FR2445310A1 - Catalyseur et procede de production de l'acide methacrylique par oxydation de la methacroleine en phase vapeur - Google Patents
Catalyseur et procede de production de l'acide methacrylique par oxydation de la methacroleine en phase vapeurInfo
- Publication number
- FR2445310A1 FR2445310A1 FR7931595A FR7931595A FR2445310A1 FR 2445310 A1 FR2445310 A1 FR 2445310A1 FR 7931595 A FR7931595 A FR 7931595A FR 7931595 A FR7931595 A FR 7931595A FR 2445310 A1 FR2445310 A1 FR 2445310A1
- Authority
- FR
- France
- Prior art keywords
- oxidation
- methacrylic acid
- catalyst
- methacroleine
- steam
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 title abstract 3
- STNJBCKSHOAVAJ-UHFFFAOYSA-N Methacrolein Chemical compound CC(=C)C=O STNJBCKSHOAVAJ-UHFFFAOYSA-N 0.000 title abstract 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 title abstract 2
- 230000003647 oxidation Effects 0.000 title abstract 2
- 238000007254 oxidation reaction Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title 1
- 238000004326 stimulated echo acquisition mode for imaging Methods 0.000 title 1
- 150000001299 aldehydes Chemical class 0.000 abstract 1
- 229910052787 antimony Inorganic materials 0.000 abstract 1
- 229910052785 arsenic Inorganic materials 0.000 abstract 1
- 229910052788 barium Inorganic materials 0.000 abstract 1
- 229910052792 caesium Inorganic materials 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000011521 glass Substances 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229910052750 molybdenum Inorganic materials 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 229910052758 niobium Inorganic materials 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 229910052763 palladium Inorganic materials 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 229910052697 platinum Inorganic materials 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 229910052702 rhenium Inorganic materials 0.000 abstract 1
- 229910052703 rhodium Inorganic materials 0.000 abstract 1
- 229910052701 rubidium Inorganic materials 0.000 abstract 1
- 229910052707 ruthenium Inorganic materials 0.000 abstract 1
- 229910052712 strontium Inorganic materials 0.000 abstract 1
- 229910052721 tungsten Inorganic materials 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
- 239000012808 vapor phase Substances 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8878—Chromium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/885—Molybdenum and copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8871—Rare earth metals or actinides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8872—Alkali or alkaline earth metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8876—Arsenic, antimony or bismuth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8993—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with chromium, molybdenum or tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
L'invention concerne une composition de catalyseur permettant d'oxyder par O2 moléculaire des aldéhydes insaturés en phase vapeur. Le catalyseur comprend une combinaison d'oxydes de Mo, Cu, P, Sb et Cs et/ou Ca, et il peut éventuellement aussi comprendre au moins l'un des éléments Ni, Zn Ru, Rh, Pd, Pt, As, K, Rb, Sr, Ba, Cr, V, Nb, W, Mn, Re et les terres rares, y compris La. Application : oxydation de la méthacroléine en acide méthacrylique pouvant servir à la fabrication de verres organiques
Applications Claiming Priority (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US05/973,354 US4374757A (en) | 1978-12-26 | 1978-12-26 | Catalyst and process for producing methacrylic acid |
US05/973,495 US4252683A (en) | 1978-12-26 | 1978-12-26 | Catalyst for producing methacrylic acid |
US05/972,743 US4252681A (en) | 1978-12-26 | 1978-12-26 | Catalyst for producing methacrylic acid |
US05/972,745 US4252682A (en) | 1978-12-26 | 1978-12-26 | Catalyst for producing methacrylic acid |
US06/027,632 US4240930A (en) | 1979-04-06 | 1979-04-06 | Catalyst and process for producing methacrylic acid |
US06/027,635 US4261860A (en) | 1979-04-06 | 1979-04-06 | Catalyst for producing methacrylic acid |
US06/027,634 US4261859A (en) | 1979-04-06 | 1979-04-06 | Catalyst for producing methacrylic acid |
US06/027,633 US4261858A (en) | 1979-04-06 | 1979-04-06 | Catalyst for producing methacrylic acid |
US06/047,860 US4377501A (en) | 1978-12-26 | 1979-06-12 | Catalyst and process for producing methacrylic acid |
US06/081,406 US4271040A (en) | 1978-12-26 | 1979-10-03 | Catalyst and process for producing methacrylic acid |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2445310A1 true FR2445310A1 (fr) | 1980-07-25 |
FR2445310B1 FR2445310B1 (fr) | 1984-05-25 |
Family
ID=27580733
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7931595A Granted FR2445310A1 (fr) | 1978-12-26 | 1979-12-24 | Catalyseur et procede de production de l'acide methacrylique par oxydation de la methacroleine en phase vapeur |
Country Status (7)
Country | Link |
---|---|
BR (1) | BR7908476A (fr) |
DE (1) | DE2952455C2 (fr) |
FR (1) | FR2445310A1 (fr) |
GB (3) | GB2040717B (fr) |
IT (1) | IT1164100B (fr) |
MX (1) | MX154396A (fr) |
NL (1) | NL7909142A (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2509722A1 (fr) * | 1981-07-17 | 1983-01-21 | Halcon Sd Group Inc | Procede d'oxydation catalytique, en phase vapeur, de la methacroleine en acide methacrylique par de l'oxygene moleculaire |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3030243A1 (de) * | 1980-08-09 | 1982-03-18 | Basf Ag, 6700 Ludwigshafen | Oxidationskatalysator insbesondere fuer die herstellung von methacrylsaeure durch gasphasenoxidation von methacrolein |
US4511548A (en) * | 1981-12-18 | 1985-04-16 | The Standard Oil Company | Ammoxidation of methanol to produce hydrogen cyanide |
DE3208571A1 (de) * | 1982-03-10 | 1983-09-22 | Basf Ag, 6700 Ludwigshafen | Oxidationskatalysator, insbesondere fuer die herstellung von methacrylsaeure durch gasphasenoxidation von methacrolein |
DE3208572A1 (de) * | 1982-03-10 | 1983-09-22 | Basf Ag, 6700 Ludwigshafen | Verfahren und katalysator zur herstellung von methacrylsaeure |
JPS59115750A (ja) * | 1982-12-22 | 1984-07-04 | Nippon Shokubai Kagaku Kogyo Co Ltd | メタクリル酸合成用触媒 |
DE19630832A1 (de) | 1996-07-31 | 1998-02-05 | Hoechst Ag | Verfahren zur selektiven Herstellung von Essigsäure |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2273586A1 (fr) * | 1974-06-07 | 1976-01-02 | Nippon Kayaku Kk | Catalyseur d'oxydation pour produire l'acide methacrylique |
FR2275436A1 (fr) * | 1974-05-31 | 1976-01-16 | Mitsubishi Rayon Co | Procede pour la preparation de l'acide acrylique ou de l'acide methacrylique |
FR2297082A1 (fr) * | 1975-01-13 | 1976-08-06 | Standard Oil Co | Catalyseurs d'oxydation |
FR2306188A1 (fr) * | 1975-04-03 | 1976-10-29 | Mitsubishi Rayon Co | Procede de preparation d'un acide carboxylique insature |
US4000088A (en) * | 1974-06-03 | 1976-12-28 | Nippon Kayaku Co., Ltd. | Oxidation catalyst for the manufacture of methacrylic acid |
FR2333770A1 (fr) * | 1975-12-03 | 1977-07-01 | Mitsubishi Rayon Co | Procede catalytique de fabrication d'acides carboxyliques insatures et produits obtenus par ce procede |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2460541C3 (de) * | 1973-12-29 | 1979-10-18 | Nippon Shokubai Kagaku Kogyo Co. Ltd., Osaka (Japan) | Phosphor, Molybdän und Vanadium sowie gegebenenfalls Kupfer, Kobalt, Zirkon, Wismut, Antimon und/oder Arsen enthaltender Oxydkatalysator und dessen Verwendung zur Herstellung von Methacrylsäure |
GB1489559A (en) * | 1975-03-03 | 1977-10-19 | Mitsubishi Rayon Co | Catalytic process for the preparation of acrylic acid or methacrylic acid |
-
1979
- 1979-12-19 NL NL7909142A patent/NL7909142A/nl not_active Application Discontinuation
- 1979-12-21 IT IT51168/79A patent/IT1164100B/it active
- 1979-12-21 BR BR7908476A patent/BR7908476A/pt unknown
- 1979-12-24 GB GB7944392A patent/GB2040717B/en not_active Expired
- 1979-12-24 FR FR7931595A patent/FR2445310A1/fr active Granted
- 1979-12-27 DE DE2952455A patent/DE2952455C2/de not_active Expired
-
1980
- 1980-01-02 MX MX180602A patent/MX154396A/es unknown
-
1983
- 1983-03-15 GB GB08307119A patent/GB2121309B/en not_active Expired
- 1983-03-15 GB GB08307118A patent/GB2116063B/en not_active Expired
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2275436A1 (fr) * | 1974-05-31 | 1976-01-16 | Mitsubishi Rayon Co | Procede pour la preparation de l'acide acrylique ou de l'acide methacrylique |
US4000088A (en) * | 1974-06-03 | 1976-12-28 | Nippon Kayaku Co., Ltd. | Oxidation catalyst for the manufacture of methacrylic acid |
FR2273586A1 (fr) * | 1974-06-07 | 1976-01-02 | Nippon Kayaku Kk | Catalyseur d'oxydation pour produire l'acide methacrylique |
FR2297082A1 (fr) * | 1975-01-13 | 1976-08-06 | Standard Oil Co | Catalyseurs d'oxydation |
FR2306188A1 (fr) * | 1975-04-03 | 1976-10-29 | Mitsubishi Rayon Co | Procede de preparation d'un acide carboxylique insature |
FR2333770A1 (fr) * | 1975-12-03 | 1977-07-01 | Mitsubishi Rayon Co | Procede catalytique de fabrication d'acides carboxyliques insatures et produits obtenus par ce procede |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2509722A1 (fr) * | 1981-07-17 | 1983-01-21 | Halcon Sd Group Inc | Procede d'oxydation catalytique, en phase vapeur, de la methacroleine en acide methacrylique par de l'oxygene moleculaire |
Also Published As
Publication number | Publication date |
---|---|
GB2121309B (en) | 1984-06-06 |
MX154396A (es) | 1987-08-07 |
GB8307118D0 (en) | 1983-04-20 |
GB8307119D0 (en) | 1983-04-20 |
GB2040717B (en) | 1983-09-14 |
GB2121309A (en) | 1983-12-21 |
NL7909142A (nl) | 1980-06-30 |
GB2040717A (en) | 1980-09-03 |
DE2952455A1 (de) | 1980-07-17 |
DE2952455C2 (de) | 1988-07-28 |
IT1164100B (it) | 1987-04-08 |
IT7951168A0 (it) | 1979-12-21 |
BR7908476A (pt) | 1980-09-23 |
GB2116063B (en) | 1984-02-01 |
FR2445310B1 (fr) | 1984-05-25 |
GB2116063A (en) | 1983-09-21 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |