FR2067854A5 - Subst vinyl cyclo-propane-1-carboxylic acids insecticidal prepn - Google Patents
Subst vinyl cyclo-propane-1-carboxylic acids insecticidal prepnInfo
- Publication number
- FR2067854A5 FR2067854A5 FR6939757A FR6939757A FR2067854A5 FR 2067854 A5 FR2067854 A5 FR 2067854A5 FR 6939757 A FR6939757 A FR 6939757A FR 6939757 A FR6939757 A FR 6939757A FR 2067854 A5 FR2067854 A5 FR 2067854A5
- Authority
- FR
- France
- Prior art keywords
- subst
- prepn
- insecticidal
- propane
- carboxylic acids
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Racemic, 1R, 2R or 1S, 2S trans-3,3-dimethyl-2-(2-R1, 2-R2-vinyl)cyclopropanecarboxylic acids of formula (I):- (where R1, R2 = alkyl (C1-C6), aryl or aralkyl; or R1 + R2 + attached C-atom form opt. substd.-carbocyclic ring (C3-C7)), are prepd. by condensing an alkyl trans-3,3-dimethyl-2-formylcyclopropnae-1-carboxylate with a cpd. of formula (II):- (where X = Cl, Br, I; Ar = opt. substd. aryl) in the presence of a strong base and finally saponifying the ester to give the desired acid. Esters of the acids, e.g. with allethrolone, pyrethrolone and 5-benzylfur-3-ylmethanol are useful insecticides.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR6939757A FR2067854A5 (en) | 1969-11-19 | 1969-11-19 | Subst vinyl cyclo-propane-1-carboxylic acids insecticidal prepn |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR6939757A FR2067854A5 (en) | 1969-11-19 | 1969-11-19 | Subst vinyl cyclo-propane-1-carboxylic acids insecticidal prepn |
Publications (1)
Publication Number | Publication Date |
---|---|
FR2067854A5 true FR2067854A5 (en) | 1971-08-20 |
Family
ID=9043292
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR6939757A Expired FR2067854A5 (en) | 1969-11-19 | 1969-11-19 | Subst vinyl cyclo-propane-1-carboxylic acids insecticidal prepn |
Country Status (1)
Country | Link |
---|---|
FR (1) | FR2067854A5 (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4048215A (en) * | 1975-04-07 | 1977-09-13 | Roussel Ulcaf | Process for preparation of trans-chrysanthemates |
EP0000345A1 (en) * | 1977-07-06 | 1979-01-24 | Bayer Ag | Substituted phenoxybenzyloxycarbonyl derivatives, their preparation and their use as insecticides and acaricides |
EP0019090A1 (en) * | 1979-04-23 | 1980-11-26 | Bayer Ag | Substituted styryl-cyclopropanecarboxylic acid derivatives, a process for their production, their use, insecticidal and acaricidal compositions, their production and process for combating insects |
FR2458542A1 (en) * | 1979-06-12 | 1981-01-02 | Roussel Uclaf | PROCESS FOR THE PREPARATION OF OPTICALLY ACTIVE ALCOHOL A-CYANES |
-
1969
- 1969-11-19 FR FR6939757A patent/FR2067854A5/en not_active Expired
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4048215A (en) * | 1975-04-07 | 1977-09-13 | Roussel Ulcaf | Process for preparation of trans-chrysanthemates |
EP0000345A1 (en) * | 1977-07-06 | 1979-01-24 | Bayer Ag | Substituted phenoxybenzyloxycarbonyl derivatives, their preparation and their use as insecticides and acaricides |
EP0019090A1 (en) * | 1979-04-23 | 1980-11-26 | Bayer Ag | Substituted styryl-cyclopropanecarboxylic acid derivatives, a process for their production, their use, insecticidal and acaricidal compositions, their production and process for combating insects |
US4316913A (en) | 1979-04-23 | 1982-02-23 | Bayer Aktiengesellschaft | Arthropodicidally active styrylcyclopropanecarboxylic acid esters |
FR2458542A1 (en) * | 1979-06-12 | 1981-01-02 | Roussel Uclaf | PROCESS FOR THE PREPARATION OF OPTICALLY ACTIVE ALCOHOL A-CYANES |
EP0021925A1 (en) * | 1979-06-12 | 1981-01-07 | Roussel-Uclaf | Process for preparing optically active alpha-cyanoalcohols |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |