FR2444019A1 - Butadiene prepn. by dehydrogenation of butane - using catalyst contg. oxides of vanadium, antimony, nickel, thorium and titanium on support - Google Patents

Butadiene prepn. by dehydrogenation of butane - using catalyst contg. oxides of vanadium, antimony, nickel, thorium and titanium on support

Info

Publication number
FR2444019A1
FR2444019A1 FR7835423A FR7835423A FR2444019A1 FR 2444019 A1 FR2444019 A1 FR 2444019A1 FR 7835423 A FR7835423 A FR 7835423A FR 7835423 A FR7835423 A FR 7835423A FR 2444019 A1 FR2444019 A1 FR 2444019A1
Authority
FR
France
Prior art keywords
butadiene
butane
support
oxides
oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7835423A
Other languages
French (fr)
Other versions
FR2444019B1 (en
Inventor
Lidia Petrovna Pilaeva
Zhalya Magerram Ky Seifullaeva
Vagab Safarovich Aliev
Ramiz Gasan Kuli Ogly Rizaev
Veli Sultan Mur Gadzhi-Kasumov
Beniamin Georgiev Ter-Sarkisov
Et Rashid Musaevic Talyshinsky
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
INST NEFTEKHIMICHESKIKH PROT
Original Assignee
INST NEFTEKHIMICHESKIKH PROT
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by INST NEFTEKHIMICHESKIKH PROT filed Critical INST NEFTEKHIMICHESKIKH PROT
Priority to FR7835423A priority Critical patent/FR2444019A1/en
Publication of FR2444019A1 publication Critical patent/FR2444019A1/en
Application granted granted Critical
Publication of FR2444019B1 publication Critical patent/FR2444019B1/fr
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/847—Vanadium, niobium or tantalum or polonium
    • B01J23/8472—Vanadium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Butadiene-1, 3 is prepd. by dehydrogenating n-butane opt. mixed with n-butane at 550-650 degrees C in the presence of oxygen an inert diluent and a catalyst contg. oxides of V and Sb deposited on a support. Specifically, the catalyst system comprises (wt. %) 5-20 (7-15) Sb2O3, 2-10 (4-8) V oxide, 4-20 (7-13) Ni oxide, 0.1-1 (0.4-0.6) Th oxide, 0.1-1 (0.4-0.6) Ti oxide and balance support (pref. Al2O3). Apart from being an important monomer, butadiene-1,3 is also used for the synthesis of hexamethylenediamine and adipic acid. The catalyst gives a high productivity of butadiene-1,3, is stable in use, has high mechanical strength and does not require periodic regeneration.
FR7835423A 1978-12-15 1978-12-15 Butadiene prepn. by dehydrogenation of butane - using catalyst contg. oxides of vanadium, antimony, nickel, thorium and titanium on support Granted FR2444019A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR7835423A FR2444019A1 (en) 1978-12-15 1978-12-15 Butadiene prepn. by dehydrogenation of butane - using catalyst contg. oxides of vanadium, antimony, nickel, thorium and titanium on support

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7835423A FR2444019A1 (en) 1978-12-15 1978-12-15 Butadiene prepn. by dehydrogenation of butane - using catalyst contg. oxides of vanadium, antimony, nickel, thorium and titanium on support

Publications (2)

Publication Number Publication Date
FR2444019A1 true FR2444019A1 (en) 1980-07-11
FR2444019B1 FR2444019B1 (en) 1982-03-26

Family

ID=9216201

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7835423A Granted FR2444019A1 (en) 1978-12-15 1978-12-15 Butadiene prepn. by dehydrogenation of butane - using catalyst contg. oxides of vanadium, antimony, nickel, thorium and titanium on support

Country Status (1)

Country Link
FR (1) FR2444019A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2831021A4 (en) * 2012-03-29 2015-11-18 Tpc Group Llc Improved controllability oxidative dehydrogenation process for producing butadiene

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1398502A (en) * 1963-06-13 1965-05-07 Distillers Co Yeast Ltd Process for the production of conjugated diolefins

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1398502A (en) * 1963-06-13 1965-05-07 Distillers Co Yeast Ltd Process for the production of conjugated diolefins

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2831021A4 (en) * 2012-03-29 2015-11-18 Tpc Group Llc Improved controllability oxidative dehydrogenation process for producing butadiene
US9908097B2 (en) 2012-03-29 2018-03-06 Tpc Group Llc Controllability oxidative dehydrogenation process for producing butadiene

Also Published As

Publication number Publication date
FR2444019B1 (en) 1982-03-26

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