FR2306225A1 - Phenolic and urea-formaldehyde resins copolymer foam - prepd. by reaction in presence of ammonium salt catalyst and blowing agent - Google Patents
Phenolic and urea-formaldehyde resins copolymer foam - prepd. by reaction in presence of ammonium salt catalyst and blowing agentInfo
- Publication number
- FR2306225A1 FR2306225A1 FR7510368A FR7510368A FR2306225A1 FR 2306225 A1 FR2306225 A1 FR 2306225A1 FR 7510368 A FR7510368 A FR 7510368A FR 7510368 A FR7510368 A FR 7510368A FR 2306225 A1 FR2306225 A1 FR 2306225A1
- Authority
- FR
- France
- Prior art keywords
- pref
- blowing agent
- phenolic
- resin
- freon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/147—Halogen containing compounds containing carbon and halogen atoms only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2361/00—Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
- C08J2361/34—Condensation polymers of aldehydes or ketones with monomers covered by at least two of the groups C08J2361/04, C08J2361/18, and C08J2361/20
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
Flame resistant and noncorrosive rigid plastic foam is obtd. by copolymerisation in all proportions of a phenolic resin and urea formaldehyde resin, in the presence of a blowing agent (e.g. Freon or other initially gaseous, liquid or solid blowing agent) and a weak catalyst such as used for UF resin e.g. NH4 salts but which does not cause polymerisation of phenolic resins (i.e. excluding pure acids as catalysts). Pref. compsn. comprises 25-75 pref. 50 wt. % phenolic resin, 75-25 pref. 50 wt. % UF resin (as 65% aqs, soln) 10-20% Freon II opt. with Freon 113 and pentane, and 3-10 pref. 3-8% NH4 salts e.g. phosphate, chloride or nitrate. Pref. 2-12% glycerine is added as pore regulator, opt. with a silicone. Used to make expansion joints, sheaths, tubes, preimpregnated materials etc.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7510368A FR2306225A1 (en) | 1975-04-03 | 1975-04-03 | Phenolic and urea-formaldehyde resins copolymer foam - prepd. by reaction in presence of ammonium salt catalyst and blowing agent |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7510368A FR2306225A1 (en) | 1975-04-03 | 1975-04-03 | Phenolic and urea-formaldehyde resins copolymer foam - prepd. by reaction in presence of ammonium salt catalyst and blowing agent |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2306225A1 true FR2306225A1 (en) | 1976-10-29 |
FR2306225B3 FR2306225B3 (en) | 1977-12-16 |
Family
ID=9153455
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7510368A Granted FR2306225A1 (en) | 1975-04-03 | 1975-04-03 | Phenolic and urea-formaldehyde resins copolymer foam - prepd. by reaction in presence of ammonium salt catalyst and blowing agent |
Country Status (1)
Country | Link |
---|---|
FR (1) | FR2306225A1 (en) |
-
1975
- 1975-04-03 FR FR7510368A patent/FR2306225A1/en active Granted
Also Published As
Publication number | Publication date |
---|---|
FR2306225B3 (en) | 1977-12-16 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |