ES480050A1 - Procedimiento para la exposidaccion catalitica de olefinas por medio de peroxido de hidrogeno. - Google Patents
Procedimiento para la exposidaccion catalitica de olefinas por medio de peroxido de hidrogeno.Info
- Publication number
- ES480050A1 ES480050A1 ES480050A ES480050A ES480050A1 ES 480050 A1 ES480050 A1 ES 480050A1 ES 480050 A ES480050 A ES 480050A ES 480050 A ES480050 A ES 480050A ES 480050 A1 ES480050 A1 ES 480050A1
- Authority
- ES
- Spain
- Prior art keywords
- olefines
- catalytic epoxidation
- catalytic
- boron
- hydrogen peroxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 230000003197 catalytic effect Effects 0.000 title abstract 3
- 238000006735 epoxidation reaction Methods 0.000 title abstract 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract 1
- 150000001638 boron Chemical class 0.000 abstract 1
- 229910052796 boron Inorganic materials 0.000 abstract 1
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000011707 mineral Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Epoxy Compounds (AREA)
Abstract
Procedimiento para la epoxidación catalítica de olefinas por medio de peroxido de hidrogeno, caracterizado porque se pone en contacto una olefina y peroxido de hidrogeno dentro de un disolvente en presencia de una cantidad catalítica de boro o de un derivado mineral u orgánico de boro o de una melaza de estos a una temperatura comprendida entre los 120 º t 200ºC, sin proceder a la eliminación del agua producida al mismo tiempo que el epóxido.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7812627A FR2424265A1 (fr) | 1978-04-28 | 1978-04-28 | Epoxydation catalytique des olefines en presence de derives du bore |
Publications (1)
Publication Number | Publication Date |
---|---|
ES480050A1 true ES480050A1 (es) | 1980-04-01 |
Family
ID=9207707
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES480050A Expired ES480050A1 (es) | 1978-04-28 | 1979-04-27 | Procedimiento para la exposidaccion catalitica de olefinas por medio de peroxido de hidrogeno. |
Country Status (10)
Country | Link |
---|---|
JP (1) | JPS54144305A (es) |
BE (1) | BE875484A (es) |
CA (1) | CA1115725A (es) |
CH (1) | CH637648A5 (es) |
DE (1) | DE2916834C2 (es) |
ES (1) | ES480050A1 (es) |
FR (1) | FR2424265A1 (es) |
GB (1) | GB2019845B (es) |
IT (1) | IT1118979B (es) |
NL (1) | NL7903373A (es) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2952755A1 (de) * | 1979-12-29 | 1981-07-02 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von oxiranen |
DE3528002A1 (de) * | 1985-08-05 | 1987-02-05 | Degussa | Verfahren zur herstellung eines cycloaliphatischen diepoxids |
DE3528003A1 (de) * | 1985-08-05 | 1987-02-05 | Degussa | Verfahren zur herstellung eines cycloaliphatischen diepoxids |
DE3528005A1 (de) * | 1985-08-05 | 1987-02-05 | Degussa | Verfahren zur herstellung von aliphatischen epoxiden |
DE3528007A1 (de) * | 1985-08-05 | 1987-02-05 | Degussa | Verfahren zur herstellung von epoxidierten polybutadienen |
DE3602254A1 (de) * | 1986-01-25 | 1987-07-30 | Basf Ag | Verfahren zur herstellung von oxiranylcarbonsaeureestern |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1038182A (en) * | 1962-06-29 | 1966-08-10 | Monsanto Co | Production of epoxides |
NL130301C (es) * | 1965-06-01 | |||
US3832363A (en) * | 1965-09-07 | 1974-08-27 | Shell Oil Co | Method of epoxidizing olefinic compounds using an oxyboron catalyst |
BE747316A (fr) * | 1969-03-14 | 1970-08-17 | Sumitomo Chemical Co | Procede de production de composes epoxydes |
US3993673A (en) * | 1970-02-26 | 1976-11-23 | Union Carbide Corporation | Production of olefin oxides |
FR2407209A2 (fr) * | 1977-10-28 | 1979-05-25 | Ugine Kuhlmann | Procede d'epoxydation des olefines par le peroxyde d'hydrogene en presence d'un catalyseur au bore |
BE863237A (fr) * | 1977-02-01 | 1978-07-24 | Ugine Kuhlmann | Procede d'epoxydation catalytique des olefines |
JPS53137903A (en) * | 1977-05-09 | 1978-12-01 | Mitsubishi Gas Chem Co Inc | Preparation of propylene oxide |
GB1517908A (en) * | 1977-05-19 | 1978-07-19 | Texaco Development Corp | Boride catalyst for epoxidizing olefinic compounds |
-
1978
- 1978-04-28 FR FR7812627A patent/FR2424265A1/fr active Granted
-
1979
- 1979-04-02 GB GB7911480A patent/GB2019845B/en not_active Expired
- 1979-04-09 CA CA325,203A patent/CA1115725A/fr not_active Expired
- 1979-04-11 BE BE0/194529A patent/BE875484A/xx not_active IP Right Cessation
- 1979-04-16 JP JP4550479A patent/JPS54144305A/ja active Pending
- 1979-04-26 DE DE2916834A patent/DE2916834C2/de not_active Expired
- 1979-04-27 CH CH401379A patent/CH637648A5/fr not_active IP Right Cessation
- 1979-04-27 ES ES480050A patent/ES480050A1/es not_active Expired
- 1979-04-27 NL NL7903373A patent/NL7903373A/xx not_active Application Discontinuation
- 1979-04-27 IT IT67899/79A patent/IT1118979B/it active
Also Published As
Publication number | Publication date |
---|---|
GB2019845B (en) | 1982-07-28 |
IT1118979B (it) | 1986-03-03 |
JPS54144305A (en) | 1979-11-10 |
FR2424265A1 (fr) | 1979-11-23 |
FR2424265B1 (es) | 1981-04-30 |
GB2019845A (en) | 1979-11-07 |
CA1115725A (fr) | 1982-01-05 |
CH637648A5 (fr) | 1983-08-15 |
BE875484A (fr) | 1979-10-11 |
DE2916834A1 (de) | 1979-10-31 |
IT7967899A0 (it) | 1979-04-27 |
NL7903373A (nl) | 1979-10-30 |
DE2916834C2 (de) | 1982-04-15 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FD1A | Patent lapsed |
Effective date: 19970612 |