FR2252982A1 - Y-Zeolitic catalyst compsn - prepd by calcining ammonium-sodium-y-zeolite followed by ion exchange treatment - Google Patents
Y-Zeolitic catalyst compsn - prepd by calcining ammonium-sodium-y-zeolite followed by ion exchange treatmentInfo
- Publication number
- FR2252982A1 FR2252982A1 FR7343216A FR7343216A FR2252982A1 FR 2252982 A1 FR2252982 A1 FR 2252982A1 FR 7343216 A FR7343216 A FR 7343216A FR 7343216 A FR7343216 A FR 7343216A FR 2252982 A1 FR2252982 A1 FR 2252982A1
- Authority
- FR
- France
- Prior art keywords
- pref
- zeolite
- sodium
- ion exchange
- exchange treatment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
- C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
- C10G47/12—Inorganic carriers
- C10G47/16—Crystalline alumino-silicate carriers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
- B01J20/186—Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/061—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing metallic elements added to the zeolite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/084—Y-type faujasite
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Abstract
The Y-zeolite catalyst is hydrothermally stable and ammonia stable. The ammonium-sodium-Y-zeolite contg. 0.6-5 wt. % Na, pref. 1-4 wt. % (cald. as Na2O) is calcined at 316-899 pref. 427-899 degrees C in 0.014 pref. 0.14-1.05 kg/cm2 steam for a period sufficient to reduce the elemental cell of the zeolite to 24.40-24.64 pref. 24.42-24.62 angstroms. This is followed by an ion exchange treatment in which >=25 pref. 70% of the remaining Na ions are replaced by ammonium ions. The prod. which contains 1 pref. 0.6 wt. % Na2O, is mixed with a water-contg. oxide of small particle size, for example Al-, Si-, Mg-, Be-, Cr oxide Ti-, Zr-, or Th dioxide, or clay and the mixt, is formed into granules or pelletes and these are again calcined at 316-816 degrees C for a period sufficient to remova ammonia without affecting the cell size to is not 24.40 angstrom. The catalyst is useful for hydrocracking, converting n-paraffins to isoparaffins, isomerising alkyl aromatics, transalkylisation of alkyl aromatics, alkylisation.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19732358485 DE2358485C2 (en) | 1973-11-23 | 1973-11-23 | Catalyst, consisting of a high temperature resistant, ammonia stable zeolite and a finely divided hydrous oxide |
FR7343216A FR2252982A1 (en) | 1973-11-23 | 1973-12-04 | Y-Zeolitic catalyst compsn - prepd by calcining ammonium-sodium-y-zeolite followed by ion exchange treatment |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19732358485 DE2358485C2 (en) | 1973-11-23 | 1973-11-23 | Catalyst, consisting of a high temperature resistant, ammonia stable zeolite and a finely divided hydrous oxide |
FR7343216A FR2252982A1 (en) | 1973-11-23 | 1973-12-04 | Y-Zeolitic catalyst compsn - prepd by calcining ammonium-sodium-y-zeolite followed by ion exchange treatment |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2252982A1 true FR2252982A1 (en) | 1975-06-27 |
FR2252982B1 FR2252982B1 (en) | 1982-06-18 |
Family
ID=25766148
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7343216A Granted FR2252982A1 (en) | 1973-11-23 | 1973-12-04 | Y-Zeolitic catalyst compsn - prepd by calcining ammonium-sodium-y-zeolite followed by ion exchange treatment |
Country Status (2)
Country | Link |
---|---|
DE (1) | DE2358485C2 (en) |
FR (1) | FR2252982A1 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0205813A3 (en) * | 1985-04-22 | 1988-09-21 | Klaus Rennebeck | Catalyst, especially for cleaning exhaust gas, process and apparatus for its manufacture |
DE4134783A1 (en) * | 1991-10-22 | 1993-04-29 | Bosch Gmbh Robert | Electroconductive porous inorganic material used as filter or sensor - contains porous inorganic substance, pref. aluminosilicate or aluminium phosphate, and semiconducting metal oxide, pref. tin di:oxide, carbon di:oxide and/or zinc oxide |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1467053C3 (en) * | 1963-02-21 | 1974-09-05 | W.R. Grace & Co., New York, N.Y. (V.St.A.) | Process for the preparation of a zeolite useful as a cracking catalyst |
US3293192A (en) * | 1965-08-23 | 1966-12-20 | Grace W R & Co | Zeolite z-14us and method of preparation thereof |
US3354077A (en) * | 1966-03-30 | 1967-11-21 | Union Oil Co | Stabilized zeolites and use thereof for hydrocarbon conversions |
GB1189850A (en) * | 1967-12-29 | 1970-04-29 | Shell Int Research | Catalyst Manufacture by Controlled Calcination |
GB1189934A (en) * | 1968-08-19 | 1970-04-29 | Shell Int Research | A process for the preparation of a Zeolite-Based Catalyst |
GB1162969A (en) * | 1968-08-19 | 1969-09-04 | Shell Int Research | A Process for Converting Hydrocarbons |
US3591488A (en) * | 1969-06-11 | 1971-07-06 | Exxon Research Engineering Co | High silica crystalline zeolites and processes for their preparation |
US3692692A (en) * | 1970-10-29 | 1972-09-19 | Union Oil Co | Rejuvenation of damaged zeolitesupported metal catalysts |
-
1973
- 1973-11-23 DE DE19732358485 patent/DE2358485C2/en not_active Expired
- 1973-12-04 FR FR7343216A patent/FR2252982A1/en active Granted
Also Published As
Publication number | Publication date |
---|---|
DE2358485A1 (en) | 1975-05-28 |
DE2358485C2 (en) | 1986-05-15 |
FR2252982B1 (en) | 1982-06-18 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |