FR2376189A1 - IMPACT RESISTANT THERMOPLASTIC MOLDING MATERIALS - Google Patents

IMPACT RESISTANT THERMOPLASTIC MOLDING MATERIALS

Info

Publication number
FR2376189A1
FR2376189A1 FR7739274A FR7739274A FR2376189A1 FR 2376189 A1 FR2376189 A1 FR 2376189A1 FR 7739274 A FR7739274 A FR 7739274A FR 7739274 A FR7739274 A FR 7739274A FR 2376189 A1 FR2376189 A1 FR 2376189A1
Authority
FR
France
Prior art keywords
weight
component
molding materials
parts
thermoplastic molding
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
FR7739274A
Other languages
French (fr)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of FR2376189A1 publication Critical patent/FR2376189A1/en
Withdrawn legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/08Polyethers derived from hydroxy compounds or from their metallic derivatives
    • C08L71/10Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
    • C08L71/12Polyphenylene oxides
    • C08L71/123Polyphenylene oxides not modified by chemical after-treatment
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00Compositions of unspecified macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/08Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
    • C08L51/085Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds on to polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L59/00Compositions of polyacetals; Compositions of derivatives of polyacetals
    • C08L59/02Polyacetals containing polyoxymethylene sequences only
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/08Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/10Block- or graft-copolymers containing polysiloxane sequences

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Matières à mouler thermoplastiques d'une résistance élevée aux chocs, qui renferment : a. 100 parties en poids d'une madère thermoplastique partiellement cristallisée b. 1 à 50 parties en poids d'un copolymère greffé caoutchouteux, dont le caoutchouc de base greffé présente une température de transition vitreuse inférieure à -40 degrés C, ainsi que c. le cas échéant, jusqu'à 10 parties en poids, rapportées au composant a, de matières de renforcement et/ou de charges de produits d'addition courants. Ces matières à mouler renferment, comme composant b, un copolymère greffé qui a été obtenu par polymérisation : 1 de 10 à 50 % en poids, rapportés au composant b, de monomères ou de mélanges de monomères formant des polymères durs compatibles avec le composant a, en présence : de 90 à 50 % en poids, rapportés au composant b, d'un organopolysiloxane et/ou d'un caoutchouc de silicone éventuellement modifiés.High impact thermoplastic molding materials which contain: a. 100 parts by weight of a partially crystallized thermoplastic madeira b. 1 to 50 parts by weight of a rubbery graft copolymer, the graft base rubber of which has a glass transition temperature below -40 degrees C, as well as c. if appropriate, up to 10 parts by weight, based on component a, of common reinforcing materials and / or additive fillers. These molding materials contain, as component b, a graft copolymer which has been obtained by polymerization: 1 from 10 to 50% by weight, based on component b, of monomers or mixtures of monomers forming hard polymers compatible with component a , in the presence: from 90 to 50% by weight, based on component b, of an organopolysiloxane and / or of an optionally modified silicone rubber.

FR7739274A 1976-12-29 1977-12-27 IMPACT RESISTANT THERMOPLASTIC MOLDING MATERIALS Withdrawn FR2376189A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19762659357 DE2659357A1 (en) 1976-12-29 1976-12-29 IMPACT TOUGH THERMOPLASTIC MOLDING COMPOUNDS

Publications (1)

Publication Number Publication Date
FR2376189A1 true FR2376189A1 (en) 1978-07-28

Family

ID=5996926

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7739274A Withdrawn FR2376189A1 (en) 1976-12-29 1977-12-27 IMPACT RESISTANT THERMOPLASTIC MOLDING MATERIALS

Country Status (5)

Country Link
BE (1) BE862397A (en)
DE (1) DE2659357A1 (en)
FR (1) FR2376189A1 (en)
GB (1) GB1590549A (en)
NL (1) NL7714075A (en)

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0034773A2 (en) * 1980-02-15 1981-09-02 E.I. Du Pont De Nemours And Company Polyalkylene terephthalate molding composition
EP0067217A1 (en) * 1980-12-23 1982-12-22 General Electric Company Compositions of polyphenylene oxides with epdm-silicone rubber
EP0135794A2 (en) * 1983-08-31 1985-04-03 Bayer Ag Thermoplastic moulding materials of polysiloxane polycarbonate block copolymers
EP0156285A2 (en) * 1984-03-28 1985-10-02 Hoechst Aktiengesellschaft Impact resistant modified polyoxymethylene and molded articles there from
EP0231776A1 (en) * 1986-01-16 1987-08-12 Mitsubishi Rayon Co., Ltd. Thermoplastic polyester resin composition
EP0249964A2 (en) * 1986-06-17 1987-12-23 Mitsubishi Rayon Co., Ltd. Polycarbonate resin composition
EP0260559A2 (en) * 1986-09-17 1988-03-23 Bayer Ag Non-aging thermoplastic moulding compositions with an enhanced degree of toughness at a low temperature
EP0260558A2 (en) * 1986-09-17 1988-03-23 Bayer Ag Non-aging thermoplastic moulding composition with a good degree of toughness
EP0260552A2 (en) * 1986-09-11 1988-03-23 Mitsubishi Rayon Co., Ltd. Graft copolymer rubber and polyphenylene ether resin composition comprising this rubber.
EP0303078A2 (en) * 1987-08-01 1989-02-15 Bayer Ag Moulding compositions from aromatic polyester and grafted silicone rubber
EP0307963A2 (en) * 1987-09-21 1989-03-22 Mitsubishi Rayon Co., Ltd. Polycarbonate resin composition
EP0308871A2 (en) * 1987-09-21 1989-03-29 Mitsubishi Rayon Co., Ltd. Thermoplastic polyester resin composition
EP0315035A2 (en) * 1987-11-06 1989-05-10 Bayer Ag Mixture of polycarbonates with siloxan containing graft polymers
EP0340546A2 (en) * 1988-05-03 1989-11-08 Bayer Ag Molding masses of polyphenylene ether
EP0369376A2 (en) * 1988-11-14 1990-05-23 Mitsubishi Rayon Co., Ltd. Flame retardant polyphenylene ether resin composition
EP0386597A2 (en) * 1989-03-04 1990-09-12 Röhm Gmbh Plastics compositions
EP0413310A2 (en) * 1989-08-15 1991-02-20 Mitsubishi Rayon Co., Ltd Thermoplastic resin composition having improved impact resistance
US5212236A (en) * 1986-09-11 1993-05-18 Mitsubishi Rayon Co., Ltd. Polyphenylene ether resin composition

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4226761A (en) * 1978-11-27 1980-10-07 General Electric Company Polyphenylene ether resin compositions containing polysiloxane-modified alkenyl aromatic resins
US5047471A (en) * 1984-03-28 1991-09-10 Hoechst Aktiengesellschaft Toughened polyoxymethylene and shaped articles produced therefrom
JPS61106614A (en) * 1984-10-30 1986-05-24 Mitsubishi Rayon Co Ltd Production of impact-resistant resin
DE3805052A1 (en) * 1988-02-18 1989-08-31 Roehm Gmbh COMPATIBLE POLYMER BLENDS
DE3738109A1 (en) * 1987-11-10 1989-05-18 Bayer Ag MIXTURES OF POLYCARBONATES WITH SILOXANE-Grafted Polymers
JP2608439B2 (en) * 1988-01-25 1997-05-07 三菱レイヨン株式会社 Impact resistant resin composition
DE3813586A1 (en) * 1988-04-22 1989-11-02 Bayer Ag THERMOPLASTIC MOLDS FROM AROMATIC POLYETHERSULPHONES AND GRAFTED SILICONE RUBBER
DE3836900A1 (en) * 1988-10-29 1990-05-03 Bayer Ag MOLDS OF POLYESTER CARBONATE, POLYALKYLENE TEREPHTHALATE AND GRAFTED SILICONE RUBBER
US4939206A (en) * 1988-11-14 1990-07-03 General Electric Company Flame retardant polyorganosiloxane-based graft polymers
US5025066A (en) * 1988-11-14 1991-06-18 General Electric Company Polycarbonate and polyester blends modified with polyorganosiloxane graft polymers combined with diene rubber-based graft polymers
US5087662A (en) * 1988-11-14 1992-02-11 General Electric Company Polyester, polycarbonate and/or polyphenylene ether with polyorganosiloxane/polyvinyl-based graft (meth) acrylate polymers
US4939205A (en) * 1988-11-14 1990-07-03 General Electric Company Thermoplastic molding compositions containing polyorganosiloxane/polyvinyl-based graft polymer modifiers
US4968746A (en) * 1988-11-14 1990-11-06 General Electric Company Polyesters modified with polyorganosiloxane/polyvinyl-based graft polymers
US5047472A (en) * 1988-11-14 1991-09-10 General Electric Company Polyphenylene ether or polyphenylene ether/polystyrene with polyorganosiloxane/polyvinyl-based graft polymer modifiers
US4927880A (en) * 1988-11-14 1990-05-22 General Electric Company Low gloss molded articles using polyorganosiloxane/polyvinyl-based graft polymers
US5079293A (en) * 1988-11-14 1992-01-07 General Electric Company Thermoplastic compositions containing combined modifiers
US5045595A (en) * 1988-11-14 1991-09-03 General Electric Company Polyorganosiloxane/polyvinyl-based graft polymers, process and thermoplastic compositions containing the same
JPH0469540A (en) * 1990-07-09 1992-03-04 Mitsubishi Heavy Ind Ltd Measurement cylinder transonic wind tunnel
JP4270787B2 (en) 1999-10-29 2009-06-03 旭化成ケミカルズ株式会社 Polyoxymethylene resin composition
DE10054275A1 (en) * 2000-11-02 2002-05-08 Bayer Ag Impact-modified polycarbonate compositions
DE10237884A1 (en) 2002-08-19 2004-03-11 Ticona Gmbh Impact-resistant polyoxymethylene molding compositions, their use and molded articles made therefrom
US8008390B2 (en) 2005-09-16 2011-08-30 Ticona Gmbh Polyoxymethylene molding compositions, their use, and moldings produced therefrom
DE102008018967A1 (en) 2008-04-16 2009-10-22 Ticona Gmbh Oxymethylene polymers, process for their preparation and their use
US8840976B2 (en) 2010-10-14 2014-09-23 Ticona Llc VOC or compressed gas containment device made from a polyoxymethylene polymer
EP2505609B1 (en) 2011-04-01 2015-01-21 Ticona GmbH High impact resistant polyoxymethylene for extrusion blow molding
US8968858B2 (en) 2011-12-30 2015-03-03 Ticona Llc Printable molded articles made from a polyoxymethylene polymer composition
US9745467B2 (en) 2012-12-27 2017-08-29 Ticona, Llc Impact modified polyoxymethylene composition and articles made therefrom that are stable when exposed to ultraviolet light
JP6938267B2 (en) * 2017-08-03 2021-09-22 旭化成株式会社 Polyoxymethylene resin composition
JP6938266B2 (en) * 2017-08-03 2021-09-22 旭化成株式会社 Polyoxymethylene resin composition and molded article

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2005036A1 (en) * 1968-03-29 1969-12-05 Midland Silicones Ltd
GB1245250A (en) * 1967-09-25 1971-09-08 Hercules Inc Polyphase compositions and process for their preparation
DE2116836A1 (en) * 1970-04-06 1971-10-21 Gen Electric Mixtures of organosilicon block copolymers with organic polymers
DE2321904A1 (en) * 1972-05-01 1973-11-15 Dow Corning REINFORCED THERMOPLASTIC PLASTIC COMPOSITION AND METHOD OF MANUFACTURING IT

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1245250A (en) * 1967-09-25 1971-09-08 Hercules Inc Polyphase compositions and process for their preparation
FR2005036A1 (en) * 1968-03-29 1969-12-05 Midland Silicones Ltd
DE2116836A1 (en) * 1970-04-06 1971-10-21 Gen Electric Mixtures of organosilicon block copolymers with organic polymers
DE2321904A1 (en) * 1972-05-01 1973-11-15 Dow Corning REINFORCED THERMOPLASTIC PLASTIC COMPOSITION AND METHOD OF MANUFACTURING IT

Cited By (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0034773A3 (en) * 1980-02-15 1981-09-09 E.I. Du Pont De Nemours And Company Polyalkylene terephthalate molding composition
EP0034773A2 (en) * 1980-02-15 1981-09-02 E.I. Du Pont De Nemours And Company Polyalkylene terephthalate molding composition
EP0067217A1 (en) * 1980-12-23 1982-12-22 General Electric Company Compositions of polyphenylene oxides with epdm-silicone rubber
EP0067217A4 (en) * 1980-12-23 1983-05-16 Gen Electric Compositions of polyphenylene oxides with epdm-silicone rubber.
US4782115A (en) * 1983-08-31 1988-11-01 Bayer Aktiengesellschaft Thermoplastic moulding compositions based on polysiloxane/polycarbonate block copolymers
EP0135794A2 (en) * 1983-08-31 1985-04-03 Bayer Ag Thermoplastic moulding materials of polysiloxane polycarbonate block copolymers
EP0135794A3 (en) * 1983-08-31 1986-02-12 Bayer Ag Thermoplastic moulding materials of polysiloxane polycarbonate block copolymers
EP0156285A2 (en) * 1984-03-28 1985-10-02 Hoechst Aktiengesellschaft Impact resistant modified polyoxymethylene and molded articles there from
EP0156285A3 (en) * 1984-03-28 1987-05-06 Hoechst Aktiengesellschaft Impact resistant modified polyoxymethylene and molded articles there from
EP0231776A1 (en) * 1986-01-16 1987-08-12 Mitsubishi Rayon Co., Ltd. Thermoplastic polyester resin composition
US4775712A (en) * 1986-01-16 1988-10-04 Mitsubishi Rayon Co., Ltd. Thermoplastic polyester resin composition
EP0249964A3 (en) * 1986-06-17 1988-07-20 Mitsubishi Rayon Co., Ltd. Polycarbonate resin composition
EP0249964A2 (en) * 1986-06-17 1987-12-23 Mitsubishi Rayon Co., Ltd. Polycarbonate resin composition
US5268403A (en) * 1986-09-11 1993-12-07 Mitsubishi Rayon Co., Ltd. Polyphenylene ether resin composition
US5212236A (en) * 1986-09-11 1993-05-18 Mitsubishi Rayon Co., Ltd. Polyphenylene ether resin composition
EP0260552A2 (en) * 1986-09-11 1988-03-23 Mitsubishi Rayon Co., Ltd. Graft copolymer rubber and polyphenylene ether resin composition comprising this rubber.
EP0260552A3 (en) * 1986-09-11 1989-03-29 Mitsubishi Rayon Co. Ltd. Polyphenylene ether resin composition
US4894415A (en) * 1986-09-11 1990-01-16 Mitsubishi Rayon Co., Ltd. Polyphenylene ether resin composition
EP0260558A3 (en) * 1986-09-17 1990-07-18 Bayer Ag Non-aging thermoplastic moulding composition with a good degree of toughness
EP0260558A2 (en) * 1986-09-17 1988-03-23 Bayer Ag Non-aging thermoplastic moulding composition with a good degree of toughness
EP0260559A3 (en) * 1986-09-17 1990-07-18 Bayer Ag Non-aging thermoplastic moulding compositions with an enhanced degree of toughness at a low temperature
EP0260559A2 (en) * 1986-09-17 1988-03-23 Bayer Ag Non-aging thermoplastic moulding compositions with an enhanced degree of toughness at a low temperature
EP0303078A3 (en) * 1987-08-01 1990-01-31 Bayer Ag Moulding compositions from aromatic polyester and grafted silicone rubber
EP0303078A2 (en) * 1987-08-01 1989-02-15 Bayer Ag Moulding compositions from aromatic polyester and grafted silicone rubber
EP0307963A2 (en) * 1987-09-21 1989-03-22 Mitsubishi Rayon Co., Ltd. Polycarbonate resin composition
EP0308871A3 (en) * 1987-09-21 1990-02-07 Mitsubishi Rayon Co., Ltd. Thermoplastic polyester resin composition
EP0307963A3 (en) * 1987-09-21 1990-01-31 Mitsubishi Rayon Co., Ltd. Polycarbonate resin composition
EP0308871A2 (en) * 1987-09-21 1989-03-29 Mitsubishi Rayon Co., Ltd. Thermoplastic polyester resin composition
EP0315035A2 (en) * 1987-11-06 1989-05-10 Bayer Ag Mixture of polycarbonates with siloxan containing graft polymers
EP0315035A3 (en) * 1987-11-06 1990-10-31 Bayer Ag Mixture of polycarbonates with siloxan containing graft polymers
EP0340546A2 (en) * 1988-05-03 1989-11-08 Bayer Ag Molding masses of polyphenylene ether
EP0340546A3 (en) * 1988-05-03 1991-02-06 Bayer Ag Molding masses of polyphenylene ether
EP0369376A3 (en) * 1988-11-14 1991-12-04 Mitsubishi Rayon Co., Ltd. Flame retardant polyphenylene ether resin composition
EP0369376A2 (en) * 1988-11-14 1990-05-23 Mitsubishi Rayon Co., Ltd. Flame retardant polyphenylene ether resin composition
EP0386597A3 (en) * 1989-03-04 1991-07-31 Röhm Gmbh Plastics compositions
EP0386597A2 (en) * 1989-03-04 1990-09-12 Röhm Gmbh Plastics compositions
US5212237A (en) * 1989-03-04 1993-05-18 Roehm Gmbh Polymer mixtures
EP0413310A2 (en) * 1989-08-15 1991-02-20 Mitsubishi Rayon Co., Ltd Thermoplastic resin composition having improved impact resistance
EP0413310A3 (en) * 1989-08-15 1992-04-22 Mitsubishi Rayon Co., Ltd Thermoplastic resin composition having improved impact resistance

Also Published As

Publication number Publication date
GB1590549A (en) 1981-06-03
BE862397A (en) 1978-06-28
DE2659357A1 (en) 1978-07-13
NL7714075A (en) 1978-07-03

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