FR2342786A1 - Catalyseurs constitues d'un polymere perfluore supporte et leur utilisation dans des procedes de transformation d'hydrocarbures - Google Patents

Catalyseurs constitues d'un polymere perfluore supporte et leur utilisation dans des procedes de transformation d'hydrocarbures

Info

Publication number
FR2342786A1
FR2342786A1 FR7706091A FR7706091A FR2342786A1 FR 2342786 A1 FR2342786 A1 FR 2342786A1 FR 7706091 A FR7706091 A FR 7706091A FR 7706091 A FR7706091 A FR 7706091A FR 2342786 A1 FR2342786 A1 FR 2342786A1
Authority
FR
France
Prior art keywords
perfluorine
polymer
supported
transformation processes
catalysts consisting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7706091A
Other languages
English (en)
Other versions
FR2342786B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of FR2342786A1 publication Critical patent/FR2342786A1/fr
Application granted granted Critical
Publication of FR2342786B1 publication Critical patent/FR2342786B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/123—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of only one hydrocarbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B01J31/08—Ion-exchange resins
    • B01J31/10—Ion-exchange resins sulfonated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/56—Addition to acyclic hydrocarbons
    • C07C2/58—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2767—Changing the number of side-chains
    • C07C5/277—Catalytic processes
    • C07C5/2794—Catalytic processes with hydrides or organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/52—Isomerisation reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/12—Silica and alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • C07C2531/08—Ion-exchange resins
    • C07C2531/10—Ion-exchange resins sulfonated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
FR7706091A 1976-03-04 1977-03-02 Catalyseurs constitues d'un polymere perfluore supporte et leur utilisation dans des procedes de transformation d'hydrocarbures Granted FR2342786A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/663,956 US4038213A (en) 1976-03-04 1976-03-04 Hydrocarbon conversion process using a supported perfluorinated polymer catalyst

Publications (2)

Publication Number Publication Date
FR2342786A1 true FR2342786A1 (fr) 1977-09-30
FR2342786B1 FR2342786B1 (fr) 1978-10-20

Family

ID=24663902

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7706091A Granted FR2342786A1 (fr) 1976-03-04 1977-03-02 Catalyseurs constitues d'un polymere perfluore supporte et leur utilisation dans des procedes de transformation d'hydrocarbures

Country Status (6)

Country Link
US (2) US4038213A (fr)
JP (1) JPS6025190B2 (fr)
DE (1) DE2709057A1 (fr)
FR (1) FR2342786A1 (fr)
GB (1) GB1564272A (fr)
NL (1) NL7702211A (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2481694A1 (fr) * 1980-05-02 1981-11-06 Toyo Soda Mfg Co Ltd Procede de production du methyl t-butyl ether a partir d'isobutylene et de methanol

Families Citing this family (53)

* Cited by examiner, † Cited by third party
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US4303551A (en) * 1976-02-23 1981-12-01 Varen Technology Supported catalyst
US4322560A (en) * 1976-02-23 1982-03-30 Varen Technology Process for controlling highly exothermic hydroperoxide decomposition
US4038213A (en) * 1976-03-04 1977-07-26 Shell Oil Company Hydrocarbon conversion process using a supported perfluorinated polymer catalyst
US4222952A (en) * 1979-06-25 1980-09-16 Union Carbide Corporation Siloxane bond rearrangement effected by solid perfluorinated polymers containing pendant sulfonic acid groups
US4348310A (en) * 1979-09-26 1982-09-07 E. I. Du Pont De Nemours And Company Solutions of sulfonyl fluoride compounds and fluoropolymers
US4446269A (en) * 1980-08-08 1984-05-01 E. I. Du Pont De Nemours And Company Solvents of carboxyl ester compounds and fluoropolymers
US4414280A (en) * 1980-08-08 1983-11-08 E. I. Du Pont De Nemours And Company Membranes and composites from fluoropolymer solutions
US4416801A (en) * 1980-12-15 1983-11-22 E. I. Du Pont De Nemours & Co. Toluic acid
US4367352A (en) * 1980-12-22 1983-01-04 Texaco Inc. Oligomerized olefins for lubricant stock
US4304724A (en) * 1980-12-22 1981-12-08 The Dow Chemical Company Process for the manufacture of anthraquinone
JPS57167737A (en) * 1981-04-10 1982-10-15 Asahi Chem Ind Co Ltd Novel fluorinated polymer acid catalyst and its production
US4433082A (en) * 1981-05-01 1984-02-21 E. I. Du Pont De Nemours And Company Process for making liquid composition of perfluorinated ion exchange polymer, and product thereof
US4453991A (en) * 1981-05-01 1984-06-12 E. I. Du Pont De Nemours And Company Process for making articles coated with a liquid composition of perfluorinated ion exchange resin
FR2505850B1 (fr) * 1981-05-12 1985-06-21 Rhone Poulenc Spec Chim Procede d'obtention de polysiloxanes de masses moleculaires elevees par polymerisation et rearrangement de polysiloxanes en presence de catalyseur constitue par un support mineral poreux recouvert d'un film polymerique porteur de groupement sulfonique ou phosphonique
US4463103A (en) * 1981-12-09 1984-07-31 E. I. Du Pont De Nemours And Company Toluic acid
US4414146A (en) * 1982-05-05 1983-11-08 Union Camp Corporation Method of polymerizing rosin
US4446329A (en) * 1983-03-24 1984-05-01 E. I. Du Pont De Nemours & Company Alkylation or aromatic compounds
US4585750A (en) * 1983-12-21 1986-04-29 Exxon Research And Engineering Co. Composite catalyst for hydrocarbon conversion reactions
US4683216A (en) * 1985-02-27 1987-07-28 Exxon Research And Engineering Company Process for activating a composite catalyst useful for hydrocarbon conversion reactions
US4673769A (en) * 1985-02-27 1987-06-16 Exxon Research And Engineering Company Composite catalyst for hydrocarbon conversion reactions
GB8517188D0 (en) * 1985-07-06 1985-08-14 Bp Chem Int Ltd Metal perfluorosulphonic acid polymer catalyst
US4791081A (en) * 1986-02-25 1988-12-13 The Dow Chemical Company Supported fluorocarbonsulfonic acid polymers and an improved method for their preparation
EP0235998A3 (fr) * 1986-02-25 1988-06-08 The Dow Chemical Company Polymères supportés d'acide fluorocarbosulfonique et procédés pour leur préparation
EP0503688A3 (fr) * 1986-02-25 1992-09-23 The Dow Chemical Company Méthode de préparation de polymères sur support munis d'acide fluorocarbosulfonique
US4783546A (en) * 1987-06-02 1988-11-08 E. I. Du Pont De Nemours And Company Preparation of 4-pentenenitrile by isomerization
US4950832A (en) * 1987-07-29 1990-08-21 Nikki Chemical Co., Ltd. Method for preparation of dialkylnaphthalenes and catalyst for the same
US4800186A (en) * 1987-10-28 1989-01-24 The Dow Chemical Company Regeneration of fluorocarbonsulfonic acid catalysts
US5034161A (en) * 1988-07-18 1991-07-23 Petrolite Corporation Synthesis of aryl-substituted aliphatic acids
US4990716A (en) * 1989-06-09 1991-02-05 The Dow Chemical Company Preparation of diphenylmethanes
US5233102A (en) * 1989-08-02 1993-08-03 E. I. Du Pont De Nemours And Company Olefin hydration
US5105047A (en) * 1989-08-02 1992-04-14 E. I. Du Pont De Nemours And Company Catalysis using blends of perfluorinated ion-exchange polymers with perfluorinated diluents
US5094995A (en) * 1989-08-02 1992-03-10 E. I. Du Pont De Nemours And Company Supported perfluorinated ion-exchange polymers
US5124299A (en) * 1989-08-02 1992-06-23 E. I. Du Pont De Nemours And Company Catalysis using blends of perfluorinated ion-exchange polymers with perfluorinated diluents
US5097087A (en) * 1990-10-15 1992-03-17 Texaco Chemical Company Dimerization of long-chain olefins using a fluorocarbonsulfonic acid polymer on an inert support
US5166114A (en) * 1992-01-14 1992-11-24 Phillips Petroleum Company Ethylene dimerization and catalyst therefor
US5260499A (en) * 1992-01-14 1993-11-09 Phillips Petroleum Company Ethylene dimerization and catalyst therefor
US5276239A (en) * 1992-07-27 1994-01-04 Texaco Chemical Company Dimerization of long-chain olefins using a silica gel alkylsulfonic acid
JP4135970B2 (ja) * 1994-01-12 2008-08-20 イー・アイ・デユポン・ドウ・ヌムール・アンド・カンパニー イオン交換用完全フッ素置換ポリマーと金属酸化物からゾル−ゲルで生成させた多孔質ミクロ複合体
US5916837A (en) * 1994-01-12 1999-06-29 E.I. Du Pont De Nemours And Company Porous microcomposite of metal cation exchanged perfluorinated ion-exchanged polymer and network of metal oxide, silica or metal oxide and silica
US5824622A (en) * 1994-01-12 1998-10-20 E. I. Du Pont De Nemours And Company Porous microcomposite of perfluorinated ion-exchange polymer and metal oxide, a network of silica, or a network of metal oxide and silica derived via a sol-gel process
US5746954A (en) * 1995-09-07 1998-05-05 The Dow Chemical Company Processes for forming thin, durable coatings of perfluorocarbon ionomers on various substrate materials
US6107233A (en) * 1997-03-24 2000-08-22 E. I. Du Pont De Nemours And Company Process for the preparation of spherically shaped microcomposites
US6262326B1 (en) 2000-06-06 2001-07-17 E. I. Du Pont De Nemours And Company Process for the preparation of spherically shaped microcomposites
DE69706038T2 (de) * 1996-03-28 2002-04-11 E.I. Du Pont De Nemours And Co., Wilmington Verfahren zur herstellung von kugelförmigem mikroverbundmaterial
US6248930B1 (en) 1997-03-07 2001-06-19 E. I. Du Pont De Nemours And Company Fluorine-modified perfluorinated ion-exchange microcomposite catalysts
US6169053B1 (en) 1997-03-26 2001-01-02 E. I. Du Pont De Nemours And Company Silylated perfluorinated ion-exchange microcomposite catalysts
US5932511A (en) * 1997-05-28 1999-08-03 E. I. Du Pont De Nemours And Company Perfluorinated ion-exchange microcomposite catalysts modified with Lewis acid
EP1011861B1 (fr) 1997-07-29 2001-10-24 E.I. Dupont De Nemours And Company Preparation d'un microcomposite catalytique a partir d'un silicate et d'une resine echangeuse d'ions hautement fluoree
US7354679B2 (en) 2002-05-13 2008-04-08 Polyfuel, Inc. Ion conductive random copolymers
CN100509875C (zh) 2002-05-13 2009-07-08 复合燃料公司 磺化共聚物
WO2004042839A2 (fr) 2002-05-13 2004-05-21 Polyfuel, Inc. Copolymeres blocs conducteurs d'ions
CN101961660B (zh) * 2010-10-08 2013-03-13 同济大学 多孔杂化树脂固体酸催化剂及其制备方法
CN103599815B (zh) * 2013-11-16 2015-08-26 南京林业大学 活性炭固载全氟磺酸树脂催化剂及其用于催化合成(甲基)丙烯酸烷氧基乙酯

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2956097A (en) * 1959-03-25 1960-10-11 Exxon Research Engineering Co Promoter for isomerization reaction
US3282875A (en) * 1964-07-22 1966-11-01 Du Pont Fluorocarbon vinyl ether polymers
FR2244563B1 (fr) * 1973-09-26 1976-06-18 Erap
US3882093A (en) * 1974-01-02 1975-05-06 Du Pont Sulfonyl-containing fluorocarbon vinyl ethers and ion exchange membrane formed therefrom
US4022847A (en) * 1976-03-04 1977-05-10 Shell Oil Company Hydrocarbon conversion process using an unsupported perfluorinated polymer catalyst
US4038213A (en) * 1976-03-04 1977-07-26 Shell Oil Company Hydrocarbon conversion process using a supported perfluorinated polymer catalyst

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2481694A1 (fr) * 1980-05-02 1981-11-06 Toyo Soda Mfg Co Ltd Procede de production du methyl t-butyl ether a partir d'isobutylene et de methanol

Also Published As

Publication number Publication date
DE2709057A1 (de) 1977-09-08
US4065515A (en) 1977-12-27
JPS6025190B2 (ja) 1985-06-17
NL7702211A (nl) 1977-09-06
FR2342786B1 (fr) 1978-10-20
GB1564272A (en) 1980-04-02
US4038213A (en) 1977-07-26
JPS52106391A (en) 1977-09-06

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Legal Events

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ST Notification of lapse