ES398411A1 - Thiazolo(thiono)-phosphoric(phosphonic)acid esters - Google Patents
Thiazolo(thiono)-phosphoric(phosphonic)acid estersInfo
- Publication number
- ES398411A1 ES398411A1 ES398411A ES398411A ES398411A1 ES 398411 A1 ES398411 A1 ES 398411A1 ES 398411 A ES398411 A ES 398411A ES 398411 A ES398411 A ES 398411A ES 398411 A1 ES398411 A1 ES 398411A1
- Authority
- ES
- Spain
- Prior art keywords
- thiono
- formula
- phosphonic
- phosphoric
- acid esters
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002253 acid Substances 0.000 title abstract 3
- 150000002148 esters Chemical class 0.000 title abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- -1 (thiono) -phosphate (phosphonate) halides Chemical class 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 abstract 1
- 239000000370 acceptor Substances 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 150000003863 ammonium salts Chemical class 0.000 abstract 1
- 125000004429 atom Chemical group 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 239000011593 sulfur Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
- C07D277/02—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings
- C07D277/20—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D277/32—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D277/56—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having alternatively specified atoms bound to the phosphorus atom and not covered by a single one of groups A01N57/10, A01N57/18, A01N57/26, A01N57/34
- A01N57/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having alternatively specified atoms bound to the phosphorus atom and not covered by a single one of groups A01N57/10, A01N57/18, A01N57/26, A01N57/34 containing heterocyclic radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6536—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having nitrogen and sulfur atoms with or without oxygen atoms, as the only ring hetero atoms
- C07F9/6539—Five-membered rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Molecular Biology (AREA)
- Agronomy & Crop Science (AREA)
- Biochemistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Procedure for obtaining thiazole (thiono) -phosphoric (phosphonic) acid esters, of formula: **(See formula)** wherein R, R1, R2, and R3 signify straight or branched chain alkyls, the same or different, with 1 to 6 carbon atoms, R1 further signifies an alkoxy residue with 1 to 6 carbon atoms, and X signifies an atom oxygen or sulfur; characterized by comprising reacting (thiono) -phosphate (phosphonate) halides **(See formula)** with 2-alkoxy-4-hydroxy-5-carbalkoxy-thiazoles of the formula: **(See formula)** in the form of the corresponding alkaline, alkaline earth or ammonium salts, or in the presence of acid acceptors, in which formulas R, R1, R2, R3 and X are defined as above and Hal represents a halogen atom, preferably chlorine, in the presence of an inert organic solvent, at temperatures on the order of 0 to 100ºC, preferably 20 to 50ºC. (Machine-translation by Google Translate, not legally binding)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19702064307 DE2064307A1 (en) | 1970-12-29 | 1970-12-29 | Thiazolo (thiono) phosphorus (phosphonic) acid esters, process for their preparation and their use as insecticides |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES398411A1 true ES398411A1 (en) | 1974-09-16 |
Family
ID=5792477
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES398411A Expired ES398411A1 (en) | 1970-12-29 | 1971-12-28 | Thiazolo(thiono)-phosphoric(phosphonic)acid esters |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US3758487A (en) |
| AU (1) | AU456615B2 (en) |
| BE (1) | BE777448A (en) |
| DE (1) | DE2064307A1 (en) |
| ES (1) | ES398411A1 (en) |
| FR (1) | FR2121065A5 (en) |
| GB (1) | GB1322860A (en) |
| IL (1) | IL38461A (en) |
| IT (1) | IT957093B (en) |
| NL (1) | NL7118054A (en) |
| ZA (1) | ZA718682B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2249091B1 (en) * | 1973-10-25 | 1978-11-17 | Roussel Uclaf | |
| FR2285397A1 (en) * | 1974-09-20 | 1976-04-16 | Roussel Uclaf | NEW THIAZOLIC ORGANOPHOSPHORUS DERIVATIVES, PROCESS FOR PREPARATION AND APPLICATION AS PESTICIDES |
| JP5690286B2 (en) * | 2009-03-04 | 2015-03-25 | イデニク プハルマセウティカルス，インコーポレイテッド | Phosphothiophene and phosphothiazole HCV polymerase inhibitors |
-
1970
- 1970-12-29 DE DE19702064307 patent/DE2064307A1/en active Pending
-
1971
- 1971-12-09 AU AU36685/71A patent/AU456615B2/en not_active Expired
- 1971-12-16 US US00208901A patent/US3758487A/en not_active Expired - Lifetime
- 1971-12-27 IL IL7138461A patent/IL38461A/en unknown
- 1971-12-27 IT IT32991/71A patent/IT957093B/en active
- 1971-12-28 ES ES398411A patent/ES398411A1/en not_active Expired
- 1971-12-28 ZA ZA718682A patent/ZA718682B/en unknown
- 1971-12-29 BE BE777448A patent/BE777448A/en unknown
- 1971-12-29 NL NL7118054A patent/NL7118054A/xx unknown
- 1971-12-29 GB GB6032171A patent/GB1322860A/en not_active Expired
- 1971-12-29 FR FR7147274A patent/FR2121065A5/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| GB1322860A (en) | 1973-07-11 |
| IL38461A0 (en) | 1972-02-29 |
| AU3668571A (en) | 1973-06-14 |
| AU456615B2 (en) | 1974-12-19 |
| BE777448A (en) | 1972-06-29 |
| IL38461A (en) | 1974-09-10 |
| ZA718682B (en) | 1972-09-27 |
| DE2064307A1 (en) | 1972-07-06 |
| FR2121065A5 (en) | 1972-08-18 |
| IT957093B (en) | 1973-10-10 |
| US3758487A (en) | 1973-09-11 |
| NL7118054A (en) | 1972-07-03 |
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