zn S: Cu ............. 45% to 55%; - un deuxieme composant Zn2 S : O : Mn ........ - a second component Zn2 S: O: Mn ........ 4 % 6 a t 4% 6 a t - un troisième composant (Zn, Mg) : O : Zn S ..... - a third component (Zn, Mg): O: Zn S ..... 5 % a 7 /0p t 5% a 7 / 0p t (iii) -Matière stabilisatrice ..... 9 % à 11 % ; (iii) -Stabilizing material ..... 9% to 11%; (iv) -Eventuellement, des traces de la matière absorbant (iv) -Possible traces of the absorbent material au moins partiellement les rayons UV ; 5.) - Produit selon la revendication 1, caractérisé en ce que la composition du mélange constitutif du produit est : at least partially UV rays; 5.) - Product according to claim 1, characterized in that the composition of the constituent mixture of the product is: (i) - Résine et liquide acrylique ..30 % à 40 % ; (i) - Resin and acrylic liquid. 30% to 40%; (ii)- Pigment comportant : (ii) - Pigment comprising: - un premier composant - a first component Zn S : Cu .......... 45 % a 55 % Zn S: Cu .......... 45% to 55% - un deuxieme composant - a second component (Zn, Mg) O : Zn S ..... 5 % à 7 % (Zn, Mg) O: Zn S ..... 5% to 7% (iii)-Matière absorbant au moins (iii) -Material absorbent at least partiellement les rayons UV .. 4 % à 6 % partially UV rays. 4% to 6% (iv) -Matière stabilisatrice ..... 5 % à 7 %  (iv) -Stabilizing material ..... 5% to 7%
FR8306571A 1982-12-02 1983-04-21 LUMINESCENT PRODUCT, LUMINESCENT DEVICE USING THE SAME AND MANUFACTURING METHOD THEREOF Expired FR2566791B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR8306571A FR2566791B2 (en) 1982-12-02 1983-04-21 LUMINESCENT PRODUCT, LUMINESCENT DEVICE USING THE SAME AND MANUFACTURING METHOD THEREOF

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR8220207A FR2569197B1 (en) 1982-12-02 1982-12-02 LUMINESCENT PRODUCT, LUMINESCENT DEVICE USING THE SAME AND MANUFACTURING METHOD THEREOF
FR8306571A FR2566791B2 (en) 1982-12-02 1983-04-21 LUMINESCENT PRODUCT, LUMINESCENT DEVICE USING THE SAME AND MANUFACTURING METHOD THEREOF

Publications (2)

Publication Number Publication Date
FR2566791A2 true FR2566791A2 (en) 1986-01-03
FR2566791B2 FR2566791B2 (en) 1988-09-23

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2658203A1 (en) * 1990-02-15 1991-08-16 Couverchel Daniel Luminescent product, especially for coating various surfaces, process for manufacture and applications
WO1991012292A1 (en) * 1990-02-15 1991-08-22 Couverchel Daniel Georges Photoluminescent materials, particularly for coating various surfaces, and uses thereof
FR2672611A1 (en) * 1991-02-08 1992-08-14 Couverchel Daniel Photoluminescent products especially for coating surfaces and its applications
US5140060A (en) * 1990-02-22 1992-08-18 Alps Electric Co., Ltd. Electroluminescence device
EP0518718A1 (en) * 1991-06-14 1992-12-16 Societe Francaise Hoechst Luminescent polymerisable fluid composition and its application

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2017741A (en) * 1978-01-23 1979-10-10 Norton C Warning Signs

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2017741A (en) * 1978-01-23 1979-10-10 Norton C Warning Signs

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2658203A1 (en) * 1990-02-15 1991-08-16 Couverchel Daniel Luminescent product, especially for coating various surfaces, process for manufacture and applications
WO1991012292A1 (en) * 1990-02-15 1991-08-22 Couverchel Daniel Georges Photoluminescent materials, particularly for coating various surfaces, and uses thereof
US5140060A (en) * 1990-02-22 1992-08-18 Alps Electric Co., Ltd. Electroluminescence device
FR2672611A1 (en) * 1991-02-08 1992-08-14 Couverchel Daniel Photoluminescent products especially for coating surfaces and its applications
EP0518718A1 (en) * 1991-06-14 1992-12-16 Societe Francaise Hoechst Luminescent polymerisable fluid composition and its application
FR2677659A1 (en) * 1991-06-14 1992-12-18 Hoechst France POLYMERIZABLE LUMINESCENT FLUID COMPOSITION AND APPLICATION THEREOF.
US5256725A (en) * 1991-06-14 1993-10-26 Societe Francaise Hoechst Polymerizable luminescent fluid composition and its use

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Publication number Publication date
FR2566791B2 (en) 1988-09-23

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