FI20105630L - Sulppuperäisten terpeenien katalyyttinen jalostus - Google Patents
Sulppuperäisten terpeenien katalyyttinen jalostus Download PDFInfo
- Publication number
- FI20105630L FI20105630L FI20105630A FI20105630A FI20105630L FI 20105630 L FI20105630 L FI 20105630L FI 20105630 A FI20105630 A FI 20105630A FI 20105630 A FI20105630 A FI 20105630A FI 20105630 L FI20105630 L FI 20105630L
- Authority
- FI
- Finland
- Prior art keywords
- terpenes
- cymene
- catalytic refining
- mentioned method
- pulp
- Prior art date
Links
- 230000003197 catalytic effect Effects 0.000 title 1
- 238000007670 refining Methods 0.000 title 1
- 150000003505 terpenes Chemical class 0.000 title 1
- 235000007586 terpenes Nutrition 0.000 title 1
- HFPZCAJZSCWRBC-UHFFFAOYSA-N p-cymene Chemical compound CC(C)C1=CC=C(C)C=C1 HFPZCAJZSCWRBC-UHFFFAOYSA-N 0.000 abstract 4
- 238000000034 method Methods 0.000 abstract 3
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- 241000779819 Syncarpia glomulifera Species 0.000 abstract 1
- 229910021536 Zeolite Inorganic materials 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006477 desulfuration reaction Methods 0.000 abstract 1
- 230000023556 desulfurization Effects 0.000 abstract 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 1
- 239000001739 pinus spp. Substances 0.000 abstract 1
- 238000004537 pulping Methods 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 abstract 1
- 229940036248 turpentine Drugs 0.000 abstract 1
- 239000010457 zeolite Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
- C07C5/2767—Changing the number of side-chains
- C07C5/277—Catalytic processes
- C07C5/2775—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/373—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
- C07C5/393—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation with cyclisation to an aromatic six-membered ring, e.g. dehydrogenation of n-hexane to benzene
- C07C5/41—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09F—NATURAL RESINS; FRENCH POLISH; DRYING-OILS; OIL DRYING AGENTS, i.e. SICCATIVES; TURPENTINE
- C09F3/00—Obtaining spirits of turpentine
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Kuvataan biopohjainen p-symeeni, joka voidaan edelleen konvertoida tereftalaatiksi. Lisäksi kuvataan menetelmä raa’an sulfaattitärpätin, joka on kerätty kemiallisesta massanvalmistuksesta, konvertoimiseksi p-symeeniksi ja mahdollisesti biologista alkuperää olevaksi tereftaalihapoksi ja vastaavasti sen tuotteet. Mainitussa menetelmässä sekä konversio että rikinpoisto suoritetaan yhdessä reaktiovaiheessa. Esillä oleva kuvaus liittyy myös zeoliittikatalyyttien käyttöön mainitussa menetelmässä.
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FI20105630A FI125782B (fi) | 2010-06-03 | 2010-06-03 | Sulppuperäisten terpeenien katalyyttinen jalostus |
CN201180027376.6A CN103003223B (zh) | 2010-06-03 | 2011-06-03 | 通过使用沸石催化剂将α-蒎烯转化成对伞花烃的方法 |
CA2801394A CA2801394C (en) | 2010-06-03 | 2011-06-03 | Method of converting alpha-pinene to para-cymene by using a zeolitic catalyst |
RU2012153228/04A RU2555368C2 (ru) | 2010-06-03 | 2011-06-03 | Способ превращения альфа-пинена в пара-цимол с использованием цеолитового катализатора |
PL11789317T PL2580179T3 (pl) | 2010-06-03 | 2011-06-03 | Sposób konwersji alfa-pinenu do paracymenu z użyciem zeolitowego katalizatora |
US13/701,658 US9469581B2 (en) | 2010-06-03 | 2011-06-03 | Catalytic refining of terpenes of pulp origin |
BR112012030782-7A BR112012030782B1 (pt) | 2010-06-03 | 2011-06-03 | Refino catalítico de terpenos de origem de polpa |
PCT/FI2011/050518 WO2011151526A1 (en) | 2010-06-03 | 2011-06-03 | Method of converting alpha-pinene to para-cymene by using a zeolitic catalyst |
EP11789317.2A EP2580179B1 (en) | 2010-06-03 | 2011-06-03 | Method of converting alpha-pinene to para-cymene by using a zeolitic catalyst |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FI20105630A FI125782B (fi) | 2010-06-03 | 2010-06-03 | Sulppuperäisten terpeenien katalyyttinen jalostus |
FI20105630 | 2010-06-03 |
Publications (4)
Publication Number | Publication Date |
---|---|
FI20105630A0 FI20105630A0 (fi) | 2010-06-03 |
FI20105630A FI20105630A (fi) | 2011-12-04 |
FI20105630L true FI20105630L (fi) | 2011-12-04 |
FI125782B FI125782B (fi) | 2016-02-15 |
Family
ID=42308087
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FI20105630A FI125782B (fi) | 2010-06-03 | 2010-06-03 | Sulppuperäisten terpeenien katalyyttinen jalostus |
Country Status (9)
Country | Link |
---|---|
US (1) | US9469581B2 (fi) |
EP (1) | EP2580179B1 (fi) |
CN (1) | CN103003223B (fi) |
BR (1) | BR112012030782B1 (fi) |
CA (1) | CA2801394C (fi) |
FI (1) | FI125782B (fi) |
PL (1) | PL2580179T3 (fi) |
RU (1) | RU2555368C2 (fi) |
WO (1) | WO2011151526A1 (fi) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SE537150C2 (sv) * | 2012-02-14 | 2015-02-17 | Holmen Ab | Metod för att isolera cymen |
CN105473535A (zh) * | 2013-08-14 | 2016-04-06 | 霍尔曼公司 | 用于制备对-甲基异丙基苯的方法 |
CN107008499B (zh) * | 2017-04-13 | 2019-12-31 | 上海科技大学 | 可将萜类化合物转化为芳香烃的组合催化剂及方法 |
WO2021021694A1 (en) * | 2019-07-26 | 2021-02-04 | International Flavors And Fragrances Inc. | Circular economic methods for fragrance ingredients |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3130007A (en) * | 1961-05-12 | 1964-04-21 | Union Carbide Corp | Crystalline zeolite y |
CA973206A (en) | 1972-02-29 | 1975-08-19 | Oldrich Prochazka | Turpentine purification process |
US3778486A (en) | 1972-04-19 | 1973-12-11 | Scm Corp | Turpentine fraction purification |
FR2243246A1 (en) | 1973-09-12 | 1975-04-04 | Scm Corp | Turpentine fraction purificn - by multi-stage activated carbon sorption process |
SU929676A1 (ru) | 1980-07-10 | 1982-05-23 | Центральный научно-исследовательский и проектный институт лесохимической промышленности | Способ очистки сульфатного скипидара |
US4382152A (en) | 1981-10-14 | 1983-05-03 | The Goodyear Tire & Rubber Company | Process for the conversion of terpenes to cymenes |
DE3513569A1 (de) | 1985-04-16 | 1986-10-16 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von alkylbenzolen |
FR2597495B1 (fr) | 1986-04-18 | 1988-07-29 | Elf Aquitaine | Procede et catalyseur de desulfuration des essences terpeniques |
FR2605900B1 (fr) | 1986-10-29 | 1988-12-23 | Elf Aquitaine | Perfectionnement au procede de desulfuration des essences terpeniques |
RU2200144C1 (ru) * | 2001-07-05 | 2003-03-10 | Институт нефтехимии и катализа АН РБ и УНЦ РАН | Способ получения п-цимола (п-метилизопропилбензола) |
CN1317348C (zh) * | 2004-09-27 | 2007-05-23 | 广西大学 | 一种高含量脱氢枞酸的浅色歧化松香和对伞花烃同时制造的方法 |
-
2010
- 2010-06-03 FI FI20105630A patent/FI125782B/fi active IP Right Grant
-
2011
- 2011-06-03 RU RU2012153228/04A patent/RU2555368C2/ru active
- 2011-06-03 EP EP11789317.2A patent/EP2580179B1/en active Active
- 2011-06-03 BR BR112012030782-7A patent/BR112012030782B1/pt active IP Right Grant
- 2011-06-03 PL PL11789317T patent/PL2580179T3/pl unknown
- 2011-06-03 CN CN201180027376.6A patent/CN103003223B/zh active Active
- 2011-06-03 CA CA2801394A patent/CA2801394C/en active Active
- 2011-06-03 WO PCT/FI2011/050518 patent/WO2011151526A1/en active Application Filing
- 2011-06-03 US US13/701,658 patent/US9469581B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
BR112012030782A8 (pt) | 2021-07-06 |
CA2801394C (en) | 2018-03-06 |
US20130165721A1 (en) | 2013-06-27 |
FI125782B (fi) | 2016-02-15 |
EP2580179B1 (en) | 2018-08-15 |
US9469581B2 (en) | 2016-10-18 |
FI20105630A (fi) | 2011-12-04 |
CA2801394A1 (en) | 2011-12-08 |
CN103003223A (zh) | 2013-03-27 |
WO2011151526A1 (en) | 2011-12-08 |
PL2580179T3 (pl) | 2019-03-29 |
EP2580179A1 (en) | 2013-04-17 |
FI20105630A0 (fi) | 2010-06-03 |
BR112012030782A2 (pt) | 2021-06-01 |
RU2555368C2 (ru) | 2015-07-10 |
EP2580179A4 (en) | 2015-11-11 |
RU2012153228A (ru) | 2014-07-20 |
CN103003223B (zh) | 2016-04-06 |
BR112012030782B1 (pt) | 2022-07-12 |
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