FR2153390A1 - Catalyst for hydroxylamine prodn - made by redn of hexachloroplatinum solns with formaldehyde - Google Patents
Catalyst for hydroxylamine prodn - made by redn of hexachloroplatinum solns with formaldehydeInfo
- Publication number
- FR2153390A1 FR2153390A1 FR7233524A FR7233524A FR2153390A1 FR 2153390 A1 FR2153390 A1 FR 2153390A1 FR 7233524 A FR7233524 A FR 7233524A FR 7233524 A FR7233524 A FR 7233524A FR 2153390 A1 FR2153390 A1 FR 2153390A1
- Authority
- FR
- France
- Prior art keywords
- catalyst
- hexachloroplatinum
- solns
- hydroxylamine
- esp
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/90—Regeneration or reactivation
- B01J23/96—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/42—Platinum
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B21/00—Nitrogen; Compounds thereof
- C01B21/082—Compounds containing nitrogen and non-metals and optionally metals
- C01B21/14—Hydroxylamine; Salts thereof
- C01B21/1409—Preparation
- C01B21/1418—Preparation by catalytic reduction of nitrogen oxides or nitrates with hydrogen
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Pt catalysts, with optional addns. of noble metals, are made by heating hexachloroplatinum solns. to boiling and adding a colloid, esp. gelatine, and an inert carrier, esp. graphite powder. The soln. is reduced using excess formaldehyde in alkaline medium, the catalyst is filtered, washed and activated with H2 in acid soln., pref. in the presence of a small amt. of ferricyanide. On exhaustion, the catalyst can be regenerated and reactivated. The materials are esp. suited for reduction of NO, NO2, alkyl nitrites, etc. with H2 for production of hydroxylamine.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
RO6827671 | 1971-09-24 |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2153390A1 true FR2153390A1 (en) | 1973-05-04 |
FR2153390B1 FR2153390B1 (en) | 1976-08-13 |
Family
ID=20089622
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7233524A Granted FR2153390A1 (en) | 1971-09-24 | 1972-09-21 | Catalyst for hydroxylamine prodn - made by redn of hexachloroplatinum solns with formaldehyde |
Country Status (4)
Country | Link |
---|---|
DE (1) | DE2222120B2 (en) |
ES (1) | ES404159A1 (en) |
FR (1) | FR2153390A1 (en) |
IT (1) | IT956627B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1964811A1 (en) * | 2007-02-28 | 2008-09-03 | China Petrochemical Development Corporation | Method for preparing hydroxylamine |
-
1972
- 1972-05-05 DE DE19722222120 patent/DE2222120B2/en active Granted
- 1972-06-15 IT IT25754/72A patent/IT956627B/en active
- 1972-06-23 ES ES404159A patent/ES404159A1/en not_active Expired
- 1972-09-21 FR FR7233524A patent/FR2153390A1/en active Granted
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1964811A1 (en) * | 2007-02-28 | 2008-09-03 | China Petrochemical Development Corporation | Method for preparing hydroxylamine |
Also Published As
Publication number | Publication date |
---|---|
DE2222120B2 (en) | 1976-07-01 |
FR2153390B1 (en) | 1976-08-13 |
DE2222120A1 (en) | 1973-04-05 |
ES404159A1 (en) | 1975-12-16 |
IT956627B (en) | 1973-10-10 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |