ES404376A1 - Preparation of piperidine-spiro-hydantoin derivatives - Google Patents
Preparation of piperidine-spiro-hydantoin derivativesInfo
- Publication number
- ES404376A1 ES404376A1 ES404376A ES404376A ES404376A1 ES 404376 A1 ES404376 A1 ES 404376A1 ES 404376 A ES404376 A ES 404376A ES 404376 A ES404376 A ES 404376A ES 404376 A1 ES404376 A1 ES 404376A1
- Authority
- ES
- Spain
- Prior art keywords
- group
- substituted
- formula
- carbon atoms
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- XYJLFRMXQFKZFC-UHFFFAOYSA-N 1,3,10-triazaspiro[4.5]decane-2,4-dione Chemical class N1C(=O)NC(=O)C11NCCCC1 XYJLFRMXQFKZFC-UHFFFAOYSA-N 0.000 title 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 5
- 125000003342 alkenyl group Chemical group 0.000 abstract 3
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- 125000005843 halogen group Chemical group 0.000 abstract 3
- 239000007983 Tris buffer Substances 0.000 abstract 2
- 125000005041 acyloxyalkyl group Chemical group 0.000 abstract 2
- 125000004183 alkoxy alkyl group Chemical group 0.000 abstract 2
- 125000003545 alkoxy group Chemical group 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 125000002768 hydroxyalkyl group Chemical group 0.000 abstract 2
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 abstract 2
- -1 phosphino group Chemical group 0.000 abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 125000002252 acyl group Chemical group 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 125000004450 alkenylene group Chemical group 0.000 abstract 1
- 125000005452 alkenyloxyalkyl group Chemical group 0.000 abstract 1
- 125000004453 alkoxycarbonyl group Chemical group 0.000 abstract 1
- 125000005078 alkoxycarbonylalkyl group Chemical group 0.000 abstract 1
- 125000006350 alkyl thio alkyl group Chemical group 0.000 abstract 1
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- 125000000304 alkynyl group Chemical group 0.000 abstract 1
- 125000004103 aminoalkyl group Chemical class 0.000 abstract 1
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 125000005160 aryl oxy alkyl group Chemical group 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 125000004966 cyanoalkyl group Chemical group 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- GQPLMRYTRLFLPF-UHFFFAOYSA-N nitrous oxide Chemical group [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 abstract 1
- 125000004430 oxygen atom Chemical group O* 0.000 abstract 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 125000005328 phosphinyl group Chemical group [PH2](=O)* 0.000 abstract 1
- 229910052717 sulfur Chemical group 0.000 abstract 1
- 125000004434 sulfur atom Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3442—Heterocyclic compounds having nitrogen in the ring having two nitrogen atoms in the ring
- C08K5/3445—Five-membered rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6561—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom containing systems of two or more relevant hetero rings condensed among themselves or condensed with a common carbocyclic ring or ring system, with or without other non-condensed hetero rings
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
- C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
- C09K15/30—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing heterocyclic ring with at least one nitrogen atom as ring member
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
PERFECTED PROCEDURE FOR THE MANUFACTURE OF PIPERIDINE-SPYRO-HYDANTOINE DERIVATIVES, comprising a compound having the formula ** (See formula) ** where: X is an oxygen atom or a sulfur atom; n is an integer from 1 to 4 inclusive; ** (See formula) ** R represents: when n is 1 an alkyl group of 1 to 20 carbon atoms, an alkenyl group that can be substituted with halogen, an alkynyl group that can be substituted with phenyl, an aralkyl group that can be substituted with halogen, alkyl of 1 to 4 carbon or halomethyl atoms, a hydroxyalkyl group, an alkoxyalkyl group, an alkenyloxyalkyl group, an aryloxyalkyl group, an alkylthioalkyl group, an acyloxyalkyl group, an N-alkyl-substituted aminoalkyl group, an alkoxycarbonylalkyl group, a group aryloxycarbonylalkyl, an aliphatic acyl group, an alkoxycarbonyl group, a phosphino group that is substituted with phenoxy or alkoxy, or a phosphinyl group that is substituted with phenoxy or alkoxy; when n is 2 an alkylene group of 1 to 10 carbon atoms, an alkenylene group of 4 to 18 carbon atoms, a dialkylene-ether group, an aralkylene group, a bis (acyloxyalkylene) group or an alkylene-bis (oxycarbonylalkyl) group); when n is 3 an alkantrile group of 3 to 10 carbon atoms, a tris group (acyloxyalkylene), an alkane-tris group (oxycarbonylalkyl) or a group of the formula: ** (See formula) ** where p is an integer from 1 to 8, inclusive, and the pes can be the same or different; and when n is 4: a tetrakis (acyloxyalkylene) group or an alkane-tetrakis (oxycarbonylalkyl) group; and R1 represents the hydrogen atom, an alkyl group of 1 to 10 carbon atoms, an alkenyl group, an alkenyl group that can be substituted with aryl, a hydroxyalkyl group, an alkoxyalkyl group, an acyloxyalkyl group, a cyanoalkyl group or a nitrous group comprising reacting a compound having the formula: ** (See formula) ** where R1 and X are as defined above or an alkali metal salt thereof, with a halide having the formula: R- (2) n (III) where n and R are as defined above and Z is a halogen atom. (Machine-translation by Google Translate, not legally binding)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4864671 | 1971-07-02 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES404376A1 true ES404376A1 (en) | 1975-11-16 |
Family
ID=12809113
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES404376A Expired ES404376A1 (en) | 1971-07-02 | 1972-06-30 | Preparation of piperidine-spiro-hydantoin derivatives |
| ES404375A Expired ES404375A1 (en) | 1971-07-02 | 1972-06-30 | Preparation of piperidine-spiro-hydantoin derivatives |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES404375A Expired ES404375A1 (en) | 1971-07-02 | 1972-06-30 | Preparation of piperidine-spiro-hydantoin derivatives |
Country Status (16)
| Country | Link |
|---|---|
| AR (1) | AR193653A1 (en) |
| AT (1) | AT320990B (en) |
| AU (1) | AU474263B2 (en) |
| BE (1) | BE785742A (en) |
| BR (1) | BR7204329D0 (en) |
| CA (2) | CA975369A (en) |
| CH (2) | CH572504A5 (en) |
| DD (1) | DD98688A5 (en) |
| DE (3) | DE2265271A1 (en) |
| ES (2) | ES404376A1 (en) |
| FR (2) | FR2145194A5 (en) |
| GB (2) | GB1393616A (en) |
| IT (2) | IT962342B (en) |
| NL (2) | NL7209271A (en) |
| SU (1) | SU484694A3 (en) |
| ZA (1) | ZA724485B (en) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4961237A (en) * | 1972-06-03 | 1974-06-13 | ||
| CH623066A5 (en) * | 1976-05-11 | 1981-05-15 | Ciba Geigy Ag | |
| CH626109A5 (en) | 1976-05-11 | 1981-10-30 | Ciba Geigy Ag | |
| FR2380290A1 (en) * | 1977-02-15 | 1978-09-08 | Argus Chem | Stabiliser preventing deterioration of organic material by light - comprises an organic phosphite cpd. |
| DE2738340A1 (en) * | 1977-08-25 | 1979-03-01 | Hoechst Ag | NEW UREA DERIVATIVES, THEIR PRODUCTION AND USE AS LIGHT PROTECTION AGENTS |
| EP0007533B1 (en) * | 1978-07-21 | 1982-09-22 | Ciba-Geigy Ag | Piperidine derivatives, process for their preparation and their use as stabilizers for synthetic polymers |
| US4250268A (en) | 1978-11-28 | 1981-02-10 | Ciba-Geigy Corporation | Polysilylesters having a polyalkylpiperidine as part of the polymer useful as light stabilizers for plastics |
| US4234699A (en) | 1978-11-29 | 1980-11-18 | Ciba-Geigy Corporation | Polymeric light stabilizers for plastics |
| US4234700A (en) | 1978-12-04 | 1980-11-18 | Ciba-Geigy Corporation | Polymeric light stabilizers for plastics |
| DE3643890A1 (en) * | 1986-12-22 | 1988-06-30 | Basf Ag | NEW POLYALKYLPIPERIDE INDEXIVES WITH ALKYLENE BRIDGES, THEIR USE AS A STABILIZER AND INTERMEDIATE PRODUCTS |
| EP0707035B1 (en) * | 1994-10-12 | 1999-01-13 | Ciba SC Holding AG | HALS phosphorinanes as stabilisers |
| WO2005058814A2 (en) * | 2003-11-17 | 2005-06-30 | Auburn University | Biocidal siloxane coating material containing n-halogenated amine and amide functional groups |
| WO2005090316A1 (en) * | 2004-03-12 | 2005-09-29 | Wyeth | HYDANTOINS HAVING RNase MODULATORY ACTIVITY |
-
0
- BE BE785742D patent/BE785742A/en unknown
-
1972
- 1972-06-27 CA CA145,824A patent/CA975369A/en not_active Expired
- 1972-06-27 CA CA145,825A patent/CA975370A/en not_active Expired
- 1972-06-29 ZA ZA724485A patent/ZA724485B/en unknown
- 1972-06-29 AT AT560872A patent/AT320990B/en not_active IP Right Cessation
- 1972-06-30 AR AR242849A patent/AR193653A1/en active
- 1972-06-30 CH CH988472A patent/CH572504A5/xx not_active IP Right Cessation
- 1972-06-30 FR FR7223705A patent/FR2145194A5/fr not_active Expired
- 1972-06-30 ES ES404376A patent/ES404376A1/en not_active Expired
- 1972-06-30 FR FR7223704A patent/FR2145193A5/fr not_active Expired
- 1972-06-30 BR BR4329/72A patent/BR7204329D0/en unknown
- 1972-06-30 ES ES404375A patent/ES404375A1/en not_active Expired
- 1972-06-30 SU SU1805633A patent/SU484694A3/en active
- 1972-06-30 DD DD164090A patent/DD98688A5/xx unknown
- 1972-06-30 NL NL7209271A patent/NL7209271A/xx unknown
- 1972-06-30 CH CH988372A patent/CH572482A5/xx not_active IP Right Cessation
- 1972-06-30 NL NL7209269A patent/NL7209269A/xx not_active Application Discontinuation
- 1972-07-01 IT IT26512/72A patent/IT962342B/en active
- 1972-07-01 DE DE19722265271 patent/DE2265271A1/en active Pending
- 1972-07-01 DE DE2233122A patent/DE2233122C3/en not_active Expired
- 1972-07-01 IT IT26511/72A patent/IT962341B/en active
- 1972-07-01 DE DE2233121A patent/DE2233121A1/en active Pending
- 1972-07-03 AU AU44142/72A patent/AU474263B2/en not_active Expired
- 1972-07-03 GB GB3094172A patent/GB1393616A/en not_active Expired
- 1972-07-03 GB GB3094272A patent/GB1393617A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DD98688A5 (en) | 1973-07-05 |
| SU484694A3 (en) | 1975-09-15 |
| NL7209271A (en) | 1973-01-04 |
| BE785742A (en) | 1973-01-02 |
| DE2265271A1 (en) | 1977-04-28 |
| AT320990B (en) | 1975-03-10 |
| DE2233121A1 (en) | 1973-01-25 |
| CA975370A (en) | 1975-09-30 |
| DE2233122B2 (en) | 1981-07-23 |
| ZA724485B (en) | 1973-03-28 |
| GB1393617A (en) | 1975-05-07 |
| CH572504A5 (en) | 1976-02-13 |
| NL7209269A (en) | 1973-01-04 |
| IT962342B (en) | 1973-12-20 |
| DE2233122C3 (en) | 1982-05-19 |
| BR7204329D0 (en) | 1973-05-31 |
| CA975369A (en) | 1975-09-30 |
| ES404375A1 (en) | 1976-04-16 |
| AU4414272A (en) | 1974-01-10 |
| GB1393616A (en) | 1975-05-07 |
| AU474263B2 (en) | 1976-07-15 |
| FR2145194A5 (en) | 1973-02-16 |
| CH572482A5 (en) | 1976-02-13 |
| IT962341B (en) | 1973-12-20 |
| AR193653A1 (en) | 1973-05-11 |
| FR2145193A5 (en) | 1973-02-16 |
| DE2233122A1 (en) | 1973-01-25 |
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