ES353946A1 - New chlorobenzilic esters, processes for their production and compositions containing them - Google Patents

New chlorobenzilic esters, processes for their production and compositions containing them

Info

Publication number
ES353946A1
ES353946A1 ES353946A ES353946A ES353946A1 ES 353946 A1 ES353946 A1 ES 353946A1 ES 353946 A ES353946 A ES 353946A ES 353946 A ES353946 A ES 353946A ES 353946 A1 ES353946 A1 ES 353946A1
Authority
ES
Spain
Prior art keywords
esters
chlorobenzilic
processes
new
production
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES353946A
Other languages
Spanish (es)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Agripat SA
Original Assignee
Agripat SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Agripat SA filed Critical Agripat SA
Publication of ES353946A1 publication Critical patent/ES353946A1/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/295—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with inorganic bases, e.g. by alkali fusion
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/10—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with ester groups or with a carbon-halogen bond
    • C07C67/11—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with ester groups or with a carbon-halogen bond being mineral ester groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
    • C07C69/73—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of unsaturated acids
    • C07C69/732—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of unsaturated acids of unsaturated hydroxy carboxylic acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention comprises benzilic acid esters of the formula in which R denotes an unsubstituted or halogensubstituted alkyl, alkenyl or alkinyl group of up to 4 carbon atoms and n is 0 or 1. The esters are obtainable by rearranging bromochlorobenziles under alkaline conditions to yield bromochlorobenzilic acids or salts thereof, which are then esterified. Examples are given. The products are useful as acaricides and insecticides (see Division A5). Bromochlorobenzils for use as starting materials are obtainable by oxidizing bromobenzylchlorophenyl ketones or chlorobenzyl-bromophenyl ketones, suitably with selenium dioxide.
ES353946A 1967-05-17 1968-05-16 New chlorobenzilic esters, processes for their production and compositions containing them Expired ES353946A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH692167A CH531475A (en) 1967-05-17 1967-05-17 Process for the preparation of new 4-bromo-4'-chlorobenzilic acid esters

Publications (1)

Publication Number Publication Date
ES353946A1 true ES353946A1 (en) 1970-02-01

Family

ID=4317130

Family Applications (1)

Application Number Title Priority Date Filing Date
ES353946A Expired ES353946A1 (en) 1967-05-17 1968-05-16 New chlorobenzilic esters, processes for their production and compositions containing them

Country Status (13)

Country Link
AT (1) AT280250B (en)
BE (1) BE715234A (en)
BG (1) BG15375A3 (en)
CH (1) CH531475A (en)
CS (1) CS157034B2 (en)
DE (1) DE1768467A1 (en)
DK (1) DK125699B (en)
ES (1) ES353946A1 (en)
FR (1) FR1566935A (en)
GB (1) GB1210447A (en)
IL (1) IL30015A (en)
NL (1) NL6806944A (en)
SE (1) SE353314B (en)

Also Published As

Publication number Publication date
BG15375A3 (en) 1976-02-25
BE715234A (en) 1968-11-18
CS157034B2 (en) 1974-08-23
GB1210447A (en) 1970-10-28
IL30015A (en) 1971-08-25
NL6806944A (en) 1968-11-18
SE353314B (en) 1973-01-29
CH531475A (en) 1972-12-15
DK125699B (en) 1973-03-26
DE1768467A1 (en) 1972-04-13
FR1566935A (en) 1969-05-09
IL30015A0 (en) 1968-07-25
AT280250B (en) 1970-04-10

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