FR2411030A1 - Catalyst comprising metal, esp. nickel, on porous support - used for amination of ethanolamine to piperazine and ethylene di:amine - Google Patents

Catalyst comprising metal, esp. nickel, on porous support - used for amination of ethanolamine to piperazine and ethylene di:amine

Info

Publication number
FR2411030A1
FR2411030A1 FR7737346A FR7737346A FR2411030A1 FR 2411030 A1 FR2411030 A1 FR 2411030A1 FR 7737346 A FR7737346 A FR 7737346A FR 7737346 A FR7737346 A FR 7737346A FR 2411030 A1 FR2411030 A1 FR 2411030A1
Authority
FR
France
Prior art keywords
catalyst
piperazine
ethanolamine
metal
esp
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7737346A
Other languages
French (fr)
Other versions
FR2411030B1 (en
Inventor
Yannick Le Goff
Michel Senes
Christian Hamon
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Azote et Produits Chimiques SA
Original Assignee
Azote et Produits Chimiques SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Azote et Produits Chimiques SA filed Critical Azote et Produits Chimiques SA
Priority to FR7737346A priority Critical patent/FR2411030A1/en
Priority to SU782690951A priority patent/SU1042605A3/en
Priority to DE7878400202T priority patent/DE2860763D1/en
Priority to EP78400202A priority patent/EP0002630B2/en
Priority to US05/966,736 priority patent/US4209424A/en
Priority to CA317,511A priority patent/CA1106349A/en
Priority to ES475896A priority patent/ES475896A1/en
Priority to JP15278378A priority patent/JPS5488892A/en
Publication of FR2411030A1 publication Critical patent/FR2411030A1/en
Application granted granted Critical
Publication of FR2411030B1 publication Critical patent/FR2411030B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/02—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements
    • C07D295/023—Preparation; Separation; Stabilisation; Use of additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

A novel amination catalyst comprises an active transition metal uniformly distributed over a porous refractory support of specific surface 10-300 (esp. 30-50)m2/g and pore dia. 5000 angstroms. The metal content of the catalyst is 30-70 wt. %. The metal is pref. Ni, opt. in association with other metals such as Cu or Ni, the Ni content of the active material being >=50%. The catalyst is used for the prodn. of ethylene diamine (ED) and piperazine (PP) from ethanolamine (EA) and NH3. Other useful by-products may also be formed, e.g. diethylene triamine, aminoethyl piperazine, aminoethyl ethanolamine and hydroxyethyl piperazine. The catalyst has high mechanical strength which is retained over long periods of operation (>5000 hrs.). Activity of the catalyst remains constant for long periods (>6 months), and in particular the ED yield is not reduced. The selectivity to ED, PP or heavier amines can be controlled by varying the catalyst parameters.
FR7737346A 1977-12-12 1977-12-12 Catalyst comprising metal, esp. nickel, on porous support - used for amination of ethanolamine to piperazine and ethylene di:amine Granted FR2411030A1 (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
FR7737346A FR2411030A1 (en) 1977-12-12 1977-12-12 Catalyst comprising metal, esp. nickel, on porous support - used for amination of ethanolamine to piperazine and ethylene di:amine
SU782690951A SU1042605A3 (en) 1977-12-12 1978-11-30 Catalyst of amination of ethanol amine
EP78400202A EP0002630B2 (en) 1977-12-12 1978-12-01 Catalyst and process for the manufacture of amines from alcohols
DE7878400202T DE2860763D1 (en) 1977-12-12 1978-12-01 Catalyst and process for the manufacture of amines from alcohols
US05/966,736 US4209424A (en) 1977-12-12 1978-12-05 Catalyst for manufacturing amines from alcohols
CA317,511A CA1106349A (en) 1977-12-12 1978-12-06 Catalyst and process for the preparation of amines from alcohols
ES475896A ES475896A1 (en) 1977-12-12 1978-12-11 Catalyst and process for the manufacture of amines from alcohols.
JP15278378A JPS5488892A (en) 1977-12-12 1978-12-12 Aminating catalyst and its manufacture

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7737346A FR2411030A1 (en) 1977-12-12 1977-12-12 Catalyst comprising metal, esp. nickel, on porous support - used for amination of ethanolamine to piperazine and ethylene di:amine

Publications (2)

Publication Number Publication Date
FR2411030A1 true FR2411030A1 (en) 1979-07-06
FR2411030B1 FR2411030B1 (en) 1981-10-02

Family

ID=9198732

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7737346A Granted FR2411030A1 (en) 1977-12-12 1977-12-12 Catalyst comprising metal, esp. nickel, on porous support - used for amination of ethanolamine to piperazine and ethylene di:amine

Country Status (2)

Country Link
FR (1) FR2411030A1 (en)
SU (1) SU1042605A3 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0908235A2 (en) * 1997-09-19 1999-04-14 Intevep SA Bimatallic catalyst for the simultaneous selective hydrogenation of diolefins and nitriles, method of making same and process for the hydrogenation of diolefins and nitriles

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2630956C1 (en) * 2016-09-06 2017-09-15 Виталий Юрьевич Хатьков Oxide-nickel catalyst production method

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2310802A1 (en) * 1975-05-14 1976-12-10 Exxon Research Engineering Co CATALYTIC COMPOSITION WITH NICKEL AND ITS MANUFACTURING PROCESS
FR2325427A1 (en) * 1975-09-29 1977-04-22 British Gas Corp CATALYST FOR REFORMING HYDROCARBONS WITH WATER VAPOR, AND ITS APPLICATION TO THE PRODUCTION OF GAS CONTAINING METHANE
FR2337585A1 (en) * 1976-01-07 1977-08-05 Union Carbide Corp NEW NICKEL AND RHENIUM HYDROGENATION CATALYST, ITS PREPARATION AND APPLICATIONS

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2310802A1 (en) * 1975-05-14 1976-12-10 Exxon Research Engineering Co CATALYTIC COMPOSITION WITH NICKEL AND ITS MANUFACTURING PROCESS
FR2325427A1 (en) * 1975-09-29 1977-04-22 British Gas Corp CATALYST FOR REFORMING HYDROCARBONS WITH WATER VAPOR, AND ITS APPLICATION TO THE PRODUCTION OF GAS CONTAINING METHANE
FR2337585A1 (en) * 1976-01-07 1977-08-05 Union Carbide Corp NEW NICKEL AND RHENIUM HYDROGENATION CATALYST, ITS PREPARATION AND APPLICATIONS

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0908235A2 (en) * 1997-09-19 1999-04-14 Intevep SA Bimatallic catalyst for the simultaneous selective hydrogenation of diolefins and nitriles, method of making same and process for the hydrogenation of diolefins and nitriles
EP0908235A3 (en) * 1997-09-19 2000-03-01 Intevep SA Bimatallic catalyst for the simultaneous selective hydrogenation of diolefins and nitriles, method of making same and process for the hydrogenation of diolefins and nitriles
EP2196259A1 (en) * 1997-09-19 2010-06-16 Intevep SA Bimetallic catalyst for the simultaneous selective hydrogenation of diolefins and nitriles, method of making same and process for the hydrogenation of diolefins and nitriles

Also Published As

Publication number Publication date
FR2411030B1 (en) 1981-10-02
SU1042605A3 (en) 1983-09-15

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