FR2407237A1 - Vinyl! chloride polymers stabilised against yellowing - contain basic inorganic cpds. and di:ketone derivs. - Google Patents

Vinyl! chloride polymers stabilised against yellowing - contain basic inorganic cpds. and di:ketone derivs.

Info

Publication number
FR2407237A1
FR2407237A1 FR7830360A FR7830360A FR2407237A1 FR 2407237 A1 FR2407237 A1 FR 2407237A1 FR 7830360 A FR7830360 A FR 7830360A FR 7830360 A FR7830360 A FR 7830360A FR 2407237 A1 FR2407237 A1 FR 2407237A1
Authority
FR
France
Prior art keywords
pts
derivs
vinyl
additives
hydrocarbon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
FR7830360A
Other languages
French (fr)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Argus Chemical NV
Original Assignee
Argus Chemical NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Argus Chemical NV filed Critical Argus Chemical NV
Publication of FR2407237A1 publication Critical patent/FR2407237A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/10—Metal compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/07—Aldehydes; Ketones

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

An additive reducing the yellowing of vinyl chloride polymers, from which As, Cd, Pb, Hg and Th are excluded, to make them environmentally acceptable, consists of (A) >=1 basic inorg. cpd. of Li, Na, K, Mg, Ca, Sr, Ba, Zn, Ti, Al, Zr, or Sn, and (B) for each pt. wt. of (A) 0.01-1 pt. wt. of a diketone deriv. of formula M R-C(=O)-CR'-C(=O)R2 n, (where R is 1-18C hydrocarbon, opt. substd. by Hal, alkoxy or alkylenedioxy; R' is H or R3-C(=O)-; R3 is 1-18C hydrocarbon; R2 is H or R; M is hydrocarbon or Li, Na, K, Mg, Ca, Sr, Ba, Zn, Al or Sb; and n=1-3 and depends on the valency of M). The additives stabilise homopolymers of vinyl chloride and copolymers of vinyl chloride with propylene, ethylene 1-hexene, vinyl acetate, diethyl maleate and diethyl fumerate. They may be applied together with known stabiliser other than those contg. Pb or Ca, used at 0.1-10 pts. wt /100 pts. wt. polymer, including 1,2-epoxides, organotin derivs., organic phosphites, salts of phenols substd. with organic radicals and/or 6-30C monocarboxylic acid salts free from N. The additives are used at 0.02-20 pts. wt. /100 pts. wt. polymer. The additives do not lead to problems of environmental contamination.
FR7830360A 1977-10-26 1978-10-25 Vinyl! chloride polymers stabilised against yellowing - contain basic inorganic cpds. and di:ketone derivs. Withdrawn FR2407237A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP52128859A JPS585933B2 (en) 1977-10-26 1977-10-26 Stabilized halogen-containing resin composition

Publications (1)

Publication Number Publication Date
FR2407237A1 true FR2407237A1 (en) 1979-05-25

Family

ID=14995125

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7830360A Withdrawn FR2407237A1 (en) 1977-10-26 1978-10-25 Vinyl! chloride polymers stabilised against yellowing - contain basic inorganic cpds. and di:ketone derivs.

Country Status (3)

Country Link
JP (1) JPS585933B2 (en)
BE (1) BE870475A (en)
FR (1) FR2407237A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0040286A2 (en) * 1980-01-14 1981-11-25 Phoenix Chemical Corporation Polyvinyl halide resin compositions containing 1,3 Dicarbonyl compounds
WO2013093242A1 (en) * 2011-12-23 2013-06-27 Bluestar Silicones France Stabilized composition based on a chlorinated thermoplastic material

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5584341A (en) * 1978-12-21 1980-06-25 Sakai Chem Ind Co Ltd Chlorine-containing resin omposition
JPS55161839A (en) * 1979-06-05 1980-12-16 Katsuta Kako Kk Halogen-containing resin composition
DE3113442A1 (en) * 1981-04-03 1982-10-21 Henkel KGaA, 4000 Düsseldorf "STABILIZED POLYVINYL CHLORIDE MOLDS"

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2669548A (en) * 1951-01-02 1954-02-16 Monsanto Chemicals Stabilized halogen-containing resins
GB1141971A (en) * 1966-12-02 1969-02-05 Grace W R & Co Improvements relating to stabilizers
FR2297227A1 (en) * 1975-01-10 1976-08-06 Rhone Poulenc Ind Thermal stabiliser mixt. for (co) polyvinyl chloride - contg. divalent metal carboxylated and beta-di-ketone or beta-keto-aldehyde (BE090776)
DE2716389A1 (en) * 1976-08-02 1978-02-09 Sekisui Chemical Co Ltd CHLORINE RESIN

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5135493B2 (en) * 1973-08-14 1976-10-02
JPS512108A (en) * 1975-02-21 1976-01-09 Hitachi Ltd CHOTSUPASEIGYO DENKISHA
JPS5247043A (en) * 1975-10-13 1977-04-14 Sekisui Chem Co Ltd Chlorine-containing resin compositions

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2669548A (en) * 1951-01-02 1954-02-16 Monsanto Chemicals Stabilized halogen-containing resins
GB1141971A (en) * 1966-12-02 1969-02-05 Grace W R & Co Improvements relating to stabilizers
FR2297227A1 (en) * 1975-01-10 1976-08-06 Rhone Poulenc Ind Thermal stabiliser mixt. for (co) polyvinyl chloride - contg. divalent metal carboxylated and beta-di-ketone or beta-keto-aldehyde (BE090776)
DE2716389A1 (en) * 1976-08-02 1978-02-09 Sekisui Chemical Co Ltd CHLORINE RESIN
FR2392079A1 (en) * 1976-08-02 1978-12-22 Sekisui Chemical Co Ltd STABILIZED CHLORINATED RESINS

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0040286A2 (en) * 1980-01-14 1981-11-25 Phoenix Chemical Corporation Polyvinyl halide resin compositions containing 1,3 Dicarbonyl compounds
EP0040286A3 (en) * 1980-01-14 1982-02-17 Phoenix Chemical Corporation 1,3-dicarbonyl compounds and polyvinyl halide resin compositions containing the same
WO2013093242A1 (en) * 2011-12-23 2013-06-27 Bluestar Silicones France Stabilized composition based on a chlorinated thermoplastic material

Also Published As

Publication number Publication date
JPS5462250A (en) 1979-05-19
BE870475A (en) 1979-01-02
JPS585933B2 (en) 1983-02-02

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