FR2371406A1 - Procede d'hydrogenolyse catalytique de l'anhydride maleique en 1,4-butanediol et tetrahydrofuranne - Google Patents

Procede d'hydrogenolyse catalytique de l'anhydride maleique en 1,4-butanediol et tetrahydrofuranne

Info

Publication number
FR2371406A1
FR2371406A1 FR7735139A FR7735139A FR2371406A1 FR 2371406 A1 FR2371406 A1 FR 2371406A1 FR 7735139 A FR7735139 A FR 7735139A FR 7735139 A FR7735139 A FR 7735139A FR 2371406 A1 FR2371406 A1 FR 2371406A1
Authority
FR
France
Prior art keywords
butanediol
tetrahydrofuran
maleic anhydride
catalytic hydrogenolysis
butyrolactone
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7735139A
Other languages
English (en)
Other versions
FR2371406B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
UCB SA
Original Assignee
UCB SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by UCB SA filed Critical UCB SA
Publication of FR2371406A1 publication Critical patent/FR2371406A1/fr
Application granted granted Critical
Publication of FR2371406B1 publication Critical patent/FR2371406B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D315/00—Heterocyclic compounds containing rings having one oxygen atom as the only ring hetero atom according to more than one of groups C07D303/00 - C07D313/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/883—Molybdenum and nickel
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
    • C07C29/177—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds with simultaneous reduction of a carboxy group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D307/06—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to ring carbon atoms
    • C07D307/08—Preparation of tetrahydrofuran

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Furan Compounds (AREA)
  • Catalysts (AREA)

Abstract

a. Chimie organique : 1,4-butanediol et tétrahydrofuranne. Procédé d'hydrogénolyse catalytique de l'anhydride maléique en 1,4-butanediol et tétrahydrofuranne en un seul stade operatoire avec de l'hydrogène à chaud et sous pression, en présence d'une suspension de catalyseur réduit solide qui contient comme élements catalytiquement actifs du nikel en association avec du molybdène et/ou du tungstène et éventuellement avec du zirconium et/ou du niobium, dans un milieu de réaction qui contient de la gamma-butyrolactone, pendant une durée telle que la quantité de gamma-butyrolactone dans le milieu de réaction final soit substantiellement égale à celle présente dans le milieu de réaction initial. c. Fabrication de 1,4-butanediol et de tétrahydrofuranne.
FR7735139A 1976-11-23 1977-11-21 Procede d'hydrogenolyse catalytique de l'anhydride maleique en 1,4-butanediol et tetrahydrofuranne Granted FR2371406A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB48795/76A GB1587198A (en) 1976-11-23 1976-11-23 Process for the production of butane-1,4 diol and tetrahydrofuran

Publications (2)

Publication Number Publication Date
FR2371406A1 true FR2371406A1 (fr) 1978-06-16
FR2371406B1 FR2371406B1 (fr) 1981-09-11

Family

ID=10449926

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7735139A Granted FR2371406A1 (fr) 1976-11-23 1977-11-21 Procede d'hydrogenolyse catalytique de l'anhydride maleique en 1,4-butanediol et tetrahydrofuranne

Country Status (7)

Country Link
US (1) US4155919A (fr)
JP (1) JPS5368710A (fr)
BE (1) BE861037A (fr)
DE (1) DE2752136A1 (fr)
FR (1) FR2371406A1 (fr)
GB (1) GB1587198A (fr)
NL (1) NL186856C (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2439176A1 (fr) * 1978-10-21 1980-05-16 Huels Chemische Werke Ag Procede de preparation continue de butane-diol-(1,4)
EP0699652A3 (fr) * 1994-09-02 1996-03-27 Bayer Ag

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4550185A (en) * 1983-12-22 1985-10-29 E. I. Du Pont De Nemours And Company Process for making tetrahydrofuran and 1,4-butanediol using Pd/Re hydrogenation catalyst
US4609636A (en) * 1983-12-22 1986-09-02 E. I. Du Pont De Nemours And Company Pd/Re hydrogenation catalyst for making tetrahydrofuran and 1,4-butanediol
GB8514002D0 (en) * 1985-06-04 1985-07-10 Davy Mckee Ltd Process
US4620016A (en) * 1985-05-16 1986-10-28 Phillips Petroleum Company Preparation of butyrolactone by catalytic hydrogenation of succinic anhydride
US4620017A (en) * 1985-05-16 1986-10-28 Phillips Petroleum Company Catalytic hydrogenation of succinic anhydride to butyrolactone
JPS63200806U (fr) * 1987-06-08 1988-12-23
JP2596604B2 (ja) * 1988-12-14 1997-04-02 東燃株式会社 １，４−ブタンジオールおよびテトラヒドロフランの製造方法
US4973713A (en) * 1989-11-28 1990-11-27 E. I. Du Pont De Nemours And Company Catalytic hydrogenation of carboxylic anhydrides to esters or lactones
DE4005293A1 (de) * 1990-02-20 1991-08-22 Basf Ag Verfahren zur herstellung von tetrahydrofuran und -butyrolacton
DE4009029A1 (de) * 1990-03-21 1991-09-26 Basf Ag Verfahren zur herstellung von 1,4-butandiol
US5808107A (en) * 1997-10-31 1998-09-15 Board Of Trustees Operating Michigan State University Process for the preparation of hydroxy substituted gamma butyrolactones
KR100835476B1 (ko) 2006-12-29 2008-06-09 주식회사 효성 1,4-부탄디올로부터 테트라하이드로퓨란의 제조방법
CA2846234A1 (fr) * 2011-08-22 2013-02-28 Suganit Systems, Inc. Production de bio-butanol et produits associes
GB201318175D0 (en) 2013-10-14 2013-11-27 Johnson Matthey Davy Technologies Ltd Process
WO2017001376A1 (fr) * 2015-06-30 2017-01-05 Shell Internationale Research Maatschappij B.V. Procédé de production de 1,4-butanediol et de tétrahydrofurane à partir de furane
WO2017064179A1 (fr) * 2015-10-15 2017-04-20 Shell Internationale Research Maatschappij B.V. Procédé de production de 1,4-butanediol et de tétrahydrofuranne à partir du furanne

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2000705A1 (fr) * 1968-01-25 1969-09-12 Mitsubishi Petrochemical Co
GB1200979A (en) * 1967-09-13 1970-08-05 Mitsubishi Petrochemical Co Process for catalytically hydrogenating dicarboxylic anhydrides
DE2455617A1 (de) * 1974-11-23 1976-05-26 Basf Ag Verfahren zur herstellung von butandiol und/oder tetrahydrofuran ueber die zwischenstufe des gamma-butyrolactons

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2772293A (en) * 1953-07-13 1956-11-27 Du Pont Process of hydrogenating maleic anhydride with a nickel or cobalt molybdite catalyst
US2772292A (en) * 1953-07-13 1956-11-27 Du Pont Hydrogenation of maleic anhydride
US2772291A (en) * 1953-08-31 1956-11-27 Du Pont Hydrogenation of maleic anhydride
US3492314A (en) * 1965-08-23 1970-01-27 Mitsubishi Petrochemical Co Process for catalytic hydrogenation of dicarboxylic acid anhydride and catalyst therefor
JPS5441560B2 (fr) * 1971-09-25 1979-12-08
US3872140A (en) * 1972-07-03 1975-03-18 Eastman Kodak Co Liquid crystalline compositions and method
JPS4932439A (fr) * 1972-07-25 1974-03-25
JPS4946978A (fr) * 1972-09-07 1974-05-07
DE2519817A1 (de) * 1975-05-03 1976-11-11 Hoechst Ag Verfahren zur herstellung von butandiol-(1.4)

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1200979A (en) * 1967-09-13 1970-08-05 Mitsubishi Petrochemical Co Process for catalytically hydrogenating dicarboxylic anhydrides
FR2000705A1 (fr) * 1968-01-25 1969-09-12 Mitsubishi Petrochemical Co
DE2455617A1 (de) * 1974-11-23 1976-05-26 Basf Ag Verfahren zur herstellung von butandiol und/oder tetrahydrofuran ueber die zwischenstufe des gamma-butyrolactons

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2439176A1 (fr) * 1978-10-21 1980-05-16 Huels Chemische Werke Ag Procede de preparation continue de butane-diol-(1,4)
EP0699652A3 (fr) * 1994-09-02 1996-03-27 Bayer Ag

Also Published As

Publication number Publication date
JPS5368710A (en) 1978-06-19
DE2752136A1 (de) 1978-05-24
GB1587198A (en) 1981-04-01
US4155919A (en) 1979-05-22
JPS6121208B2 (fr) 1986-05-26
FR2371406B1 (fr) 1981-09-11
BE861037A (fr) 1978-05-22
NL7712728A (nl) 1978-05-25
NL186856C (nl) 1991-03-18
DE2752136C2 (fr) 1988-01-14

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