FR2391978A1 - Light olefin cpds. prodn. from carbon mon:oxide and hydrogen - using organo-metallic iron, cobalt or nickel on inorganic support as catalyst - Google Patents
Light olefin cpds. prodn. from carbon mon:oxide and hydrogen - using organo-metallic iron, cobalt or nickel on inorganic support as catalystInfo
- Publication number
- FR2391978A1 FR2391978A1 FR7716450A FR7716450A FR2391978A1 FR 2391978 A1 FR2391978 A1 FR 2391978A1 FR 7716450 A FR7716450 A FR 7716450A FR 7716450 A FR7716450 A FR 7716450A FR 2391978 A1 FR2391978 A1 FR 2391978A1
- Authority
- FR
- France
- Prior art keywords
- catalyst
- prodn
- inorganic support
- cpds
- organo
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/0425—Catalysts; their physical properties
- C07C1/0445—Preparation; Activation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/20—Carbonyls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/06—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen in the presence of organic compounds, e.g. hydrocarbons
- C07C1/063—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen in the presence of organic compounds, e.g. hydrocarbons the organic compound being the catalyst or a part of the catalyst system
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/842—Iron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/845—Cobalt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/847—Nickel
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- C07C2521/08—Silica
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/10—Magnesium; Oxides or hydroxides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/12—Silica and alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/12—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of actinides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- C07C2531/20—Carbonyls
Abstract
Process is effected using catalyst produced by depositing an organometallic Fe, Co and/or Ni cluster on an inorganic support, (substd.) metal carbonyl clusters being pref. Used for the prodn. of 2-4C olefins. The selectivity is good and only traces of condensn. prods. with >=5C are formed. In an example, a catalyst was prepd. by impregnating Al2O3 with a reaction prod. of Fe(CO)5 and pyridine of the formula Fe(C5H5N)6 Fe4(CO)13 . In the reaction of H2 and CO at 10 bar and 360 degrees C, this gave a gas contg. 16 vol.% hydrocarbons, comprising 72.4 wt.% 1-4C paraffins and 27.5 wt.% 2-4C olefins. Little water and no liquid hydrocarbons were formed.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7716450A FR2391978A1 (en) | 1977-05-26 | 1977-05-26 | Light olefin cpds. prodn. from carbon mon:oxide and hydrogen - using organo-metallic iron, cobalt or nickel on inorganic support as catalyst |
DE19782822656 DE2822656A1 (en) | 1977-05-26 | 1978-05-24 | METHOD FOR PRODUCING LIGHT OLEFINIC HYDROCARBONS BY CONVERSING HYDROGEN WITH CARBON MONOXIDE IN THE PRESENCE OF A CATALYST |
ZA00783017A ZA783017B (en) | 1977-05-26 | 1978-05-25 | New catalyst process for the synthesis of light olefinic hydrocarbons by reaction of hydrogen with carbon monoxide |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7716450A FR2391978A1 (en) | 1977-05-26 | 1977-05-26 | Light olefin cpds. prodn. from carbon mon:oxide and hydrogen - using organo-metallic iron, cobalt or nickel on inorganic support as catalyst |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2391978A1 true FR2391978A1 (en) | 1978-12-22 |
FR2391978B1 FR2391978B1 (en) | 1980-05-16 |
Family
ID=9191411
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7716450A Granted FR2391978A1 (en) | 1977-05-26 | 1977-05-26 | Light olefin cpds. prodn. from carbon mon:oxide and hydrogen - using organo-metallic iron, cobalt or nickel on inorganic support as catalyst |
Country Status (3)
Country | Link |
---|---|
DE (1) | DE2822656A1 (en) |
FR (1) | FR2391978A1 (en) |
ZA (1) | ZA783017B (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2456718A1 (en) * | 1979-05-17 | 1980-12-12 | Vielstich Wolf | PROCESS FOR THE PREPARATION OF GASEOUS OLEFINS FROM CARBON MONOXIDE AND HYDROGEN, AND CATALYSTS FOR THIS PROCESS |
FR2471961A1 (en) * | 1979-12-18 | 1981-06-26 | Haldor Topsoe As | PROCESS AND CATALYST FOR THE PREPARATION OF A GASEOUS MIXTURE COMPRISING A HIGH CONTENT OF C2 HYDROCARBONS |
FR2564748A1 (en) * | 1984-05-24 | 1985-11-29 | Charbonnages Ste Chimique | Catalyst for hydrocondensation of carbon monoxide, process for its preparation and its application to the manufacture of hydrocarbons and aliphatic oxygen compounds |
EP0170534A1 (en) * | 1984-05-04 | 1986-02-05 | Elf Atochem S.A. | Process for the hydrocondensation of carbon monoxide |
WO2009013174A2 (en) * | 2007-07-20 | 2009-01-29 | Basf Se | Method for producing olefins through reaction of carbon monoxide with hydrogen |
WO2010028995A1 (en) * | 2008-09-10 | 2010-03-18 | Basf Se | Integrated method for producing carbonyl iron powder and hydrocarbons |
WO2014174372A3 (en) * | 2013-04-24 | 2015-03-26 | Saudi Basic Industries Corporation | Production of products from natural resources |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ZA814841B (en) * | 1980-07-23 | 1983-02-23 | British Petroleum Co | Process for the production of lower hydrocarbons and oxygenated derivatives thereof by the catalytic conversion of carbon monoxide and hydrogen |
EP2314557A1 (en) * | 2009-10-23 | 2011-04-27 | Netherlands Organisation for Scientific Research (Advanced Chemical Technologies for Sustainability) | Production of lower olefins from synthesis gas |
WO2011054738A1 (en) | 2009-11-06 | 2011-05-12 | Basf Se | Ferrous heterogeneous catalyst and method for producing olefins by converting carbon monoxide with hydrogen |
EP2496348B1 (en) | 2009-11-06 | 2016-01-06 | Basf Se | Heterogeneous catalyst containing iron and manganese and method for producing olefins by converting carbon monoxide with hydrogen |
CN102665899B (en) | 2009-11-06 | 2015-08-12 | 巴斯夫欧洲公司 | The heterogeneous catalyst of iron content and copper and the method by preparing alkene with hydrogen gas carbon monoxide |
-
1977
- 1977-05-26 FR FR7716450A patent/FR2391978A1/en active Granted
-
1978
- 1978-05-24 DE DE19782822656 patent/DE2822656A1/en not_active Withdrawn
- 1978-05-25 ZA ZA00783017A patent/ZA783017B/en unknown
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2456718A1 (en) * | 1979-05-17 | 1980-12-12 | Vielstich Wolf | PROCESS FOR THE PREPARATION OF GASEOUS OLEFINS FROM CARBON MONOXIDE AND HYDROGEN, AND CATALYSTS FOR THIS PROCESS |
FR2471961A1 (en) * | 1979-12-18 | 1981-06-26 | Haldor Topsoe As | PROCESS AND CATALYST FOR THE PREPARATION OF A GASEOUS MIXTURE COMPRISING A HIGH CONTENT OF C2 HYDROCARBONS |
EP0170534A1 (en) * | 1984-05-04 | 1986-02-05 | Elf Atochem S.A. | Process for the hydrocondensation of carbon monoxide |
FR2564748A1 (en) * | 1984-05-24 | 1985-11-29 | Charbonnages Ste Chimique | Catalyst for hydrocondensation of carbon monoxide, process for its preparation and its application to the manufacture of hydrocarbons and aliphatic oxygen compounds |
WO2009013174A2 (en) * | 2007-07-20 | 2009-01-29 | Basf Se | Method for producing olefins through reaction of carbon monoxide with hydrogen |
WO2009013174A3 (en) * | 2007-07-20 | 2009-09-24 | Basf Se | Method for producing olefins through reaction of carbon monoxide with hydrogen |
WO2010028995A1 (en) * | 2008-09-10 | 2010-03-18 | Basf Se | Integrated method for producing carbonyl iron powder and hydrocarbons |
US8608824B2 (en) | 2008-09-10 | 2013-12-17 | Basf Se | Integrated method for producing carbonyl iron powder and hydrocarbons |
WO2014174372A3 (en) * | 2013-04-24 | 2015-03-26 | Saudi Basic Industries Corporation | Production of products from natural resources |
US10112883B2 (en) | 2013-04-24 | 2018-10-30 | Saudi Basic Industries Corporation | Production of products from natural resources |
US10676419B2 (en) | 2013-04-24 | 2020-06-09 | Saudi Basic Industries Corporation | Production of products from natural resources |
Also Published As
Publication number | Publication date |
---|---|
DE2822656A1 (en) | 1978-12-07 |
ZA783017B (en) | 1979-06-27 |
FR2391978B1 (en) | 1980-05-16 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |