FR1279273A - New phenyl-benz-azoles and their preparation process - Google Patents

New phenyl-benz-azoles and their preparation process

Info

Publication number
FR1279273A
FR1279273A FR838732A FR838732A FR1279273A FR 1279273 A FR1279273 A FR 1279273A FR 838732 A FR838732 A FR 838732A FR 838732 A FR838732 A FR 838732A FR 1279273 A FR1279273 A FR 1279273A
Authority
FR
France
Prior art keywords
benz
azoles
preparation process
materials
sept
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
FR838732A
Other languages
French (fr)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novartis AG
BASF Schweiz AG
Original Assignee
Ciba Geigy AG
Ciba AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Geigy AG, Ciba AG filed Critical Ciba Geigy AG
Application granted granted Critical
Publication of FR1279273A publication Critical patent/FR1279273A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D263/00—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings
    • C07D263/52—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings condensed with carbocyclic rings or ring systems
    • C07D263/54—Benzoxazoles; Hydrogenated benzoxazoles
    • C07D263/56—Benzoxazoles; Hydrogenated benzoxazoles with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached in position 2
    • C07D263/57—Aryl or substituted aryl radicals
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
    • A61K8/4946—Imidazoles or their condensed derivatives, e.g. benzimidazoles
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D235/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings
    • C07D235/02—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings condensed with carbocyclic rings or ring systems
    • C07D235/04—Benzimidazoles; Hydrogenated benzimidazoles
    • C07D235/18—Benzimidazoles; Hydrogenated benzimidazoles with aryl radicals directly attached in position 2
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
    • C07D277/60—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings condensed with carbocyclic rings or ring systems
    • C07D277/62—Benzothiazoles
    • C07D277/64—Benzothiazoles with only hydrocarbon or substituted hydrocarbon radicals attached in position 2
    • C07D277/66—Benzothiazoles with only hydrocarbon or substituted hydrocarbon radicals attached in position 2 with aromatic rings or ring systems directly attached in position 2
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0041—Optical brightening agents, organic pigments
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3442—Heterocyclic compounds having nitrogen in the ring having two nitrogen atoms in the ring
    • C08K5/3445—Five-membered rings
    • C08K5/3447—Five-membered rings condensed with carbocyclic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/35—Heterocyclic compounds having nitrogen in the ring having also oxygen in the ring
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
    • C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
    • C09K15/30—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing heterocyclic ring with at least one nitrogen atom as ring member
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B5/00—Preserving by using additives, e.g. anti-oxidants
    • C11B5/0042—Preserving by using additives, e.g. anti-oxidants containing nitrogen
    • C11B5/0064—Heterocyclic compounds containing nitrogen in the ring
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/35—Heterocyclic compounds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Medicinal Chemistry (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Textile Engineering (AREA)
  • Power Engineering (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Dermatology (AREA)
  • Computer Hardware Design (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
  • Paints Or Removers (AREA)
  • Cosmetics (AREA)

Abstract

946,728. Leather. CIBA Ltd. Sept. 14, 1960 [Sept. 23, 1959 ; Dec. 8, 1959], No. 19727/62. Divided out of 941,990. Heading C6C. [Also in Divisions A2, A5, B5, C2, C3, C4, C5, Dl, D2 and G2] Materials are protected against ultra-violet rays by means of compounds of formula where A1 is a branched alkyl group having at least 4 carbon atoms, A2 is an unbranched alkyl group, and n is I or 2 (see Division C2). Materials specified include fibrous materials such as skins and hides and leathers made from the latter and products made therefrom.
FR838732A 1959-09-23 1960-09-16 New phenyl-benz-azoles and their preparation process Expired FR1279273A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CH317661A CH483276A (en) 1959-09-23 1959-09-23 Use of 2-phenyl-benzazoles as a protective agent against ultraviolet radiation outside the textile industry
CH7855059 1959-09-23
CH8156459 1959-12-08

Publications (1)

Publication Number Publication Date
FR1279273A true FR1279273A (en) 1961-12-22

Family

ID=31498871

Family Applications (1)

Application Number Title Priority Date Filing Date
FR838732A Expired FR1279273A (en) 1959-09-23 1960-09-16 New phenyl-benz-azoles and their preparation process

Country Status (6)

Country Link
US (1) US3095422A (en)
CH (1) CH483276A (en)
DE (1) DE1201953B (en)
FR (1) FR1279273A (en)
GB (2) GB941990A (en)
NL (1) NL256123A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3533308A1 (en) * 1984-09-19 1986-03-27 Centre International de Recherches Dermatologiques - C.I.R.D., Valbonne AROMATIC, HETEROCYCLIC DERIVATIVES AND THEIR USE IN THE PHARMACEUTICAL AND COSMETIC AREA
WO1993015712A1 (en) * 1992-02-13 1993-08-19 Merck Patent Gmbh Use of benzimidazole derivatives as protective light filters

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3205083A (en) * 1961-07-31 1965-09-07 Air Prod & Chem Ultra-violet absorbers
DE1157231B (en) * 1961-12-20 1963-11-14 Bayer Ag Process for the preparation of 3-hydroxy-benzisoxazoles
NL300695A (en) * 1962-11-19
US3183231A (en) * 1963-07-17 1965-05-11 American Cyanamid Co Cyanonaphthoxazole brighteners
CH420045A (en) * 1964-09-01 1967-03-15 Ciba Geigy Use of new polyazoles as optical brightening agents for textile organic materials
CH449843A (en) * 1964-09-15 1968-01-15 Ciba Geigy Process for the production of optically brightened moldings from regenerated cellulose
CH472220A (en) * 1966-04-21 1969-05-15 Ciba Geigy Use of 2-phenylbenzoxazole derivatives as ultraviolet absorbers in cosmetic products
US4011236A (en) * 1968-09-09 1977-03-08 Merck & Co., Inc. N-(benzimidazol-2-yl)arylcarboxamides as ultraviolet (uv) light absorbers
IL37633A (en) * 1970-09-10 1975-08-31 Merck & Co Inc 2-(4-(2-benzoxazolyl)phenyl)alkanoic acid derivatives
US3716489A (en) * 1970-10-02 1973-02-13 American Cyanamid Co Supersaturated solid solutions of photochromic materials in epoxies
US3876791A (en) * 1973-11-30 1975-04-08 Uniroyal Inc Control of acarids using certain benzothiazoles or benzothiazolines
US3928617A (en) * 1973-11-30 1975-12-23 Uniroyal Inc Control of acarids using certain benzothiazoles or benzothiazolines
US4109093A (en) * 1975-01-14 1978-08-22 Produits Chimiques Ugine Kuhlmann Process for making 2-(4'-aminophenyl) 5-amino benzimidazole
US3974287A (en) * 1975-01-24 1976-08-10 Uniroyal Inc. Control of acarids using certain benzothiazoles or benzothiazolines
US4046905A (en) * 1975-02-10 1977-09-06 Merck & Co., Inc. Anti-inflammatory, analgesic and antipyretic phenylacetic acids
US4020165A (en) * 1975-08-20 1977-04-26 Uniroyal Inc. Control of acarids using certain benzothiazoles or benzothiazolines
DE2816819A1 (en) * 1978-04-18 1979-10-31 Bayer Ag LIGHT PROTECTION AGENTS
US4522808A (en) * 1980-08-15 1985-06-11 Societe Anonyme Dite: L'oreal Anti-sunburn compositions containing 2-phenyl-indole derivatives
EP0251760B1 (en) * 1986-07-01 1994-01-26 Bridgestone Corporation Rubber composition
DE3905884A1 (en) * 1989-02-25 1990-09-20 Huels Chemische Werke Ag METHOD FOR PRODUCING A THERMOPLASTICALLY PROCESSABLE, AROMATIC POLYAMIDE
IT1284526B1 (en) * 1996-09-13 1998-05-21 3V Sigma Spa BENZOSSAZOLE DERIVATIVES THEIR USE AS STABILIZERS AGAINST UV RADIATIONS
CA2723455C (en) 2008-05-14 2015-04-28 Otsuka Pharmaceutical Factory, Inc. Lipoprotein lipase-activating compositions comprising benzene derivates

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE676103C (en) * 1933-03-31 1939-05-25 I G Farbenindustrie Akt Ges Radiation protection agents
US2746971A (en) * 1954-11-02 1956-05-22 Dow Chemical Co Dinitrobenzoxazoles
NL208082A (en) * 1955-06-17
US2985661A (en) * 1956-02-06 1961-05-23 American Cyanamid Co Preparation of 2(omicron-aminophenyl)-benzimidazole
AT195922B (en) * 1956-06-02 1958-02-25 Ciba Geigy Process for the preparation of α, β-di- [aryloxazolyl- (2)] - ethylene compounds
DE1022360B (en) * 1956-07-28 1958-01-09 Bayer Ag Sunscreens for human skin
NL219455A (en) * 1956-07-31
US2933503A (en) * 1957-01-14 1960-04-19 Merck & Co Inc Benzimidazole derivatives
DE1040753B (en) * 1957-05-02 1958-10-09 Bayer Ag Radiation protection agents
US2932649A (en) * 1958-09-10 1960-04-12 Rhone Poulenc Sa 2-thiocyanomethyl benzothiazole and corresponding 5-chlorobenzothiazole and benzoxazoe

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3533308A1 (en) * 1984-09-19 1986-03-27 Centre International de Recherches Dermatologiques - C.I.R.D., Valbonne AROMATIC, HETEROCYCLIC DERIVATIVES AND THEIR USE IN THE PHARMACEUTICAL AND COSMETIC AREA
WO1993015712A1 (en) * 1992-02-13 1993-08-19 Merck Patent Gmbh Use of benzimidazole derivatives as protective light filters

Also Published As

Publication number Publication date
CH483276A (en) 1969-12-31
DE1201953B (en) 1965-09-30
GB941990A (en) 1963-11-20
US3095422A (en) 1963-06-25
GB946728A (en) 1964-01-15
NL256123A (en) 1964-03-25

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