FR2357512A1 - Preparation d'aldehydes non satures en a, b a partir d'olefines avec un rendement eleve et peu de sous-produits - Google Patents

Preparation d'aldehydes non satures en a, b a partir d'olefines avec un rendement eleve et peu de sous-produits

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Publication number
FR2357512A1
FR2357512A1 FR7720776A FR7720776A FR2357512A1 FR 2357512 A1 FR2357512 A1 FR 2357512A1 FR 7720776 A FR7720776 A FR 7720776A FR 7720776 A FR7720776 A FR 7720776A FR 2357512 A1 FR2357512 A1 FR 2357512A1
Authority
FR
France
Prior art keywords
olefin
product
aldehydes
olefins
unsaturated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7720776A
Other languages
English (en)
Other versions
FR2357512B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of FR2357512A1 publication Critical patent/FR2357512A1/fr
Application granted granted Critical
Publication of FR2357512B1 publication Critical patent/FR2357512B1/fr
Granted legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/847—Vanadium, niobium or tantalum or polonium
    • B01J23/8472—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8993—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/057—Selenium or tellurium; Compounds thereof
    • B01J27/0576—Tellurium; Compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

L'invention se rapporte à la chimie organique industrielle. Elle concerne un procédé d'oxydation catalytique en phase vapeur d'une oléfine en C3 -C5 en aldéhyde non saturé en alpha , beta avec peu d'acide non saturé en alpha , beta , par mise en contact de l'oléfine, d'oxygène, d'un gaz inerte modérateur et, éventuellement, d'eau en proportions adéquates, avec un catalyseur approprié à une température de 300-500 degrés C pendant un temps suffisant pour obtenir une conversion de 25 à 80 % de l'oléfine en aldéhyde; séparation de l'oléfine n'ayant pas réagi et du sous-produit gaz inerte du courant de produit; et recyclage de l'oléfine et du sous-produit. Utilisation par l'industrie chimique, en particulier pour la production d'acroléine.
FR7720776A 1976-07-07 1977-07-06 Preparation d'aldehydes non satures en a, b a partir d'olefines avec un rendement eleve et peu de sous-produits Granted FR2357512A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/703,285 US4335264A (en) 1976-07-07 1976-07-07 High yield, low byproduct α, β-unsaturated aldehydes from olefins

Publications (2)

Publication Number Publication Date
FR2357512A1 true FR2357512A1 (fr) 1978-02-03
FR2357512B1 FR2357512B1 (fr) 1982-09-10

Family

ID=24824779

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7720776A Granted FR2357512A1 (fr) 1976-07-07 1977-07-06 Preparation d'aldehydes non satures en a, b a partir d'olefines avec un rendement eleve et peu de sous-produits

Country Status (13)

Country Link
US (1) US4335264A (fr)
JP (1) JPS537609A (fr)
BE (1) BE856541A (fr)
BR (1) BR7704430A (fr)
CA (1) CA1091252A (fr)
CH (1) CH634542A5 (fr)
DE (1) DE2723899A1 (fr)
ES (1) ES460492A1 (fr)
FR (1) FR2357512A1 (fr)
GB (1) GB1576544A (fr)
IT (1) IT1080630B (fr)
NL (1) NL7707226A (fr)
PL (1) PL108169B1 (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0000564A1 (fr) * 1977-07-28 1979-02-07 The Standard Oil Company Catalyseurs contenant du fer et du molybdène et utilisation de ces catalyseurs pour la préparation d'acrylonitrile ou de méthacrylonitrile
FR2432007A1 (fr) * 1978-06-12 1980-02-22 Ube Industries Procede de preparation de methacroleine
EP0009239A1 (fr) * 1978-09-25 1980-04-02 BASF Aktiengesellschaft Procédé de préparation de benzaldéhydes p-substitués
FR2460910A1 (fr) * 1979-07-09 1981-01-30 Sumitomo Chemical Co Procede de production de methacroleine par oxydation catalytique d'isobutylene et/ou d'alcool t-butylique, et nouveau produit ainsi obtenu
EP0027351A1 (fr) * 1979-10-12 1981-04-22 Rohm And Haas Company Catalyseurs d'oxydation et procédé de préparation de la méthacroléine par oxydation en phase vapeur
FR2525212A1 (fr) * 1982-04-14 1983-10-21 Halcon Sd Group Inc Procede de transformation catalytique d'alcanes en aldehydes insatures

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS56113726A (en) * 1980-02-08 1981-09-07 Standard Oil Co Manufacture of aldehyde and carboxylic acid
US4479013A (en) * 1981-12-07 1984-10-23 The Halcon Sd Group, Inc. Catalyst and process for unsaturated aldehydes
JPS6123206A (ja) * 1984-07-11 1986-01-31 Fuji Electric Co Ltd 原動機の出力変化率制御装置
DE3733783A1 (de) * 1986-10-06 1988-04-14 Canon Kk Vibrations-antriebsvorrichtung
DE3930534A1 (de) * 1989-09-13 1991-03-21 Degussa Verfahren zur herstellung von acrolein durch katalytische gasphasenoxidation von propen
CA2261269A1 (fr) * 1996-04-01 1997-10-09 Barbara Knight Warren Procedes de production de methylmercaptopropanal
KR20010104053A (ko) * 2000-05-12 2001-11-24 성재갑 프로필렌의 기상 산화 반응에 의한 아크롤레인의 제조 방법
US11772080B2 (en) * 2019-04-15 2023-10-03 Asahi Kasei Kabushiki Kaisha Catalyst, method for producing catalyst, and method for producing acrylonitrile
WO2023115291A1 (fr) * 2021-12-21 2023-06-29 Rhodia Operations PROCÉDÉ DE PRODUCTION DE COMPOSÉS D'ALDÉHYDE α,β-INSATURÉS

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3883588A (en) * 1971-03-16 1975-05-13 Rohm & Haas Method of preparing acrylic acid
FR2280623A1 (fr) * 1974-07-31 1976-02-27 Basf Ag Procede de preparation d'acide acrylique par oxydation de propylene a l'aide de gaz contenant de l'oxygene en deux etapes catalytiques separees
US3951861A (en) * 1971-06-14 1976-04-20 Sumitomo Chemical Company, Limited Catalysts for the preparation of acrolein

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3524823A (en) * 1965-08-30 1970-08-18 Goodrich Co B F Catalyst and method of preparing unsaturated acids and aldehydes
DE1667130C3 (de) * 1967-07-05 1974-01-31 Knapsack Ag, 5033 Huerth Katalysator für die katalytische Gasphasenoxidation von Propylen oder Acrolein zu Acrylsäure
US3716496A (en) * 1969-09-06 1973-02-13 Nitto Chemical Industry Co Ltd Catalyst composition for the oxidation and the oxidative dehydrogenation of olefins
US3804903A (en) * 1970-07-31 1974-04-16 Japanese Gun Co Ltd Process for production of methacrolein
US3799978A (en) * 1971-12-23 1974-03-26 Nippon Catalytic Chem Ind Process for the preparation of unsaturated carbonyl compounds
JPS5112603B1 (fr) * 1971-05-26 1976-04-21
US4001317A (en) * 1974-07-22 1977-01-04 Standard Oil Company Process for the oxidation of olefins using catalysts containing various promoter elements
GB1490683A (en) * 1975-03-12 1977-11-02 Mitsubishi Rayon Co Process and a catalyst for producing unsaturated aldehydes unsaturated carboxylic acids or conjugated diene

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3883588A (en) * 1971-03-16 1975-05-13 Rohm & Haas Method of preparing acrylic acid
US3951861A (en) * 1971-06-14 1976-04-20 Sumitomo Chemical Company, Limited Catalysts for the preparation of acrolein
FR2280623A1 (fr) * 1974-07-31 1976-02-27 Basf Ag Procede de preparation d'acide acrylique par oxydation de propylene a l'aide de gaz contenant de l'oxygene en deux etapes catalytiques separees

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0000564A1 (fr) * 1977-07-28 1979-02-07 The Standard Oil Company Catalyseurs contenant du fer et du molybdène et utilisation de ces catalyseurs pour la préparation d'acrylonitrile ou de méthacrylonitrile
FR2432007A1 (fr) * 1978-06-12 1980-02-22 Ube Industries Procede de preparation de methacroleine
EP0009239A1 (fr) * 1978-09-25 1980-04-02 BASF Aktiengesellschaft Procédé de préparation de benzaldéhydes p-substitués
FR2460910A1 (fr) * 1979-07-09 1981-01-30 Sumitomo Chemical Co Procede de production de methacroleine par oxydation catalytique d'isobutylene et/ou d'alcool t-butylique, et nouveau produit ainsi obtenu
EP0027351A1 (fr) * 1979-10-12 1981-04-22 Rohm And Haas Company Catalyseurs d'oxydation et procédé de préparation de la méthacroléine par oxydation en phase vapeur
FR2525212A1 (fr) * 1982-04-14 1983-10-21 Halcon Sd Group Inc Procede de transformation catalytique d'alcanes en aldehydes insatures

Also Published As

Publication number Publication date
CA1091252A (fr) 1980-12-09
GB1576544A (en) 1980-10-08
PL108169B1 (pl) 1980-03-31
JPS537609A (en) 1978-01-24
FR2357512B1 (fr) 1982-09-10
ES460492A1 (es) 1978-06-16
DE2723899A1 (de) 1978-01-12
PL199366A1 (pl) 1978-04-10
BR7704430A (pt) 1978-05-02
CH634542A5 (de) 1983-02-15
IT1080630B (it) 1985-05-16
NL7707226A (nl) 1978-01-10
US4335264A (en) 1982-06-15
BE856541A (fr) 1978-01-06

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