FR2392948A1 - Procede de production d'acides et d'esters carboxyliques - Google Patents

Procede de production d'acides et d'esters carboxyliques

Info

Publication number
FR2392948A1
FR2392948A1 FR7800779A FR7800779A FR2392948A1 FR 2392948 A1 FR2392948 A1 FR 2392948A1 FR 7800779 A FR7800779 A FR 7800779A FR 7800779 A FR7800779 A FR 7800779A FR 2392948 A1 FR2392948 A1 FR 2392948A1
Authority
FR
France
Prior art keywords
rhodium
atoms
phosphorus
esters
arsenic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
FR7800779A
Other languages
English (en)
Inventor
Charles Michael Bartish
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Air Products and Chemicals Inc
Original Assignee
Air Products and Chemicals Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Air Products and Chemicals Inc filed Critical Air Products and Chemicals Inc
Publication of FR2392948A1 publication Critical patent/FR2392948A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1895—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing arsenic or antimony
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/37—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by reaction of ethers with carbon monoxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

La présente invention est relative à un nouveau procédé de production d'acides et d'esters carboxyliques. Ce procédé est caractérisé en ce que les réactions de carbonylation ont lieu en présence d'un catalyseur comprenant un composé de rhodium et un composant halogéné, ledit composé de rhodium étant un complexe formé entre un composant du rhodium étant un complexe formé entre un composant du rhodium et un coordinat contenant du phosphore ou de l'arsenic de formule (R1 R2 P 1 A P2 R3 R4 ), où R1 et R 3 sont des groupes alcényle comprenant de 1 à 6 atomes de carbone, des atomes d'hydrogène, des groupes aryle, et leurs dérivés substitués; R 2 et R4 sont des groupes aryle substitués ou non; P1 et P2 sont des atomes de phosphore ou d'arsenic; A est un groupe aryle, un groupe alcényle comportant de 2 à 4 atomes de carbone et leurs dérivés substitués ou un groupe (CH2 )n où n est compris entre 1 et 3, lorsque P1 et P2 sont des atomes de phosphore et entre 2 et 4 lorsque P1 ou P 2 sont des atomes d'arsenic.
FR7800779A 1977-01-13 1978-01-12 Procede de production d'acides et d'esters carboxyliques Withdrawn FR2392948A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/759,082 US4102920A (en) 1977-01-13 1977-01-13 Production of carboxylic acids and esters

Publications (1)

Publication Number Publication Date
FR2392948A1 true FR2392948A1 (fr) 1978-12-29

Family

ID=25054351

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7800779A Withdrawn FR2392948A1 (fr) 1977-01-13 1978-01-12 Procede de production d'acides et d'esters carboxyliques

Country Status (8)

Country Link
US (1) US4102920A (fr)
JP (1) JPS5390204A (fr)
BE (1) BE862828A (fr)
CA (1) CA1100525A (fr)
DE (1) DE2800986A1 (fr)
FR (1) FR2392948A1 (fr)
GB (1) GB1584740A (fr)
NL (1) NL7800264A (fr)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4284586A (en) * 1979-12-26 1981-08-18 Halcon Research And Development Corp. Process for the preparation of acetic anhydride
US4284585A (en) * 1979-12-26 1981-08-18 Halcon Research And Development Corp. Process for the preparation of acetic anhydride
JPS6033418B2 (ja) * 1980-09-16 1985-08-02 三菱瓦斯化学株式会社 酢酸ビニルの製造方法
US4325834A (en) * 1980-11-21 1982-04-20 Air Products And Chemicals, Inc. Heterogeneous catalyst supports
EP0058442B1 (fr) * 1981-02-09 1985-01-02 Shell Internationale Researchmaatschappij B.V. Procédé de coproduction d'un ester de l'acide dicarboxylique d'alcoylidène et d'un acide carboxylique
IT1139455B (it) * 1981-09-21 1986-09-24 Montedison Spa Processo per la preparazione di acidi alfa-arilpropionici e loro sali alcalini
IT1198351B (it) * 1981-09-21 1988-12-21 Montedison Spa Processo per la carbonilazione di alogenuri benzilici secondari
DE3144772A1 (de) * 1981-11-11 1983-05-19 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von essigsaeureanhydrid und essigsaeure
JPS6094933A (ja) * 1983-10-31 1985-05-28 Sagami Chem Res Center α−ペルフルオロアルキルアクリル酸の製造方法
CA1231966A (fr) * 1983-12-02 1988-01-26 David J. Schreck Production d'acides carboxyliques a partir d'alcool
CA1231965A (fr) * 1983-12-02 1988-01-26 David J. Schreck Production synergistique d'acides carboxyliques a partir d'alcool
CA1252480A (fr) * 1984-07-20 1989-04-11 Richard W. Wegman Obtention d'acides carboxyliques a partir d'esters formates en presence de catalyseurs a base de complexe de rhodium
CA1237728A (fr) * 1984-07-20 1988-06-07 Anthony G. Abatjoglou Preparation d'acides carboxyliques a partir d'alcools en presence de catalyseurs a base de complexe de rhodium
US5026907A (en) * 1984-08-16 1991-06-25 Union Carbide Chemicals And Plastics Technology Corporation Production of carboxylic acids from alcohols using rhodium complex catalysts and organic ester source
US4611082A (en) * 1984-11-09 1986-09-09 Monsanto Company Production of hex-3-enedioate esters from 1,4 dialkoxy butenes
US4698422A (en) * 1985-05-20 1987-10-06 Smithkline Beckman Corporation Triphos and tetraphos gold compounds and ligands
US4794165A (en) * 1987-02-23 1988-12-27 Shell Oil Company Carbon monoxide/olefin polymerization with bidentate ligand containing
DK158221C (da) * 1987-06-30 1990-09-10 Haldor Topsoe As Fremgangsmaade til fremstilling af eddikesyre, metylacetat, eddikesyreanhydrid eller blandinger deraf
US6031129A (en) * 1995-10-03 2000-02-29 Quantum Chemical Corporation Use of pentavalent group VA oxides in acetic acid processing
US5817869A (en) * 1995-10-03 1998-10-06 Quantum Chemical Corporation Use of pentavalent Group VA oxides in acetic acid processing
US6337418B1 (en) 1999-04-09 2002-01-08 Eastman Chemical Co. Preparation of C1-C5 alkyl esters of nitro or thioether substituted aromatic carboxylic acids
GB0311092D0 (en) * 2003-05-14 2003-06-18 Bp Chem Int Ltd Process
GB0311091D0 (en) * 2003-05-14 2003-06-18 Bp Chem Int Ltd Process

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2055060A5 (fr) * 1969-07-14 1971-05-07 Johnson Matthey Co Ltd

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3769329A (en) * 1970-03-12 1973-10-30 Monsanto Co Production of carboxylic acids and esters
US3946082A (en) * 1972-03-24 1976-03-23 Exxon Research & Engineering Co. Preparation of zerovalent phosphine substituted rhodium compounds and their use in the selective carbonylation of olefins

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2055060A5 (fr) * 1969-07-14 1971-05-07 Johnson Matthey Co Ltd

Also Published As

Publication number Publication date
GB1584740A (en) 1981-02-18
CA1100525A (fr) 1981-05-05
BE862828A (nl) 1978-05-02
JPS5390204A (en) 1978-08-08
US4102920A (en) 1978-07-25
DE2800986A1 (de) 1978-07-20
NL7800264A (nl) 1978-07-17

Similar Documents

Publication Publication Date Title
FR2392948A1 (fr) Procede de production d'acides et d'esters carboxyliques
FR2392037A1 (fr) Catalyseurs pour la polymerisation d'olefines
FR2372176A1 (fr) Procede de preparation de derives d'alcoxy-3 androstanones-17
KR850006171A (ko) 피롤리디논 유도체의 제조방법
NO162232C (no) Fremgangsmaate og katalysatorkompleks for fremstilling av organiske karboksylsyrer.
KR890000507A (ko) 시스플라틴(cisplatin) 유사체 및 그의 합성
KR860001780A (ko) 로듐 착화합물 촉매를 이용한 카복실산 무수물의 제조방법
FR2397389A1 (fr) Procede de preparation d'alcoylesters d'acides carboxyliques
ES454266A1 (es) Un procedimiento para la produccion de un derivado reactivo en el grupo carboxilo de la 2,3-dioxipiperazina.
AU587581B2 (en) Production of anhydrous carboxylic acids from alcohols using rhodium complex catalysts and organic ester source
FR2378805A1 (fr) Copolymere de chlorure de vinyle a plastification interne
KR850000390A (ko) 치환된 알칸티오카복실산 유도체의 제조방법
KR950700246A (ko) E형 프로스타글라딘류의 제조방법
BE1002696A3 (fr) Derives de dioxazocine, leur procede de preparation et compositions pharmaceutiques les contenant.
EP0352166A1 (fr) Procédé d'hydrocarbonylation de dérivés aromatiques halogènes
KR890011830A (ko) 2-옥시이미노 -3- 옥소부티르산의 제조방법
KR860700248A (ko) 로듐 착화합물 촉매를 사용하여 유기포르 메이트 에스테르로부터 카복실산을 제조하는 방법
GB997043A (en) Derivatives of 1,5-diarylpyrrole-2-propionic acid
FR2362813A1 (fr) Procede de preparation de desoxy-a-acides
JPS5585534A (en) Carbonylation of olefinic compound
AU584347B2 (en) Production of acetate esters from alcohols using rhodium complex catalyst
ES405171A1 (es) Procedimiento para la preparacion de cumarinas y sus deri- vados.
ES285014A1 (es) Procedimiento para la preparacion de 3-metilen-esteroides
TH3862A (th) การผลิตคาร์บอกซิลิแอนไฮไดรด์ จากเมธิลคาร์บอกซิเลตโดยใช้แคทาลิสท์ สารประกอบเชิงซ้อนโรเดียม
TH2973A (th) การผลิตคาร์บอกซิลิแอซิดที่ปราศจากน้ำจากแอลกอฮอล์ต่างๆการใช้แคทาลิสท์เชิงซ้อนโรเดียมและสารเป็นกำเนิดเอสเทอร์อินทรีย์

Legal Events

Date Code Title Description
ST Notification of lapse