FR2499458A1 - Transparent plastic sheet with a shimmering appearance - made with a textile pattern printed on or applied as a base - Google Patents

Transparent plastic sheet with a shimmering appearance - made with a textile pattern printed on or applied as a base Download PDF

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Publication number
FR2499458A1
FR2499458A1 FR8102950A FR8102950A FR2499458A1 FR 2499458 A1 FR2499458 A1 FR 2499458A1 FR 8102950 A FR8102950 A FR 8102950A FR 8102950 A FR8102950 A FR 8102950A FR 2499458 A1 FR2499458 A1 FR 2499458A1
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FR
France
Prior art keywords
sheet
sheet according
support
mat
base
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR8102950A
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French (fr)
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FR2499458B1 (en
Inventor
Alain Goisnard
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MARECHAL ETS
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MARECHAL ETS
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Filing date
Publication date
Application filed by MARECHAL ETS filed Critical MARECHAL ETS
Priority to FR8102950A priority Critical patent/FR2499458A1/en
Priority to FR8108389A priority patent/FR2504448A2/en
Priority to IT2073582U priority patent/IT8220735V0/en
Priority to BE1/10420A priority patent/BE892056A/en
Priority to ES509517A priority patent/ES8305244A1/en
Priority to DE19828203855 priority patent/DE8203855U1/en
Publication of FR2499458A1 publication Critical patent/FR2499458A1/en
Application granted granted Critical
Publication of FR2499458B1 publication Critical patent/FR2499458B1/fr
Granted legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/065—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of foam
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/18—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/022—Non-woven fabric
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/245—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it being a foam layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44F—SPECIAL DESIGNS OR PICTURES
    • B44F1/00—Designs or pictures characterised by special or unusual light effects
    • B44F1/02—Designs or pictures characterised by special or unusual light effects produced by reflected light, e.g. matt surfaces, lustrous surfaces
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44F—SPECIAL DESIGNS OR PICTURES
    • B44F1/00—Designs or pictures characterised by special or unusual light effects
    • B44F1/08—Designs or pictures characterised by special or unusual light effects characterised by colour effects
    • B44F1/14—Iridescent effects
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44F—SPECIAL DESIGNS OR PICTURES
    • B44F9/00—Designs imitating natural patterns
    • B44F9/08—Designs imitating natural patterns of crystalline structures, pearl effects, or mother-of-pearl effects
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D06N7/0005—Floor covering on textile basis comprising a fibrous substrate being coated with at least one layer of a polymer on the top surface
    • D06N7/0028—Floor covering on textile basis comprising a fibrous substrate being coated with at least one layer of a polymer on the top surface characterised by colour effects, e.g. craquelé, reducing gloss
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B32B2307/402—Coloured
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B32B2307/409—Iridescent, pearlescent surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B32B2307/412—Transparent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2327/00—Polyvinylhalogenides
    • B32B2327/06—PVC, i.e. polyvinylchloride
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2375/00—Polyureas; Polyurethanes

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Laminated Bodies (AREA)

Abstract

Coloured plastic sheet with a shimmering appearance is made from transparent sheet having a mat texture on one face, due to an adjacent coating or base. The mat surface may be due to application of a coating of a mat varnish, having a colour identical to or differing from that of the transparent sheet, pref. being a slightly darker shade of the same colour, opt. printed on by any convenient technique in a pattern to resemble a textile. Esp. claimed for decorative effects from sheets made of polymers or copolymers of vinyl chloride or polyurethane resins tinted using complex organic metal salts and/or pigments having a refractive index similar to that of the base resin. The scintillating sheet may be backed by an adhesive-bonded support comprising either a cellular plastic layer or a fabric. Applicable to (waterproof) clothing, soft furnishings, shoes, decorations, etc.

Description

La présente invention concerne une feuille de matière plastique colorée d'aspect chatoyant et présentant des reflets analogues à ceux présentés par certains tissus tels que la soie. The present invention relates to a colored plastic sheet of shimmering appearance and having reflections similar to those presented by certain fabrics such as silk.

Il est bien connu de réaliser des feuilles de matières plastiques colorées translucides ou transparentes. En général, ces feuilles présentent une surface aussi lisse que possible. Ces feuilles présentent toujours un aspect qui ne permet aucun doute sur la nature de la matière constitutive et ne se rapproche en rien de celui d'un tissu tel que la soie. It is well known to produce sheets of translucent or transparent colored plastic materials. In general, these sheets have as smooth a surface as possible. These leaves always have an aspect which leaves no doubt as to the nature of the constituent material and is in no way close to that of a fabric such as silk.

La présente invention vise à fournir une feuille de matière plastique colorée d'aspect chatoyant et présentant des reflets analogues à ceux présentés par certains tissus tels que la soie. The present invention aims to provide a colored plastic sheet of shimmering appearance and having reflections similar to those presented by certain fabrics such as silk.

I1 s'agit de reflets pouvant aussi etre qualifiés de satinés ou de veloutés et provenant d'une variation de couleur, de profondeur ou d'intensité de coloration suivant l'incidence de la lumière réfléchie par la face apparente de la feuille. These are reflections which can also be qualified as satin or velvety and coming from a variation in color, depth or intensity of coloring depending on the incidence of the light reflected by the visible face of the sheet.

L'invention concerne à cet effet une feuille constituée d'une matière plastique colorée transparente qui présente sur une de ses faces, un état de surface mat. To this end, the invention relates to a sheet made of a transparent colored plastic material which has on one of its faces, a matt surface finish.

Toute matière plastique susceptible de permettre la formation d'une feuille transparente ou translucide sous une épaisseur de 10 mm peut convenir pour réaliser la feuille plastique conforme à l'invention. A titre d'exemples de pareilles matières plastiques, on peut citer les résines à base de polychîcrure ce vinyle ou de copolymères du chlorure de vinyle, les résines de polyuréthanes, les polyoléfines,les résines cellulosiques, les résines acryliques, les résines de polyamides et les résines de polyester. Parmi celles-ci, les résines à base de polychiorine de vinyle ou de copolymères du chlorure de vinyle et les res rwes de polyuréthanes sont préférées. Any plastic material capable of allowing the formation of a transparent or translucent sheet under a thickness of 10 mm may be suitable for producing the plastic sheet according to the invention. Examples of such plastics include resins based on polyvinyl chloride or vinyl chloride copolymers, polyurethane resins, polyolefins, cellulose resins, acrylic resins, polyamide resins and polyester resins. Among these, resins based on polyvinylchloride or on vinyl chloride copolymers and polyurethane resins are preferred.

Ces matières plastiques peuvent contenir ds additif s usuels tels que des plastifiants, des stabilisants, des matières de charge etc, pour autant que ces produits soient compatibles avec la production de feuilles transparentes comme spécifié ci-dessus. These plastics may contain usual additives such as plasticizers, stabilizers, fillers, etc., provided that these products are compatible with the production of transparent sheets as specified above.

Les colorants ou les pigments utilisés pour colorer la feuille selon l'invention doivent également être choisis en fonction de la matière plastique utilisée en vue de permettre la production de feuilles colorées transparentes. The dyes or pigments used to color the sheet according to the invention must also be chosen according to the plastic material used in order to allow the production of transparent colored sheets.

Parmi les colorants utilisables, on peut citer les colorants basiques, les colorants à l'acétate, les colorants à étain, les dérives mono- et diazoiques, les derivés d'amino-anthraquinones et les colorants du type des complexes métalliques organiques, ces derniers étant préférés. Among the dyes which can be used, mention may be made of basic dyes, acetate dyes, tin dyes, mono- and diazo derivatives, amino-anthraquinone derivatives and dyes of the type of organic metal complexes, the latter being preferred.

Les pigments utilisables présentent de préférence, un indice de réfraction voisin de celui de la matière plastique dans laquelle ils sont incorporés. La plupart des pigments inorganiques ou organiques satisfaisant a cette condition peuvent convenir. On peut aussi utiliser des pigments du type opacifiant seuls ou mélangés avec les matières colorantes susmentionnées c'est-a-dire des pigments ayant un indice de réfraction s 'écartant nettement de celui de la matière plastique pour autant que ceux-ci soient utilisés en quantités très faibles, de préférence n1 excédant pas 0,5% en poids environ par rapport au poids de la matière plastique a colorer. The pigments which can be used preferably have a refractive index close to that of the plastic material in which they are incorporated. Most inorganic or organic pigments satisfying this condition may be suitable. It is also possible to use pigments of the opacifying type alone or mixed with the abovementioned coloring materials, that is to say pigments having an index of refraction which is clearly different from that of the plastic material, provided that these are used in very small quantities, preferably n1 not exceeding about 0.5% by weight relative to the weight of the plastic to be colored.

Pour le choix des colorants et des pigments, on se référera utilement à l'ouvrage "La couleur et les plastique" de J.DELORME et
M.DERIBERE édité en 1960 par les éditions AMPHORA 119 avenue
Parmentier à Paris ou encore à un article de M.M.PEACOCK publié dans la revue Matiere Plastiche de septembre 1954 (p.708 à 720) ou enfin aux tableaux reproduits aux pages 682 et suivantes de
International Modern Plastics Encyclopedia, vol.52, NO 10A, 1975-1976, qui indiquent pour chaque type de matière plastique les colorants et pigments compatibles conduisant à des produits colorés transparents.For the choice of dyes and pigments, we will usefully refer to the book "Color and plastics" by J. DELORME and
M.DERIBERE published in 1960 by AMPHORA editions 119 avenue
Parmentier in Paris or an article by MMPEACOCK published in the journal Matiere Plastiche from September 1954 (p.708 to 720) or finally to the tables reproduced on pages 682 et seq.
International Modern Plastics Encyclopedia, vol. 52, NO 10A, 1975-1976, which indicate for each type of plastic the compatible dyes and pigments leading to transparent colored products.

La feuille de matière plastique colorée peut être produite selon toute technique connue et on peut citer à titre d'exemple l'enduction ou le coulage sur support provisoire à partir de solutions ou de dispersions, le calandrage, l'extrusion ou l'extrusion soufflée, le dépôt par cylindres lisses ou gravés, la sérigraphie, le pistolage et l'enduction par machine à rideau. The colored plastic sheet can be produced according to any known technique and mention may, for example, be made of coating or casting on a temporary support from solutions or dispersions, calendering, extrusion or blown extrusion. , deposit by smooth or engraved cylinders, serigraphy, spraying and coating by curtain machine.

La feuille conforme à l'invention doit présenter sur une de ses faces, un état de surface mat. Cet aspect de surface mat peut être conféré aux deux faces de la feuille plastique ou à une seule de ces deux faces, qui dans ce cas, est la face apparente lors de l'utilisation. The sheet according to the invention must have on one of its faces, a matt surface condition. This matt surface appearance can be imparted to the two faces of the plastic sheet or to only one of these two faces, which in this case is the visible face during use.

Cet état de surface mat peut être obtenu de diverses façons. This matt surface finish can be obtained in various ways.

Ainsi, selon une première technique, la feuille de matière plastique peut être produite par enduction ou coulage par transfert en utilisant un support mat tel qu'un papier mat ou une bande métallique mate sans fin comme support provisoire. Cet état peut encore etre obtenu par vernissage en utilisant un vernis mat ou une technique conduisant au matage du vernis. Cet état peut enfin etre réalisé par des voies mécaniques et thermiques telles que le grainage, le gaufrage ou encore le moulage par exemple par haute fréquence en utilisant une empreinte mate en silicone.Thus, according to a first technique, the plastic sheet can be produced by coating or transfer casting using a mat support such as a mat paper or an endless matte metal strip as a provisional support. This state can also be obtained by varnishing using a matt varnish or a technique leading to matting of the varnish. This state can finally be achieved by mechanical and thermal means such as embossing, embossing or even molding for example by high frequency using a matt silicone imprint.

La feuille conforme à l'invention peut etre autoportante ou etre associée à un support. Ce support peut etre constitué par une autre feuille de matière plastique colorée ou non, transparente ou opaque, par une feuille de matière plastique de structure cellulaire, par une plaque de bois ou d'un dérivé cellulosique, par une feuille de métal, par un textile tel qu'un tissé ou un tricot ou encore un non tissé, ce textile pouvant etre blanc, coloré, imprimé ou produit à partir de fils ou de fibres de différentes couleurs. The sheet according to the invention can be self-supporting or be associated with a support. This support may be constituted by another sheet of plastic material, colored or not, transparent or opaque, by a sheet of plastic material of cellular structure, by a wooden plate or a cellulose derivative, by a metal sheet, by a textile such as a woven or knitted fabric or a nonwoven, this textile being able to be white, colored, printed or produced from yarns or fibers of different colors.

L'association entre la feuille et le support peut être obtenue directement par application du support sur la matière plastique chaude ou non encore gélifiée ou réticulée ou encore à l'intervention d'une colle, cette colle pouvant être transparente et entre colorée. The association between the sheet and the support can be obtained directly by applying the support to the hot plastic material or not yet gelled or crosslinked or even with the intervention of an adhesive, this adhesive being able to be transparent and colored.

La feuille supportée ou non, norme à l'invention est, de par son aspect particulier, susceptible de nombreuses applications notamment dans le domaine du vertement, de l'ameublement, de la maroquinerie, de la chaussure et de la décoratIon. The supported or unsupported sheet, standard to the invention is, by its particular aspect, susceptible of numerous applications in particular in the field of embellishment, furniture, leather goods, footwear and decoration.

La feuille conforme à l'invention est par ailleurs explicitée plus en détail dans les deux exemples de réalisation prat-que suivants donnés titre illustratif et pour la description desquels on se réfèrera aux figures des dessins annexés dans lesquelles
- la fig.1 est une vue en coupe d'une feuille conforme a
l'invention réalisée selon le premier exemple
- la fig.2 est une vue schématique d'une installation pour
réaliser le produit selon la fig.1
- la fig.3 est une vue en coupe d'plue autre feuille conforme à
l'invention réalisée selon le second exemple.The sheet according to the invention is also explained in more detail in the following two practical examples given by way of illustration and for the description of which reference will be made to the figures of the accompanying drawings in which
- Fig.1 is a sectional view of a sheet conforming to
the invention made according to the first example
- Fig.2 is a schematic view of an installation for
make the product according to fig. 1
- Fig.3 is a sectional view of another sheet in accordance with
the invention carried out according to the second example.

Exemple 1
On réalise une pate incolore a partir d'une résine de poly uréthane aliphatique commercialisée sous la dénomination U6366 par la firme STAHL CHEMICAL INDUSTRIES B.V en diluant cette résine dans un mélange solvant compos de diméthylformamide, de toluène et d'isopropanol et on colore cette pâte avec 0,40 % an poids de la résine sèche de jaune de benzidine et 0,01: en poids de la résine sèche de noir de carbone. Les matières colorantes sont au préalable empâtées puis broyées par passage sur broyeur tricylindre dans une partie de la pâte de façon à réaliser un mélange maître qui est ensuite dispersé dans la pâte. L'extrait sec de la pâte colorée est de 30% en poids. On réalise également une colle constituée d'un adhésif incolore d'un type polyurethane en solution.Example 1
A colorless paste is produced from an aliphatic polyurethane resin marketed under the name U6366 by the company STAHL CHEMICAL INDUSTRIES BV by diluting this resin in a solvent mixture composed of dimethylformamide, toluene and isopropanol and this paste is colored. with 0.40% by weight of the dry resin of benzidine yellow and 0.01: by weight of the dry resin of carbon black. The coloring matters are previously pasted and then ground by passage over a three-cylinder mill in a portion of the dough so as to produce a masterbatch which is then dispersed in the dough. The dry extract of the colored paste is 30% by weight. An adhesive is also produced consisting of a colorless adhesive of the polyurethane type in solution.

Sur un papier transfert mat 1, ainsi qu'il est montré à la fig.2, on dépose, au moyen d'une racle sur contrepartie 2, une couche de la pâte colorée 3, le poids humide de pate déposée étant de 100 g/m2 humide. Le complexe ainsi formé est ensuite séché dans -un four à air chaud 4 puis refroidi par passage dans une enceinte de réfrigération 5. On dépose ensuite sur l'ensemble, côté enduit, une couche de la colle 6 au moyen d'une râcle sur contrepartie 7 et sur cette couche de colle encore humide on applique ensuite un support textile tissé 8. L'ensemble passe ensuite dans un four 9 qui assure la prise de la colle puis dans une enceinte de refroidissement 10. Après refroidissement, le tissu enduit 11 est séparé du papier transfert 1.Ce tissu enduit observé par sa face enduite présente un aspect chatoyant rappelant un textile et convient particulièrement pour la production de vêtements imperméables. Ce tissu enduit est représenté en coupe à la fig. 1.  On a mat transfer paper 1, as shown in fig. 2, a layer of colored paste 3 is deposited by means of a doctor blade on the counterpart 2, the wet weight of deposited paste being 100 g. / m2 wet. The complex thus formed is then dried in a hot air oven 4 and then cooled by passing through a refrigeration chamber 5. Next, a layer of glue 6 is deposited on the assembly, coated side, by means of a scraper on counterpart 7 and on this layer of glue, which is still wet, a woven textile support 8 is then applied. The assembly then passes through an oven 9 which sets the adhesive, then into a cooling chamber 10. After cooling, the coated fabric 11 is separated from the transfer paper 1. This coated fabric observed by its coated side has a shimmering appearance reminiscent of a textile and is particularly suitable for the production of waterproof clothing. This coated fabric is shown in section in FIG. 1.

Exemple 2
On réalise une première pâte constituée d'un mélange de polychlorure de vinyle de qualité "cristal clear" préparé par polymérisation en émulsion, de plastifiants (mélange de phtalate de butyle benzyle et de phtalate de dioctyle en proportion 15/50), d'une charge de carbonate de calcium, d'un diluant (kérosène désodorisé) et d'un sel de baryum comme stabilisant, et on colore cette pâte au moyen de 0,8% en poids de la résine sèche de bleu de phtalocyamine et de 0,01% en poids de la résine sèche de dioxyde de titane.Example 2
A first paste is produced, consisting of a mixture of polyvinyl chloride of "crystal clear" quality prepared by emulsion polymerization, of plasticizers (mixture of butyl benzyl phthalate and dioctyl phthalate in 15/50 proportion), of a load of calcium carbonate, of a diluent (deodorized kerosene) and of a barium salt as stabilizer, and this paste is colored by means of 0.8% by weight of the dry resin of phthalocyamine blue and 0, 01% by weight of the dry titanium dioxide resin.

On réalise également une seconde pâte identique à la précédente mais contenant en outre 1% en poids de la résine d'azodicarbonamide et un accélérateur de décomposition de ce composé. A second paste is also produced which is identical to the previous one but which also contains 1% by weight of the azodicarbonamide resin and an accelerator for the decomposition of this compound.

Enfin, on prépare un vernis mat ayant la composition suivante
copolymère de chlorure et d'acétate de vinyle 10
résine acrylique 5
diméthylformamide 20
méthyléthylcétone 60
silice 5
Le copolymère utilisé est un produit commercialisée par SOLVIC
SA sous la dénomination SOLVIC 550GA et la résine acrylique un produit commercialisé par ROHM GmbH sous la dénomination PLEXIGUM
M345.Finally, a matt varnish having the following composition is prepared
copolymer of vinyl chloride and acetate 10
acrylic resin 5
dimethylformamide 20
methyl ethyl ketone 60
silica 5
The copolymer used is a product marketed by SOLVIC
SA under the name SOLVIC 550GA and acrylic resin a product marketed by ROHM GmbH under the name PLEXIGUM
M345.

Sur un papier transfert brillant, on applique une couche de la première pâte et après prégélification une couche de la seconde pâte. Sur cette seconde couche encore humide, on applique un textile non tissé puis on fait passer l'ensemble dans un four pour provoquer la gélification des deux couches de pate et l'expansion de la seconde couche. Apres gélification n sépare l'ensemble formé du papier transfert.Sur la face enduite de l'ensemble ondépose ensuite une couche du vernis par l'intermédiare d'un cylindre tramé et ce a raison de 5g/m2 de vernis sec Après séchage du vernis on obtient un tissu enduit de polychorure de vinyle dont la face enduite présente egalement un aspect chatoyant rappelant celui d'un textile et qui convient particulièrement pour des applications dans le domaine de la chaussure Ce tissu enduit est illustré en coupe dans la fig.3 qui montre ses constituants successifs a savoir le textile non tissé 12, a couche de polychlorure de vinyle cellulaire 1-, la couche décorative de polychlorure de vinyle transparent et coloré 14 et la couche de vernis 15 donnant un etat de surface mat au tissu enduit.  On a glossy transfer paper, apply a layer of the first paste and after pregelling a layer of the second paste. On this second still wet layer, a nonwoven fabric is applied and then the assembly is passed through an oven to cause the gelling of the two layers of dough and the expansion of the second layer. After gelling n separates the whole formed from the transfer paper. On the coated side of the whole wavy layer a layer of varnish through a screened cylinder and this at the rate of 5 g / m2 of dry varnish After drying the varnish a fabric coated with polyvinyl chloride is obtained, the coated side of which also has a shimmering appearance reminiscent of a textile and which is particularly suitable for applications in the field of footwear. This coated fabric is illustrated in section in FIG. 3 which shows its successive constituents, namely the nonwoven fabric 12, with a layer of cellular polyvinyl chloride 1-, the decorative layer of transparent and colored polyvinyl chloride 14 and the layer of varnish 15 giving a matt surface state to the coated fabric.

Claims (9)

REVENDICATIONS 1 - Feuille en matière plastique colorée d'aspect chatoyant caractérisée en ce qu'elle est constituée d'une matière plastique colorée transparente et en ce qu'elle présente sur une de ses faces un état de surface mat. 1 - Sheet of colored plastic material of shimmering appearance characterized in that it consists of a transparent colored plastic material and in that it has on one of its faces a matt surface condition. 2 - Feuille selon la revendication 1 caractérisée en ce que la matière plastique transparente est une résine à base de polychlorure de vinyle ou de copolymère du chlorure de vinyle ou une résine de polyuréthane. 2 - Sheet according to claim 1 characterized in that the transparent plastic is a resin based on polyvinyl chloride or copolymer of vinyl chloride or a polyurethane resin. 3 - Feuille selon la revendication 1 ou 2 caractérisée en ce que la matière plastique colorée transparente contient un colorant du type des complexes métalliques organiques. 3 - Sheet according to claim 1 or 2 characterized in that the transparent colored plastic material contains a dye of the type of organic metal complexes. 4 - Feuille selon l'une quelconque des revendications 1 à 3 caractérisée en ce que la matière plastique colorée transparente contient un pigment ayant un indice de réfraction sensiblement egal à celui de la résine constituant la feuille. 4 - Sheet according to any one of claims 1 to 3 characterized in that the transparent colored plastic material contains a pigment having a refractive index substantially equal to that of the resin constituting the sheet. 5 - Feuille plastique selon l'une quelconque des revendications 1 à 4 caractérisée en ce que la face présentant 11 état de surface mat comprend une couche de vernis mat. 5 - Plastic sheet according to any one of claims 1 to 4 characterized in that the face having 11 mat surface state comprises a layer of mat varnish. 6 - Feuille selon l'une quelconque des revendications 1 à 5 caractérisée en ce qu'elle est associée à un support. 6 - Sheet according to any one of claims 1 to 5 characterized in that it is associated with a support. 7 - Feuille selon la revendication 6 caractérisée en ce que le support est une feuille de matière plastique cellulaire. 7 - Sheet according to claim 6 characterized in that the support is a sheet of cellular plastic. 8 - Feuille selon la revendication 6 caractérisée en ce que le support est un support textile. 8 - Sheet according to claim 6 characterized in that the support is a textile support. 9 - Feuille plastique selon l'une quelconque des revendications 6 à 8 caractérisée en ce que la feuille est associée au support par l'intermédiaire d'une colle.  9 - Plastic sheet according to any one of claims 6 to 8 characterized in that the sheet is associated with the support by means of an adhesive.
FR8102950A 1981-02-12 1981-02-12 Transparent plastic sheet with a shimmering appearance - made with a textile pattern printed on or applied as a base Granted FR2499458A1 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
FR8102950A FR2499458A1 (en) 1981-02-12 1981-02-12 Transparent plastic sheet with a shimmering appearance - made with a textile pattern printed on or applied as a base
FR8108389A FR2504448A2 (en) 1981-02-12 1981-04-23 Transparent plastic sheet with a shimmering appearance - made with a textile pattern printed on or applied as a base
IT2073582U IT8220735V0 (en) 1981-02-12 1982-02-05 COLORED PLASTIC SHEET OF CHANGING APPEARANCE.
BE1/10420A BE892056A (en) 1981-02-12 1982-02-08 COLORFUL PLASTIC MATERIAL SHEET
ES509517A ES8305244A1 (en) 1981-02-12 1982-02-11 Transparent plastic sheet with a shimmering appearance - made with a textile pattern printed on or applied as a base
DE19828203855 DE8203855U1 (en) 1981-02-12 1982-02-12 COLORED PLASTIC FILM SHimmering Appearance

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR8102950A FR2499458A1 (en) 1981-02-12 1981-02-12 Transparent plastic sheet with a shimmering appearance - made with a textile pattern printed on or applied as a base

Publications (2)

Publication Number Publication Date
FR2499458A1 true FR2499458A1 (en) 1982-08-13
FR2499458B1 FR2499458B1 (en) 1983-07-29

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FR8102950A Granted FR2499458A1 (en) 1981-02-12 1981-02-12 Transparent plastic sheet with a shimmering appearance - made with a textile pattern printed on or applied as a base

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Country Link
BE (1) BE892056A (en)
FR (1) FR2499458A1 (en)

Cited By (1)

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Publication number Priority date Publication date Assignee Title
WO2000041584A1 (en) * 1999-01-12 2000-07-20 Texon Uk Limited Shoe insole and sheet material suitable for use in making a shoe insole

Families Citing this family (1)

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Publication number Priority date Publication date Assignee Title
GB2339785A (en) * 1998-06-26 2000-02-09 Michael Ellis Retroreflective PVC coatings

Citations (11)

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DE483322C (en) * 1927-11-18 1929-09-28 Leopold Rado Process for the production of silk or brocade-like fabrics
FR1246355A (en) * 1958-10-24 1960-11-18 Patrician Plastic Corp Method and apparatus for the manufacture of pearlescent plastic sheet and products thus obtained
US2971223A (en) * 1959-01-16 1961-02-14 Grunin Louis Process of preparing cast synthetic resin having integral sheen
US3125484A (en) * 1959-11-12 1964-03-17 Flexible plastic sheet haying
FR1356316A (en) * 1963-02-06 1964-03-27 Rhone Poulenc Sa New decorative items
FR1469886A (en) * 1965-02-23 1967-02-17 Ici Ltd Matt lacquer
BE696820A (en) * 1967-04-10 1967-10-10
FR1516901A (en) * 1967-01-04 1968-02-05 Chausson Usines Sa Process for the production of sheets, plates and the like of synthetic resin
GB1106211A (en) * 1964-03-16 1968-03-13 Gen Tire & Rubber Co Article having iridescent surface and method of making same
DE2222871A1 (en) * 1972-05-10 1973-11-22 Wella Ag Iridescent effect lacquering - avoiding masking the display of the basic lacquer colouring
DE2903212A1 (en) * 1979-01-27 1980-07-31 Manfred Rudolf Neuberger Printing ink contg. pearly titanium oxide pigment - for offset printing giving mother-of-pearl effects on plastics, paper, etc.

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Publication number Priority date Publication date Assignee Title
DE483322C (en) * 1927-11-18 1929-09-28 Leopold Rado Process for the production of silk or brocade-like fabrics
FR1246355A (en) * 1958-10-24 1960-11-18 Patrician Plastic Corp Method and apparatus for the manufacture of pearlescent plastic sheet and products thus obtained
US2971223A (en) * 1959-01-16 1961-02-14 Grunin Louis Process of preparing cast synthetic resin having integral sheen
US3125484A (en) * 1959-11-12 1964-03-17 Flexible plastic sheet haying
FR1356316A (en) * 1963-02-06 1964-03-27 Rhone Poulenc Sa New decorative items
GB1106211A (en) * 1964-03-16 1968-03-13 Gen Tire & Rubber Co Article having iridescent surface and method of making same
FR1469886A (en) * 1965-02-23 1967-02-17 Ici Ltd Matt lacquer
FR1516901A (en) * 1967-01-04 1968-02-05 Chausson Usines Sa Process for the production of sheets, plates and the like of synthetic resin
CH477289A (en) * 1967-01-04 1969-08-31 Chausson Usines Sa Process for the production of synthetic resin laminated sheets or plates
BE696820A (en) * 1967-04-10 1967-10-10
DE2222871A1 (en) * 1972-05-10 1973-11-22 Wella Ag Iridescent effect lacquering - avoiding masking the display of the basic lacquer colouring
DE2903212A1 (en) * 1979-01-27 1980-07-31 Manfred Rudolf Neuberger Printing ink contg. pearly titanium oxide pigment - for offset printing giving mother-of-pearl effects on plastics, paper, etc.

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000041584A1 (en) * 1999-01-12 2000-07-20 Texon Uk Limited Shoe insole and sheet material suitable for use in making a shoe insole

Also Published As

Publication number Publication date
FR2499458B1 (en) 1983-07-29
BE892056A (en) 1982-08-09

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