FI3874013T3 - Biodiesel composition - Google Patents

Biodiesel composition Download PDF

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Publication number
FI3874013T3
FI3874013T3 FIEP19798695.3T FI19798695T FI3874013T3 FI 3874013 T3 FI3874013 T3 FI 3874013T3 FI 19798695 T FI19798695 T FI 19798695T FI 3874013 T3 FI3874013 T3 FI 3874013T3
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Finland
Prior art keywords
lignin
biodiesel
biodiesel composition
depolymerized
composition according
Prior art date
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FIEP19798695.3T
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Finnish (fi)
Inventor
Suvi Pietarinen
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Upm Kymmene Corp
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Publication of FI3874013T3 publication Critical patent/FI3874013T3/en

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C10L1/026—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for compression ignition
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/192—Macromolecular compounds
    • C10L1/198—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07G—COMPOUNDS OF UNKNOWN CONSTITUTION
    • C07G1/00—Lignin; Lignin derivatives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00—Compositions of lignin-containing materials
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/146—Macromolecular compounds according to different macromolecular groups, mixtures thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/1802—Organic compounds containing oxygen natural products, e.g. waxes, extracts, fatty oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00—Components of fuel compositions
    • C10L2200/04—Organic compounds
    • C10L2200/0461—Fractions defined by their origin
    • C10L2200/0469—Renewables or materials of biological origin
    • C10L2200/0476—Biodiesel, i.e. defined lower alkyl esters of fatty acids first generation biodiesel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
    • C10L2230/04—Catalyst added to fuel stream to improve a reaction
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
    • C10L2230/08—Inhibitors
    • C10L2230/081—Anti-oxidants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2270/00—Specifically adapted fuels
    • C10L2270/02—Specifically adapted fuels for internal combustion engines
    • C10L2270/026—Specifically adapted fuels for internal combustion engines for diesel engines, e.g. automobiles, stationary, marine
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/24—Mixing, stirring of fuel components
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Materials Engineering (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Compounds Of Unknown Constitution (AREA)
  • Medicines Containing Plant Substances (AREA)

Claims (14)

PATENTTIVAATIMUKSETPATENT CLAIMS 1. Menetelmä stabilointiaineen tuottamiseksi biodieselkoostumusta varten, jossa menetelmä käsittää: ligniinin tarjoamisen käyttöön; ja ligniinin altistamisen depolymerisaatiomenetelmälle, joka on emäskatalysoitu hajotusmenetelmä tai entsymaattinen depolymerisaatiomenetelmä, depolymer- isoidun ligniinin saamiseksi, jonka painokeskiarvo- molekyylipaino on ainakin 360 g/mol ja enintään 5 000 g/mol, ligniinin antioksidanttikapasiteetin lisäämistä varten, jossa depolymerisoidun ligniinin TEAC-arvo (Trolox-ekvivalentti antioksidanttikapasiteetti) on enintään 50 % vastaavan ligniinin TEAC-arvosta ennen sen depolymerisoimista, ja jossa depolymerisoidun lig- niinin painokeskiarvomolekyylipaino on enintään 60 % vastaavan ligniinin Ppainokeskiarvomolekyylipainosta, jossa vastaava ligniini on sama ligniinimolekyyli kuin depolymerisoitu ligniini, mutta ennen kuin se on de- polymerisoitu.1. A method of producing a stabilizer for a biodiesel composition, wherein the method comprises: providing lignin for use; and subjecting the lignin to a depolymerization method, which is a base-catalyzed decomposition method or an enzymatic depolymerization method, to obtain a depolymerized lignin having a weight average molecular weight of at least 360 g/mol and not more than 5,000 g/mol, for increasing the antioxidant capacity of the lignin, wherein the TEAC value of the depolymerized lignin (Trolox -equivalent antioxidant capacity) is at most 50% of the TEAC value of the corresponding lignin before it is depolymerized, and where the weight average molecular weight of the depolymerized lignin is at most 60% of the Pweight average molecular weight of the corresponding lignin, where the corresponding lignin is the same lignin molecule as the depolymerized lignin, but before it is depolymerized . 2. Menetelmä biodieselkoostumuksen tuottam- iseksi, jossa patenttivaatimuksen 1 mukaisella men- etelmällä saatava stabilointiaine yhdistetään biod- ieselin kanssa.2. A method for producing a biodiesel composition, in which the stabilizer obtained by the method according to claim 1 is combined with biodiesel. 3. Biodieselkoostumus, joka käsittää patent- tivaatimuksen 1 mukaisella menetelmällä saatavaa sta- bilointiainetta.3. A biodiesel composition comprising a stabilizer obtainable by the method according to patent claim 1. 4. Patenttivaatimuksen 3 mukainen hbiodies- elkoostumus, jossa depolymerisoidun ligniinin TEAC- arvo on enintään 40 % tai enintään 30 % tai enintään 20 % vastaavan ligniinin TEAC-arvosta ennen sen de- polymerisoimista.4. The hbiodiesel composition according to claim 3, wherein the TEAC value of the depolymerized lignin is at most 40% or at most 30% or at most 20% of the TEAC value of the corresponding lignin before its depolymerization. 5. Jonkin patenttivaatimuksista 3 tai 4 mukainen biodieselkoostumus, jossa depolymerisoidun ligniinin painokeskiarvomolekyylipaino on 420 - 4 000 g/mol tai 500 - 3 600 g/mol tai 700 - 3 000 g/mol.5. The biodiesel composition according to one of claims 3 or 4, wherein the weight average molecular weight of the depolymerized lignin is 420 to 4,000 g/mol or 500 to 3,600 g/mol or 700 to 3,000 g/mol. 6. Jonkin patenttivaatimuksista 3, 4 tai 5 mukainen biodieselkoostumus, jossa depolymerisoidun ligniinin painokeskiarvomolekyylipaino on enintään 50 % tai enintään 40 % vastaavan ligniinin painokeskiar- vomolekyylipainosta.6. The biodiesel composition according to one of claims 3, 4 or 5, in which the weight average molecular weight of the depolymerized lignin is at most 50% or at most 40% of the weight average molecular weight of the corresponding lignin. 7. Jonkin patenttivaatimuksista 3 - 6 mukain- en biodieselkoostumus, jossa biodieselkoostumus sis- ältää enintään 15 ppm rikkiä tai enintään 10 ppm rikkiä tai ei sisällä olennaisesti ollenkaan rikkiä.7. The biodiesel composition according to one of claims 3 to 6, where the biodiesel composition contains no more than 15 ppm sulfur or no more than 10 ppm sulfur or contains essentially no sulfur at all. 8. Jonkin patenttivaatimuksista 3 - 7 mukain- en biodieselkoostumus, jossa depolymerisoitava ligni- ini on teknistä ligniiniä.8. The biodiesel composition according to one of claims 3 to 7, in which the lignin to be depolymerized is technical lignin. 9. Jonkin patenttivaatimuksista 3 - 8 mukain- en biodieselkoostumus, jossa biodiesel on rasvahappo- metyyliesteripohjaista biodieseliä.9. The biodiesel composition according to one of claims 3 to 8, where the biodiesel is fatty acid methyl ester-based biodiesel. 10. Jonkin patenttivaatimuksista 3 - 9 mukainen biodieselkoostumus, jossa biodieselkoostumus käsittää 250 - 1 000 ppm stabilointiainetta.10. The biodiesel composition according to one of claims 3 to 9, wherein the biodiesel composition comprises 250 to 1,000 ppm stabilizer. 11. Jonkin patenttivaatimuksista 3 - 10 mukainen biodieselkoostumus, jossa biodieselkoostumus käsittää enintään yhden %painoprosentin fossiilista hiiltä tai enintään 0,5 painoprosenttia fossiilista hiiltä tai ei sisällä olennaisesti ollenkaan fossiilista hiiltä.11. The biodiesel composition according to one of claims 3 to 10, wherein the biodiesel composition comprises no more than one % by weight of fossil carbon or no more than 0.5 % by weight of fossil carbon or contains essentially no fossil carbon at all. 12. Dieselpolttoaine, joka käsittää jonkin patenttivaatimuksista 3 - 11 mukaista biodieselkoos- tumusta.12. Diesel fuel comprising a biodiesel composition according to one of claims 3 to 11. 13. Stabilointiaine biodieselkoostumusta varten, joka stabilointiaine on saatavissa patent- tivaatimuksen 1 mukaisesti.13. A stabilizer for a biodiesel composition, which stabilizer is obtainable according to patent claim 1. 14. Patenttivaatimuksen 1 mukaisella men- etelmällä saatavan stabilointiaineen käyttö biodies- elkoostumuksen oksidaation vähentämiseksi.14. Use of the stabilizer obtained by the method according to claim 1 to reduce the oxidation of the biodiesel composition.
FIEP19798695.3T 2018-10-31 2019-10-28 Biodiesel composition FI3874013T3 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FI20185919A FI20185919A1 (en) 2018-10-31 2018-10-31 Biodiesel composition
PCT/FI2019/050764 WO2020089521A1 (en) 2018-10-31 2019-10-28 Biodiesel composition

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FI3874013T3 true FI3874013T3 (en) 2024-05-16

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FI20185919A FI20185919A1 (en) 2018-10-31 2018-10-31 Biodiesel composition
FIEP19798695.3T FI3874013T3 (en) 2018-10-31 2019-10-28 Biodiesel composition

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US (1) US11434442B2 (en)
EP (1) EP3874013B1 (en)
JP (1) JP7510410B2 (en)
CN (1) CN112996886A (en)
BR (1) BR112021007543A2 (en)
CA (1) CA3116152A1 (en)
FI (2) FI20185919A1 (en)
MX (1) MX2021004791A (en)
WO (1) WO2020089521A1 (en)

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005220227A (en) * 2004-02-05 2005-08-18 Dawn Of The World:Kk Biodiesel fuel and method for producing the same
US8680029B2 (en) * 2009-10-02 2014-03-25 Exxonmobil Research And Engineering Company Lubricating oil compositions for biodiesel fueled engines
BR112013008806B8 (en) 2010-10-15 2018-05-15 Upm Kymmene Corp continuous method for precipitation of lignin from black liquor
FI125991B (en) 2010-10-15 2016-05-13 Upm Kymmene Corp Method and apparatus for continuous precipitation of lignin from black liquor
EP2522690A1 (en) * 2011-03-24 2012-11-14 Annikki GmbH Method for manufacturing lignin derivatives
CA2896791C (en) * 2013-01-25 2021-03-23 Ren Fuel K2B Ab Compositions of biomass materials for refining
NZ629052A (en) * 2013-03-15 2017-04-28 Renmatix Inc High purity lignin, lignin compositions, and higher structured lignin
EP3074484B1 (en) * 2013-11-27 2020-04-15 Kat2Biz AB Depolymerisation of lignin in biomass
WO2015199608A1 (en) * 2014-06-27 2015-12-30 Ren Fuel K2B Ab Depolymerisation of lignin
EP3307751B1 (en) 2015-06-15 2020-02-05 Ren Fuel K2B AB Composition comprising derivatized lignin for fuel production
SE542463C2 (en) 2015-12-01 2020-05-12 Ren Fuel K2B Ab Depolymerized lignin in hydrocarbon oil

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Publication number Publication date
JP7510410B2 (en) 2024-07-03
US20210403820A1 (en) 2021-12-30
BR112021007543A2 (en) 2021-07-27
CN112996886A (en) 2021-06-18
JP2022504811A (en) 2022-01-13
EP3874013B1 (en) 2024-02-28
WO2020089521A1 (en) 2020-05-07
FI20185919A (en) 2020-05-01
EP3874013A1 (en) 2021-09-08
FI20185919A1 (en) 2020-05-01
US11434442B2 (en) 2022-09-06
MX2021004791A (en) 2021-06-08
CA3116152A1 (en) 2020-05-07

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