ES8605456A1 - Un procedimiento para preparar hidrocarburos por reaccion catalitica de monoxido de carbono con hidrogeno - Google Patents

Un procedimiento para preparar hidrocarburos por reaccion catalitica de monoxido de carbono con hidrogeno

Info

Publication number
ES8605456A1
ES8605456A1 ES546888A ES546888A ES8605456A1 ES 8605456 A1 ES8605456 A1 ES 8605456A1 ES 546888 A ES546888 A ES 546888A ES 546888 A ES546888 A ES 546888A ES 8605456 A1 ES8605456 A1 ES 8605456A1
Authority
ES
Spain
Prior art keywords
sigma
cobalt
peel
kernel
catalyst particles
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES546888A
Other languages
English (en)
Other versions
ES546888A0 (es
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=19844465&utm_source=***_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES8605456(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of ES546888A0 publication Critical patent/ES546888A0/es
Publication of ES8605456A1 publication Critical patent/ES8605456A1/es
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/86—Chromium
    • B01J23/864—Cobalt and chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8913—Cobalt and noble metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/12—Silica and alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/26—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/75—Cobalt
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Abstract

PROCEDIMIENTO PARA PREPARAR HIDROCARBUROS DE REACCION CATALITICA DE MONOXIDO DE CARBONO CON HIDROGENO. CONSISTE EN PONER EN CONTACTO A UNA MEZCLA DE CO/H2 CON UN CATALIZADOR DE COBALTO, A UNA TEMPERATURA ENTRE 125 Y 350JC Y A UNA PRESION ENTRE 54 Y 100 BARES. EL CATALIZADOR DE COBALTO ESTA SOSTENIDO POR UN SOPORTE DE ALUMINA SILICE O SILICE ALUMINA; CONTIENE ACTUADORES ELEGIDOS ENTRE ZIRCONIO, TITANIO, CROMO Y RUTENIO; TIENE FORMA DE LECHO FIJO CON UNA SUPERFICIE EXTERNA ENTRE 5 Y 70 CM/ML Y SE DISTRIBUYE EN EL SOPORTE SEGUN LA RELACION EVP/EVC H 0,85. SIENDO EVC EL VOLUMEN TOTAL DE LAS PARTICULAS DE CATALIZADOR EN CONSIDERACION Y EVP EL VOLUMEN TOTAL DE LAS CASCARAS PRESENTES EN LAS PARTICULAS DEL CATALIZADOR CUANDO ESTAN COMPUESTAS DE UN NUCLEO QUE ESTA RODEADO POR UNA CASCARA, Y TIENE UNA FORMA TAL QUE EN CUALQUIER LUGAR DE SU PERIMETRO LA DISTANCIA MAS CORTA AL PERIMETRO DE LA CASCARA ES LA MISMA.
ES546888A 1984-09-13 1985-09-11 Un procedimiento para preparar hidrocarburos por reaccion catalitica de monoxido de carbono con hidrogeno Expired ES8605456A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL8402807 1984-09-13

Publications (2)

Publication Number Publication Date
ES546888A0 ES546888A0 (es) 1986-03-16
ES8605456A1 true ES8605456A1 (es) 1986-03-16

Family

ID=19844465

Family Applications (1)

Application Number Title Priority Date Filing Date
ES546888A Expired ES8605456A1 (es) 1984-09-13 1985-09-11 Un procedimiento para preparar hidrocarburos por reaccion catalitica de monoxido de carbono con hidrogeno

Country Status (10)

Country Link
US (1) US4599481A (es)
EP (1) EP0174696B1 (es)
JP (1) JPH0639391B2 (es)
BR (1) BR8504383A (es)
CA (1) CA1247654A (es)
DE (1) DE3574011D1 (es)
ES (1) ES8605456A1 (es)
GB (1) GB2164266B (es)
NZ (1) NZ213438A (es)
ZA (1) ZA856947B (es)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8527549D0 (en) * 1985-11-08 1985-12-11 Shell Int Research Supported metal catalysts
GB8623233D0 (en) * 1986-09-26 1986-10-29 British Petroleum Co Plc Syngas conversion catalyst
US6319960B1 (en) * 1986-10-03 2001-11-20 Exxon Research & Engineering Company Method for hydrocarbon synthesis reactions
US5545674A (en) * 1987-05-07 1996-08-13 Exxon Research And Engineering Company Surface supported cobalt catalysts, process utilizing these catalysts for the preparation of hydrocarbons from synthesis gas and process for the preparation of said catalysts
US4962078A (en) * 1987-05-07 1990-10-09 Exxon Research And Engineering Company Cobalt-titania catalysts, process utilizing these catalysts for the preparation of hydrocarbons from synthesis gas, and process for the preparation of said catalysts
US4977126A (en) * 1987-05-07 1990-12-11 Exxon Research And Engineering Company Process for the preparation of surface impregnated dispersed cobalt metal catalysts
US5128377A (en) * 1987-05-07 1992-07-07 Exxon Research And Engineering Company Cobalt-titania catalysts, process utilizing these catalysts for the preparation of hydrocarbons from synthesis gas, and process for the preparation of said catalysts (C-2448)
US5036032A (en) * 1988-03-25 1991-07-30 Exxon Research And Engineering Company Selective catalysts and their preparation for catalytic hydrocarbon synthesis
US5652193A (en) * 1989-03-29 1997-07-29 Exxon Research And Engineering Company Method for hydrocarbon synthesis reactions
GB9010076D0 (en) * 1990-05-04 1990-06-27 Shell Int Research Process for the conversion of methanol into liquid hydrocarbons
US6284807B1 (en) * 1995-08-08 2001-09-04 Exxon Research And Engineering Company Slurry hydrocarbon synthesis process with increased catalyst life
US5939350A (en) * 1997-02-10 1999-08-17 Energy International Corporation Processes and catalysts for conducting fischer-tropsch synthesis in a slurry bubble column reactor
FR2784096B1 (fr) 1998-09-18 2000-12-01 Inst Francais Du Petrole Procede de conversion du gaz de synthese en presence d'un catalyseur a base de metal du groupe viii, les particules du metal etant reparties sous forme d'agregats
DZ2966A1 (fr) 1999-02-15 2004-03-15 Shell Int Research Procédé de préparation d'hydrocarbures à partir demonoxyde de carbone et d'hydrogène.
US6169120B1 (en) 1999-09-17 2001-01-02 Syntroleum Corporation Extended catalyst life two stage hydrocarbon synthesis process
US6239184B1 (en) 1999-09-22 2001-05-29 Syntroleum Corporation Extended catalyst life Fischer-Tropsch process
US7993599B2 (en) * 2006-03-03 2011-08-09 Zeropoint Clean Tech, Inc. Method for enhancing catalyst selectivity
US20080260631A1 (en) 2007-04-18 2008-10-23 H2Gen Innovations, Inc. Hydrogen production process
CN101462079B (zh) * 2007-12-20 2011-07-20 中国石油化工股份有限公司 一种壳层分布催化剂制备方法
CN102553634B (zh) * 2010-12-31 2014-04-30 中国石油化工股份有限公司 一种费托合成催化剂及其应用
CN103157492B (zh) * 2011-12-15 2015-07-29 中国石油化工股份有限公司 一种壳层分布的催化剂及其制备方法
CN112742381B (zh) * 2019-10-29 2023-03-10 中国石油化工股份有限公司 壳层分布型催化剂及其制备方法和应用

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2496095B1 (fr) * 1980-12-15 1985-11-15 Shell Int Research Procede de preparation d'un melange hydrocarbone a partir d'un melange h2/co
US4396539A (en) * 1981-08-14 1983-08-02 Sapienza Richard S Hydrocarbon synthesis catalyst and method of preparation
DE3375913D1 (en) * 1982-11-22 1988-04-14 Shell Int Research Process for the preparation of hydrocarbons

Also Published As

Publication number Publication date
ZA856947B (en) 1986-04-30
US4599481A (en) 1986-07-08
GB8522527D0 (en) 1985-10-16
ES546888A0 (es) 1986-03-16
AU4736785A (en) 1986-03-20
EP0174696A1 (en) 1986-03-19
JPH0639391B2 (ja) 1994-05-25
GB2164266B (en) 1988-09-21
AU571733B2 (en) 1988-04-21
GB2164266A (en) 1986-03-19
CA1247654A (en) 1988-12-28
EP0174696B1 (en) 1989-11-02
JPS61251629A (ja) 1986-11-08
DE3574011D1 (en) 1989-12-07
BR8504383A (pt) 1986-07-08
NZ213438A (en) 1988-04-29

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Legal Events

Date Code Title Description
FD1A Patent lapsed

Effective date: 20041213