FR2332803A1 - Procede de production de catalyseurs d'(amm)oxydation a base de molybdene et de bismuth et nouveaux produits ainsi obtenus - Google Patents

Procede de production de catalyseurs d'(amm)oxydation a base de molybdene et de bismuth et nouveaux produits ainsi obtenus

Info

Publication number
FR2332803A1
FR2332803A1 FR7635834A FR7635834A FR2332803A1 FR 2332803 A1 FR2332803 A1 FR 2332803A1 FR 7635834 A FR7635834 A FR 7635834A FR 7635834 A FR7635834 A FR 7635834A FR 2332803 A1 FR2332803 A1 FR 2332803A1
Authority
FR
France
Prior art keywords
molybdene
catalyzers
bismuth
production
new products
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7635834A
Other languages
English (en)
Other versions
FR2332803B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Co
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of FR2332803A1 publication Critical patent/FR2332803A1/fr
Application granted granted Critical
Publication of FR2332803B1 publication Critical patent/FR2332803B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
    • C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
    • B01J27/192—Molybdenum with bismuth
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
FR7635834A 1975-11-28 1976-11-26 Procede de production de catalyseurs d'(amm)oxydation a base de molybdene et de bismuth et nouveaux produits ainsi obtenus Granted FR2332803A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/636,011 US4040978A (en) 1975-11-28 1975-11-28 Production of (amm)oxidation catalyst

Publications (2)

Publication Number Publication Date
FR2332803A1 true FR2332803A1 (fr) 1977-06-24
FR2332803B1 FR2332803B1 (fr) 1982-01-15

Family

ID=24550038

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7635834A Granted FR2332803A1 (fr) 1975-11-28 1976-11-26 Procede de production de catalyseurs d'(amm)oxydation a base de molybdene et de bismuth et nouveaux produits ainsi obtenus

Country Status (14)

Country Link
US (1) US4040978A (fr)
JP (1) JPS6029536B2 (fr)
AU (1) AU502608B2 (fr)
BE (1) BE848793A (fr)
BR (1) BR7607932A (fr)
CA (1) CA1082165A (fr)
DE (1) DE2653863A1 (fr)
DK (1) DK535276A (fr)
ES (1) ES453604A1 (fr)
FR (1) FR2332803A1 (fr)
GB (1) GB1564545A (fr)
IL (1) IL50998A (fr)
IT (1) IT1107704B (fr)
NL (1) NL7613086A (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2436135A1 (fr) * 1978-09-13 1980-04-11 Ube Industries Procede pour la preparation catalytique de l'acrylonitrile
FR2441423A1 (fr) * 1978-11-13 1980-06-13 Celanese Corp Procede de preparation d'un catalyseur pour l'oxydation des olefines, catalyseur ainsi obtenu et procede d'oxydation des olefines en l'utilisant
FR2502977A1 (fr) * 1981-04-06 1982-10-08 Euteco Impianti Spa Catalyseur pour la conversion d'hydrocarbures insatures en diolefines ou/et en aldehydes et nitriles insatures, et procede pour la preparation de ce catalyseur
FR2670685A1 (fr) * 1990-12-20 1992-06-26 Rhone Poulenc Chimie Procede de preparation de catalyseurs enrobes a base de molybdates de bismuth et de fer dopes par du phosphore et du potassium.

Families Citing this family (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4168246A (en) * 1975-11-28 1979-09-18 Monsanto Company Production of (amm)oxidation catalyst
US4148757A (en) * 1977-08-10 1979-04-10 The Standard Oil Company Process for forming multi-component oxide complex catalysts
US4212766A (en) * 1978-04-21 1980-07-15 Standard Oil Company Process for forming multi-component oxide complex catalysts
DE2849715A1 (de) * 1978-11-16 1980-05-29 Hoechst Ag Traegerkatalysator und verfahren zu seiner herstellung
US4405498A (en) * 1979-12-17 1983-09-20 Monsanto Company Oxidation and ammoxidation catalysts
DE3260617D1 (en) * 1981-02-17 1984-10-04 Standard Oil Co Ohio Preparation of composite oxidation catalyst and use thereof for the production of unsaturated aldehydes and acids from propylene and isobutylene
US4415482A (en) * 1981-11-12 1983-11-15 Monsanto Company Oxidation and ammoxidation catalyst
JPH01131336U (fr) * 1988-03-01 1989-09-06
JP2520279B2 (ja) * 1988-03-03 1996-07-31 日東化学工業株式会社 アクリロニトリルの製造方法
JP2520282B2 (ja) * 1988-04-15 1996-07-31 日東化学工業株式会社 アクリロニトリルの製造方法
FR2670686B1 (fr) * 1990-12-20 1994-08-12 Rhone Poulenc Chimie Composition catalytique pour la preparation d'aldehydes alpha,beta-insatures par oxydation d'olefines en phase gazeuse et procede d'oxydation.
DE19517106C2 (de) * 1995-05-10 1997-11-06 Doerfert Hans Joachim Sicherheitssystem für mit gefährlichen Stoffen kontaminierte Luft für einen Arbeitsraum einer Abzugwerkbank
US5840648A (en) * 1997-09-02 1998-11-24 The Standard Oil Company Catalyst for the manufacture of acrylonitrile and hydrogen cyanide
US6017846A (en) * 1999-01-11 2000-01-25 Saudi Basic Industries Corporation Highly active and selective catalysts for the production of unsaturated nitriles, methods of making and using the same
US6037304A (en) * 1999-01-11 2000-03-14 Saudi Basic Industries Corporation Highly active and selective catalysts for the production of unsaturated nitriles, methods of making and using the same
US6486091B1 (en) 2000-03-14 2002-11-26 Saudi Basic Industries Corporation Process for making highly active and selective catalysts for the production of unsaturated nitriles
US7851397B2 (en) 2005-07-25 2010-12-14 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
US7732367B2 (en) 2005-07-25 2010-06-08 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
US7649112B2 (en) 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Integrated plant for producing 2-ethyl-hexanol and methacrylic acid and a method based thereon
US7649111B2 (en) 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Catalyst for the oxidation of a mixed aldehyde feedstock to methacrylic acid and methods for making and using same
KR101086731B1 (ko) * 2008-10-17 2011-11-25 금호석유화학 주식회사 1-부텐의 산화/탈수소화 반응에서 1,3-부타디엔 제조용 비스무스 몰리브덴 철 복합 산화물 촉매 및 제조방법
US8153546B2 (en) 2010-03-23 2012-04-10 Ineos Usa Llc Mixed metal oxide ammoxidation catalysts
MX2012010925A (es) 2010-03-23 2012-12-17 Ineos Usa Llc Proceso de amoxidacion de alta eficiencia y catalizadores de oxido de metal mezclados.
US8455388B2 (en) 2010-03-23 2013-06-04 Ineos Usa Llc Attrition resistant mixed metal oxide ammoxidation catalysts
US8258073B2 (en) * 2010-03-23 2012-09-04 Ineos Usa Llc Process for preparing improved mixed metal oxide ammoxidation catalysts
US8420566B2 (en) * 2010-03-23 2013-04-16 Ineos Usa Llc High efficiency ammoxidation process and mixed metal oxide catalysts
US9433929B2 (en) 2011-09-21 2016-09-06 Ineos Europe Ag Mixed metal oxide catalysts
US8921257B2 (en) 2011-12-02 2014-12-30 Saudi Basic Industries Corporation Dual function partial oxidation catalyst for propane to acrylic acid conversion
DE102012010542A1 (de) 2011-12-20 2013-06-20 CCP Technology GmbH Verfahren und anlage zur erzeugung von synthesegas
US8722940B2 (en) 2012-03-01 2014-05-13 Saudi Basic Industries Corporation High molybdenum mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
US9211527B1 (en) 2014-05-29 2015-12-15 Ineos Europe Ag Selective ammoxidation catalysts
BR112016027658B1 (pt) 2014-05-29 2021-09-28 Ineos Europe Ag Composições catalíticas
US9844769B2 (en) 2014-12-17 2017-12-19 Ineos Europe Ag Mixed metal oxide ammoxidation catalysts
US9815045B2 (en) 2015-03-23 2017-11-14 Clariant Corporation Metal oxide catalyst material and processes for making and using same
KR20180100178A (ko) 2016-01-09 2018-09-07 어센드 퍼포먼스 머티리얼즈 오퍼레이션즈 엘엘씨 아크릴로나이트릴 반응기 공급 스트림에서 사이안화 수소의 직접 제조를 위한 촉매 조성물 및 공정
US10626082B2 (en) 2016-10-11 2020-04-21 Ineos Europe Ag Ammoxidation catalyst with selective co-product HCN production
US10479759B2 (en) 2017-02-08 2019-11-19 Clariant Corporation Synthetic methods for the preparation of propylene ammoxidation catalysts
US10479760B2 (en) 2017-02-08 2019-11-19 Clariant Corporation Synthetic methods for the preparation of propylene ammoxidation catalysts
US11772080B2 (en) * 2019-04-15 2023-10-03 Asahi Kasei Kabushiki Kaisha Catalyst, method for producing catalyst, and method for producing acrylonitrile
EP4205844A4 (fr) * 2020-11-17 2024-03-27 Lg Chem, Ltd. Catalyseur d'ammoxydation, son procédé de production, et procédé de production d'acrylonitrile à l'aide du catalyseur d'ammoxydation

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR79628E (fr) * 1958-10-28 1962-12-28 Montecatini Societa Gen Per L Catalyseur pour la production de formaldéhyde à partir du méthanol
FR1511572A (fr) * 1965-08-25 1968-02-02 Grace W R & Co Oxydation des oléfines en acides carboxyliques à l'aide d'un catalyseur au molybdate de cobalt activé par du bismuth
FR2233315A1 (fr) * 1973-06-15 1975-01-10 Standard Oil Co

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT674763A (fr) * 1962-09-20
US3471556A (en) * 1964-12-07 1969-10-07 Nippon Kayaku Kk Production of unsaturated aliphatic acids
US3642930A (en) * 1968-12-30 1972-02-15 Standard Oil Co Ohio Process for the manufacture of isoprene from isoamylenes and methyl butanols and catalyst therefor
US3636066A (en) * 1969-03-05 1972-01-18 Ube Industries Process for the manufacture of acrylonitrile by ammoxidation
BE749305A (fr) * 1969-05-02 1970-10-01 Nippon Kayaku Kk Catalyseur d'oxydation et son utilisation (
JPS4843096B1 (fr) * 1970-01-31 1973-12-17
JPS529649B1 (fr) * 1970-06-12 1977-03-17
US3746657A (en) * 1971-06-28 1973-07-17 Standard Oil Co Catalyst manufacturing process

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR79628E (fr) * 1958-10-28 1962-12-28 Montecatini Societa Gen Per L Catalyseur pour la production de formaldéhyde à partir du méthanol
FR1511572A (fr) * 1965-08-25 1968-02-02 Grace W R & Co Oxydation des oléfines en acides carboxyliques à l'aide d'un catalyseur au molybdate de cobalt activé par du bismuth
FR2233315A1 (fr) * 1973-06-15 1975-01-10 Standard Oil Co

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2436135A1 (fr) * 1978-09-13 1980-04-11 Ube Industries Procede pour la preparation catalytique de l'acrylonitrile
FR2441423A1 (fr) * 1978-11-13 1980-06-13 Celanese Corp Procede de preparation d'un catalyseur pour l'oxydation des olefines, catalyseur ainsi obtenu et procede d'oxydation des olefines en l'utilisant
FR2502977A1 (fr) * 1981-04-06 1982-10-08 Euteco Impianti Spa Catalyseur pour la conversion d'hydrocarbures insatures en diolefines ou/et en aldehydes et nitriles insatures, et procede pour la preparation de ce catalyseur
FR2670685A1 (fr) * 1990-12-20 1992-06-26 Rhone Poulenc Chimie Procede de preparation de catalyseurs enrobes a base de molybdates de bismuth et de fer dopes par du phosphore et du potassium.
EP0493275A1 (fr) * 1990-12-20 1992-07-01 Rhone-Poulenc Chimie Procédé de préparation de catalyseurs enrobés à base de molybdates de bismuth et de fer dopés par du phosphore et du potassium

Also Published As

Publication number Publication date
JPS5268094A (en) 1977-06-06
DE2653863A1 (de) 1977-06-08
ES453604A1 (es) 1977-11-16
BE848793A (fr) 1977-05-26
GB1564545A (en) 1980-04-10
JPS6029536B2 (ja) 1985-07-11
NL7613086A (nl) 1977-06-01
CA1082165A (fr) 1980-07-22
DE2653863C2 (fr) 1988-10-20
AU2002676A (en) 1978-06-01
BR7607932A (pt) 1977-11-08
DK535276A (da) 1977-05-29
FR2332803B1 (fr) 1982-01-15
US4040978A (en) 1977-08-09
IL50998A (en) 1980-10-26
AU502608B2 (en) 1979-08-02
IT1107704B (it) 1985-11-25
IL50998A0 (en) 1977-01-31

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