ES480166A1 - Metodo para preparar nuevas 2-arilamino-hexahidropiridinas y 2-arilamino-imidazolidinas. - Google Patents
Metodo para preparar nuevas 2-arilamino-hexahidropiridinas y 2-arilamino-imidazolidinas.Info
- Publication number
- ES480166A1 ES480166A1 ES480166A ES480166A ES480166A1 ES 480166 A1 ES480166 A1 ES 480166A1 ES 480166 A ES480166 A ES 480166A ES 480166 A ES480166 A ES 480166A ES 480166 A1 ES480166 A1 ES 480166A1
- Authority
- ES
- Spain
- Prior art keywords
- groups
- carbon atoms
- alcohol
- group
- arylamino
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001875 compounds Chemical class 0.000 title abstract 6
- 238000000034 method Methods 0.000 title abstract 2
- 150000003839 salts Chemical class 0.000 title abstract 2
- 230000000855 fungicidal effect Effects 0.000 title 1
- 239000000203 mixture Substances 0.000 title 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 9
- 125000003158 alcohol group Chemical group 0.000 abstract 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 4
- 125000003545 alkoxy group Chemical group 0.000 abstract 3
- -1 benzyloxy- Chemical class 0.000 abstract 3
- 125000005843 halogen group Chemical group 0.000 abstract 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- 230000001476 alcoholic effect Effects 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical group OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 1
- 125000004453 alkoxycarbonyl group Chemical group 0.000 abstract 1
- 125000003277 amino group Chemical group 0.000 abstract 1
- 125000000000 cycloalkoxy group Chemical group 0.000 abstract 1
- 238000002955 isolation Methods 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 125000003356 phenylsulfanyl group Chemical group [*]SC1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 abstract 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
- C07D239/06—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
- C07D239/08—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms directly attached in position 2
- C07D239/12—Nitrogen atoms not forming part of a nitro radical
- C07D239/14—Nitrogen atoms not forming part of a nitro radical with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, attached to said nitrogen atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P31/00—Antiinfectives, i.e. antibiotics, antiseptics, chemotherapeutics
- A61P31/04—Antibacterial agents
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/04—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
- C07D233/28—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D233/44—Nitrogen atoms not forming part of a nitro radical
- C07D233/50—Nitrogen atoms not forming part of a nitro radical with carbocyclic radicals directly attached to said nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/003—Compounds containing elements of Groups 2 or 12 of the Periodic Table without C-Metal linkages
Landscapes
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Environmental Sciences (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Pest Control & Pesticides (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Agronomy & Crop Science (AREA)
- General Chemical & Material Sciences (AREA)
- Oncology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Communicable Diseases (AREA)
- Medicinal Chemistry (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Pharmacology & Pharmacy (AREA)
- Animal Behavior & Ethology (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
Un método para preparar nuevas 2-arilamino- hexahidropirimidinas y 2-arilamino-imidazolidinas, o sales o complejos de las mismas, caracterizado porque se prepara un compuesto de la fórmula general: **(Fórmula-01)** en la que n es 0 ó 1, R1 y R2 son iguales o diferentes y representan átomos de hidrógeno, grupos alcohilo, alcohiloxi o alcohiltio que tienen de 4 a 12 átomos de carbono, grupos cicloalcohilo que tienen de 3 a 7 átomos de carbono, grupos benciloxi-, benciltio-, fenoxi- ó feniltio opcionalmente sustituidos con halógeno ó alcohilo de C1-C4, grupos fenialcohilo que tienen de 7 a 11 átomos de carbono, de los cuales el grupo fenilo está sustituido opcionalmente con halógeno, dialcohilamino, o con alcohilo, alcoxi o alcohiltio, los cuales grupos alcohilo, alcoxi o alcohiltio tienen de 1 a 6 átomos de carbono y están opcionalmente halogenados, grupos furialcohilo ó tienialcohilo de los cuales los grupos alcohilo tienen de 1 a 4 átomos de carbono, grupos dialcohilamino de los cuales losgrupos alcohilo tienen cada uno de ellos de 2 a 6 átomos de carbono, o grupos alcoxicarbonilo que tienen de 4 a 12 átomos de carbono, o en la cual R1 y R2 representan juntos un grupo trimetileno, tetrametileno ó butadienileno, con la condición de que R1 y R2 no son ambos átomos de hidrógeno, R3, R4, R7 y R8 son iguales o diferentes y representan átomos de hidrógeno o grupos alcohilo que tienen de 1 a 4 átomos de carbono, y R5 y R6 son iguales o diferentes y representan átomos de hidrógeno ó grupos alcohilo que tienen de 1 a 4 átomos de carbono, haciendo reaccionar un compuesto de la fórmula general **(Fórmula-02)** en la que R1 y R2 tienen los significados indicados anteriormente e Y y Z pueden ser ambos átomos de halógeno o grupos alcohiltio, o bien, cuando Y es un grupo amino, Z es un grupo alcoxi o grupo alcohiltio, con un compuesto de la fórmula general **(Fórmula-03)** en la que n, R3, R4, R5, R6, R7 y R8 tienen los significados antes indicados, haciendo que se separen HY y HZ, después de lo cual se obtiene el compuesto final mediante una reacción de aislamiento.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL7711390A NL7711390A (nl) | 1977-10-18 | 1977-10-18 | Nieuwe 2-arylimino-hexahydopyrimidinen en - imi- dazolidinen, zouten en complexen daarvan, werk- wijze ter bereiding van de nieuwe verbindingen, alsmede fungicide preparaten op basis van de nieuwe verbindingen. |
Publications (1)
Publication Number | Publication Date |
---|---|
ES480166A1 true ES480166A1 (es) | 1979-12-16 |
Family
ID=19829358
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES474227A Expired ES474227A1 (es) | 1977-10-18 | 1978-10-16 | Metodo para preparar nuevas 2-arilamino-hexahidropirimidinasy 2-arilamino-imidazolidinas |
ES480166A Expired ES480166A1 (es) | 1977-10-18 | 1979-05-02 | Metodo para preparar nuevas 2-arilamino-hexahidropiridinas y 2-arilamino-imidazolidinas. |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES474227A Expired ES474227A1 (es) | 1977-10-18 | 1978-10-16 | Metodo para preparar nuevas 2-arilamino-hexahidropirimidinasy 2-arilamino-imidazolidinas |
Country Status (21)
Country | Link |
---|---|
US (2) | US4374143A (es) |
EP (1) | EP0001663B1 (es) |
JP (1) | JPS5463080A (es) |
AR (1) | AR225601A1 (es) |
AU (1) | AU521181B2 (es) |
CA (1) | CA1106845A (es) |
CS (2) | CS208757B2 (es) |
DD (2) | DD139989A5 (es) |
DE (1) | DE2861822D1 (es) |
DK (1) | DK458178A (es) |
EG (1) | EG13497A (es) |
ES (2) | ES474227A1 (es) |
HU (1) | HU178690B (es) |
IL (1) | IL55728A (es) |
IT (1) | IT1099744B (es) |
NL (1) | NL7711390A (es) |
NZ (1) | NZ188660A (es) |
PL (2) | PL120588B1 (es) |
SU (2) | SU895289A3 (es) |
TR (1) | TR20567A (es) |
ZA (1) | ZA785278B (es) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL7711390A (nl) * | 1977-10-18 | 1979-04-20 | Philips Nv | Nieuwe 2-arylimino-hexahydopyrimidinen en - imi- dazolidinen, zouten en complexen daarvan, werk- wijze ter bereiding van de nieuwe verbindingen, alsmede fungicide preparaten op basis van de nieuwe verbindingen. |
US4321838A (en) * | 1979-08-13 | 1982-03-30 | Feldman Robert I | Power coupling for a chain saw |
DE2933930A1 (de) * | 1979-08-22 | 1981-03-12 | C.H. Boehringer Sohn, 6507 Ingelheim | 2-(2-chlor-4-cyclopropyl-phenylimino)-imidazolidin, dessen saeureadditionssalze, diese enthaltende arzneimittel und verfahren zur herstellung derselben. |
US4647557A (en) * | 1982-12-28 | 1987-03-03 | Gerard Moinet | Novel heterocyclic derivatives bearing an amino radical, processes for their production and the pharmaceutical compositions containing them |
GB8922750D0 (en) * | 1989-10-10 | 1989-11-22 | Dow Chemical Co | Fungicidal compounds,their production and use |
US5292743A (en) * | 1989-10-10 | 1994-03-08 | Dowelanco | Fungicidal compositions, fungicidal compounds, their production and use |
GB9016800D0 (en) * | 1990-07-31 | 1990-09-12 | Shell Int Research | Tetrahydropyrimidine derivatives |
US5866579A (en) | 1997-04-11 | 1999-02-02 | Synaptic Pharmaceutical Corporation | Imidazole and imidazoline derivatives and uses thereof |
NZ331480A (en) | 1997-09-04 | 2000-02-28 | F | 2-(Arylphenyl)amino-imidazoline derivatives and pharmaceutical compositions |
US6184242B1 (en) * | 1997-09-04 | 2001-02-06 | Syntex Usa (Llc) | 2-(substituted-phenyl)amino-imidazoline derivatives |
US6417186B1 (en) | 2000-11-14 | 2002-07-09 | Syntex (U.S.A.) Llc | Substituted-phenyl ketone derivatives as IP antagonists |
JP2006525254A (ja) * | 2003-05-01 | 2006-11-09 | エフ.ホフマン−ラ ロシュ アーゲー | Ipアンタゴニストとしてのイミダゾリン−2−イルアミノ−フェニルアミド類 |
MXPA06000269A (es) * | 2003-07-09 | 2006-04-07 | Hoffmann La Roche | Tiofenilaminoimidazolinas. |
JP2007308392A (ja) * | 2006-05-16 | 2007-11-29 | Bayer Cropscience Ag | 殺虫性ベンズアミジン類 |
WO2016043260A1 (ja) * | 2014-09-19 | 2016-03-24 | 塩野義製薬株式会社 | 環状グアニジンまたはアミジン化合物 |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2899434A (en) * | 1959-08-11 | Z-phenylamino-l | ||
US2899426A (en) * | 1959-08-11 | Synthesis of l | ||
FR1211341A (fr) * | 1955-12-19 | 1960-03-15 | A Wander Dr | Procédé pour la préparation de 2-amino-imidazolines |
US3190802A (en) * | 1961-10-09 | 1965-06-22 | Boehringer Sohn Ingelheim | Shaving composition and method of using same |
US3236857A (en) * | 1961-10-09 | 1966-02-22 | Boehringer Sohn Ingelheim | 2-(phenyl-amino)-1, 3-diazacyclopentene-(2) substitution products |
BE632578A (es) * | 1963-05-22 | |||
DE1670274A1 (de) * | 1966-10-31 | 1970-07-16 | Boehringer Sohn Ingelheim | Neues Verfahren zur Herstellung von 2-Arylamino-1,3-diazacycloalkenen-(2) |
US3882229A (en) * | 1972-07-21 | 1975-05-06 | Nordmark Werke Gmbh | Composition and method for shrinking mucous membranes |
DE2316377C3 (de) * | 1973-04-02 | 1978-11-02 | Lentia Gmbh, Chem. U. Pharm. Erzeugnisse - Industriebedarf, 8000 Muenchen | Verfahren zur Herstellung von 2-Phenyl-amino-2-imidazolin-Derivaten und von deren Salzen |
AT330769B (de) * | 1974-04-05 | 1976-07-26 | Chemie Linz Ag | Verfahren zur herstellung von 2-arylamino- 2-imidazolin-derivaten und ihren salzen |
DE2542702C2 (de) * | 1975-09-25 | 1983-11-10 | Lentia GmbH Chem. u. pharm. Erzeugnisse - Industriebedarf, 8000 München | Verfahren zur Herstellung von 1-Benzoyl-2-(2,6-dichlorphenylamino)-2-imidazolin |
NL7711390A (nl) * | 1977-10-18 | 1979-04-20 | Philips Nv | Nieuwe 2-arylimino-hexahydopyrimidinen en - imi- dazolidinen, zouten en complexen daarvan, werk- wijze ter bereiding van de nieuwe verbindingen, alsmede fungicide preparaten op basis van de nieuwe verbindingen. |
US4262005A (en) * | 1978-05-31 | 1981-04-14 | The Boots Company Limited | Compounds, compositions and methods for controlling pests |
DE2933930A1 (de) * | 1979-08-22 | 1981-03-12 | C.H. Boehringer Sohn, 6507 Ingelheim | 2-(2-chlor-4-cyclopropyl-phenylimino)-imidazolidin, dessen saeureadditionssalze, diese enthaltende arzneimittel und verfahren zur herstellung derselben. |
-
1977
- 1977-10-18 NL NL7711390A patent/NL7711390A/xx not_active Application Discontinuation
-
1978
- 1978-09-18 ZA ZA785278A patent/ZA785278B/xx unknown
- 1978-09-27 AR AR273866A patent/AR225601A1/es active
- 1978-10-13 DK DK458178A patent/DK458178A/da not_active Application Discontinuation
- 1978-10-13 IL IL55728A patent/IL55728A/xx unknown
- 1978-10-13 HU HU78PI643A patent/HU178690B/hu unknown
- 1978-10-13 CA CA313,362A patent/CA1106845A/en not_active Expired
- 1978-10-13 IT IT28761/78A patent/IT1099744B/it active
- 1978-10-16 ES ES474227A patent/ES474227A1/es not_active Expired
- 1978-10-16 PL PL1978210324A patent/PL120588B1/pl unknown
- 1978-10-16 CS CS786730A patent/CS208757B2/cs unknown
- 1978-10-16 AU AU40754/78A patent/AU521181B2/en not_active Expired
- 1978-10-16 EP EP78200241A patent/EP0001663B1/en not_active Expired
- 1978-10-16 CS CS786730A patent/CS208758B2/cs unknown
- 1978-10-16 TR TR20567A patent/TR20567A/xx unknown
- 1978-10-16 DE DE7878200241T patent/DE2861822D1/de not_active Expired
- 1978-10-16 DD DD78208481A patent/DD139989A5/de unknown
- 1978-10-16 JP JP12724678A patent/JPS5463080A/ja active Granted
- 1978-10-16 NZ NZ188660A patent/NZ188660A/xx unknown
- 1978-10-16 DD DD78217704A patent/DD147846A5/de unknown
- 1978-10-16 PL PL21699678A patent/PL216996A1/xx unknown
- 1978-10-17 EG EG606/78A patent/EG13497A/xx active
-
1979
- 1979-03-21 SU SU792739504A patent/SU895289A3/ru active
- 1979-05-02 ES ES480166A patent/ES480166A1/es not_active Expired
-
1980
- 1980-02-28 SU SU802891001A patent/SU969160A3/ru active
-
1981
- 1981-05-18 US US06/264,460 patent/US4374143A/en not_active Expired - Fee Related
- 1981-05-18 US US06/264,461 patent/US4396617A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
IL55728A0 (en) | 1978-12-17 |
ZA785278B (en) | 1980-05-28 |
US4374143A (en) | 1983-02-15 |
DE2861822D1 (en) | 1982-07-01 |
EP0001663B1 (en) | 1982-05-12 |
PL216996A1 (es) | 1980-07-14 |
SU969160A3 (ru) | 1982-10-23 |
AU521181B2 (en) | 1982-03-18 |
AR225601A1 (es) | 1982-04-15 |
US4396617A (en) | 1983-08-02 |
PL210324A1 (es) | 1980-03-10 |
JPS6141353B2 (es) | 1986-09-13 |
IL55728A (en) | 1982-05-31 |
NZ188660A (en) | 1980-03-05 |
ES474227A1 (es) | 1979-10-16 |
IT1099744B (it) | 1985-09-28 |
IT7828761A0 (it) | 1978-10-13 |
PL120588B1 (en) | 1982-03-31 |
TR20567A (tr) | 1982-01-01 |
JPS5463080A (en) | 1979-05-21 |
SU895289A3 (ru) | 1981-12-30 |
DD147846A5 (de) | 1981-04-22 |
EP0001663A1 (en) | 1979-05-02 |
CS208758B2 (en) | 1981-09-15 |
EG13497A (en) | 1982-06-30 |
HU178690B (en) | 1982-06-28 |
DD139989A5 (de) | 1980-02-06 |
NL7711390A (nl) | 1979-04-20 |
CS208757B2 (en) | 1981-09-15 |
DK458178A (da) | 1979-04-19 |
CA1106845A (en) | 1981-08-11 |
AU4075478A (en) | 1980-04-24 |
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